Chao Fang

Electron transfer within and between molecules is crucial in chemistry, biochemistry, and energy science. This study describes a quantum simulation method that explores the influence of light polarization on the electron transfer between two molecules. By implementing precise and coherent control among the quantum states of trapped atomic ions, we can induce quantum dynamics that mimic the electron transfer dynamics in molecules. We use $3$-level systems (qutrits), rather than traditional two-level systems (qubits) to enhance the simulation efficiency and realize high-fidelity simulations of electron transfer dynamics. We treat the quantum interference between the electron coupling pathways from a donor with two degenerate excited states to an acceptor and analyze the transfer efficiency. We also examine the potential error sources that enter the quantum simulations. The trapped ion systems have favorable scalings with system size compared to those of classical computers, promising access to electron-transfer simulations of increasing richness.

The universality theorem in quantum computing states that any quantum computational task can be decomposed into a finite set of logic gates operating on one and two qubits. However, the process of such decomposition is generally inefficient, often leading to exponentially many gates to realize an arbitrary computational task. Practical processor designs benefit greatly from availability of multi-qubit gates that operate on more than two qubits to implement the desired circuit. In 1995, Cirac and Zoller proposed a method to realize native multi-qubit controlled-$Z$ gates in trapped ion systems, which has a stringent requirement on ground-state cooling of the motional modes utilized by the gate. An alternative approach, the Mølmer-Sørensen gate, is robust against residual motional excitation and has been a foundation for many high-fidelity gate demonstrations. This gate does not scale well beyond two qubits, incurring additional overhead when used to construct many target algorithms. Here, we take advantage of novel performance benefits of long ion chains to realize fully programmable and scalable high-fidelity Cirac-Zoller gates.

Conical intersections are common in molecular physics and photochemistry, and are often invoked to explain observed reaction products. A conical intersection can occur when an excited electronic potential energy surface intersects with the ground electronic potential energy surface in the coordinate space of the nuclear positions. Theory predicts that the conical intersection will result in a geometric phase for a wavepacket on the ground potential energy surface. Although conical intersections have been observed experimentally, the geometric phase has not been observed in a molecular system. Here we use a trapped atomic ion system to perform a quantum simulation of a conical intersection. The internal state of a trapped atomic ion serves as the electronic state and the motion of the atomic nuclei are encoded into the normal modes of motion of the ions. The simulated electronic potential is constructed by applying state-dependent forces to the ion with a near-resonant laser. We experimentally observe the geometric phase on the ground-state surface using adiabatic state preparation followed by motional state measurement. Our experiment shows the advantage of combining spin and motion degrees of freedom in a quantum simulator.

Real-time control software and hardware is essential for operating quantum computers. In particular, the software plays a crucial role in bridging the gap between quantum programs and the quantum system. Unfortunately, current control software is often optimized for a specific system at the cost of flexibility and portability. We propose a systematic design strategy for modular real-time quantum control software and demonstrate that modular control software can reduce the execution time overhead of kernels by 63.3% on average while not increasing the binary size. Our analysis shows that modular control software for two distinctly different systems can share between 49.8% and 91.0% of covered code statements. To demonstrate the modularity and portability of our software architecture, we run a portable randomized benchmarking experiment on two different ion-trap quantum systems.

High-fidelity two-qubit gates in quantum computers are often hampered by fluctuating experimental parameters. The effects of time-varying parameter fluctuations lead to coherent noise on the qubits, which can be suppressed by designing control signals with appropriate filter functions. Here, we develop filter functions for Mølmer-Sørensen gates of trapped-ion quantum computers that accurately predict the change in gate error due to small parameter fluctuations at any frequency. We then design the filter functions of frequency-modulated laser pulses, and compare this method with pulses that are robust to static offsets of the motional-mode frequencies. Experimentally, we measure the noise spectrum of the motional modes and use it for designing the filter functions, which improves the gate fidelity from 99.23(7)% to 99.55(7)% in a five-ion chain.

Crosstalk between target and neighboring spectator qubits due to spillover of control signals represents a major error source limiting the fidelity of two-qubit entangling gates in quantum computers. We show that in our laser-driven trapped-ion system coherent crosstalk error can be modelled as residual $X\hatσ_φ$ interaction and can be actively cancelled by single-qubit echoing pulses. We propose and demonstrate a crosstalk suppression scheme that eliminates all first-order crosstalk, yet only requires local control by driving rotations solely on the target qubits. We report a two-qubit Bell state fidelity of $99.52(6) \%$ with the echoing pulses applied after collective gates and $99.37(5) \%$ with the echoing pulses applied to each gate in a 5-ion chain. This scheme is widely applicable to other platforms with analogous interaction Hamiltonians.

Trapped atomic ions are a versatile platform for studying interactions between spins and bosons by coupling the internal states of the ions to their motion. Measurement of complex motional states with multiple modes is challenging, because all motional state populations can only be measured indirectly through the spin state of ions. Here we present a general method to determine the Fock state distributions and to reconstruct the density matrix of an arbitrary multi-mode motional state. We experimentally verify the method using different entangled states of multiple radial modes in a 5-ion chain. This method can be extended to any system with Jaynes-Cummings type interactions.

Cryogenic environments benefit ion trapping experiments by offering lower motional heating rates, collision energies, and an ultra-high vacuum (UHV) environment for maintaining long ion chains for extended periods of time. Mechanical vibrations caused by compressors in closed-cycle cryostats can introduce relative motion between the ion and the wavefronts of lasers used to manipulate the ions. Here, we present a novel ion trapping system where a commercial low-vibration closed-cycle cryostat is used in a custom monolithic enclosure. We measure mechanical vibrations of the sample stage using an optical interferometer, and observe a root-mean-square relative displacement of 2.4 nm and a peak-to-peak displacement of 17 nm between free-space beams and the trapping location. We packaged a surface ion trap in a cryo-package assembly that enables easy handling, while creating a UHV environment for the ions. The trap cryo-package contains activated carbon getter material for enhanced sorption pumping near the trapping location, and source material for ablation loading. Using $^{171}$Yb$^{+}$ as our ion we estimate the operating pressure of the trap as a function of package temperature using phase transitions of zig-zag ion chains as a probe. We measured the radial mode heating rate of a single ion to be 13 quanta/s on average. The Ramsey coherence measurements yield 330 ms coherence time for counter-propagating Raman carrier transitions using a 355 nm mode-locked pulse laser, demonstrating the high optical stability.

Two-qubit gates in trapped-ion quantum computers are generated by applying spin-dependent forces that temporarily entangle the internal state of the ion with its motion. Laser pulses are carefully designed to generate a maximally entangling gate between the ions while minimizing any residual entanglement between the motion and the ion. The quality of the gates suffers when the actual experimental parameters differ from the ideal case. Here, we improve the robustness of frequency-modulated Mølmer-Sørensen gates to motional mode-frequency offsets by optimizing the average performance over a range of systematic errors using batch optimization. We then compare this method with frequency-modulated gates optimized for ideal parameters that include an analytic robustness condition. Numerical simulations show good performance up to 12 ions, and the method is experimentally demonstrated on a two-ion chain.

Coherent gate errors are a concern in many proposed quantum computing architectures. These errors can be effectively handled through composite pulse sequences for single-qubit gates, however, such techniques are less feasible for entangling operations. In this work, we benchmark our coherent errors by comparing the actual performance of composite single-qubit gates to the predicted performance based on characterization of individual single-qubit rotations. We then propose a compilation technique, which we refer to as hidden inverses, that creates circuits robust to these coherent errors. We present experimental data showing that these circuits suppress both overrotation and phase misalignment errors in our trapped ion system.

In a large scale trapped atomic ion quantum computer, high-fidelity two-qubit gates need to be extended over all qubits with individual control. We realize and characterize high-fidelity two-qubit gates in a system with up to 4 ions using radial modes. The ions are individually addressed by two tightly focused beams steered using micro-electromechanical system (MEMS) mirrors. We deduce a gate fidelity of 99.49(7)% in a two-ion chain and 99.30(6)% in a four-ion chain by applying a sequence of up to 21 two-qubit gates and measuring the final state fidelity. We characterize the residual errors and discuss methods to further improve the gate fidelity towards values that are compatible with fault-tolerant quantum computation.