Christian Tomás Schmiegelow

The simulation of vibrational energy transport and quantum thermodynamics with trapped ions requires good methods for the estimation of temperatures. One valuable tool for this purpose is based on the fit of dark resonances in the fluorescence spectrum. However, this fit demands numerical simulations of the coupled electronic-motional dynamics which usually involve a trade-off between accuracy and speed. Here, we discuss several techniques with simplified dynamical equations for the simulation of the spectrum of a trapped ion that undergoes thermal motion, identifying the advantages and limitations of each method. We start with a three-level model to provide a better insight into the approximations involved, and then move on to tackle the experimentally relevant case of an eight-level calcium ion. We observe that mimicking the effect of thermal motion by means of additional dephasing is computationally very convenient, but can lead to significant errors in the estimation of the temperature. Nevertheless, this can be counteracted by a proper calibration, supporting the use of dark resonances as a practical thermometer.

In this work, we present the design, implementation, and construction of a linear Paul trap in a blade configuration. The trap was optimized to minimize micromotion and enable the formation of linear ion chains comprising tens of ions. We use ytterbium atoms, and in particular, we describe the trapping and cooling of the isotopes $^{174} \mathrm{Yb}^+$ and $^{171} \mathrm{Yb}^+$, starting from an isotope-selective ionization process based on laser frequency stabilization and optimization of fluorescence for each isotope. The electronic control system-including magnetic field generation, laser delivery, and microwave driving-was fully implemented and is described in detail. The system supports pulsed operation, and we performed Rabi oscillations of the hyperfine states in the $^2 \mathrm{S}_{1/2}$ level, demonstrating coherent spectroscopy. These capabilities are fundamental tools for the experiments we aim to pursue, including the use of structured light beams, quantum simulation protocols, and the generation of non-classical motional states.

We present an experiment investigating the rotational Doppler effect using a single trapped ion excited by two copropagating vortex laser beams. The setup isolates the azimuthal gradients of the fields, eliminating longitudinal and curvature effects. We provide a detailed characterization of the phenomenon by deterministically positioning a single ion across the beams, achieving a signal which depends on the angular velocity of the ion and the difference of optical orbital angular momentum between the two beams. The interpretation of the measurements is supported by numerical simulations and by a simplified analytical model. Our results reveal key properties of the rotational Doppler effect, showing that it increases approaching the center of the beam and that it is independent of the waist of the beam. This offers insights into the feasibility of super-kicks or super-Doppler shifts for sensing and manipulating atomic motion transverse to the beams' propagation direction.

We study the influence of micromotion on the spectrum of trapped ions with a lambda-type level scheme, leading to dark resonances due to coherent population trapping. We work with calcium ions trapped in a ring-shaped Paul trap, in which one can compensate excess micromotion for only one ion of the crystal. We observe that micromotion affects the shapes of the dark resonances and causes the appearance of "echoes" separated by intervals given by the drive frequency. We present a theoretical model that provides good fits to the measurements and can be used to estimate the amplitude of the micromotion modulation of the atomic motion. We estimate an effective temperature of the ions from the spectra and observe clear micromotion heating as well as impaired cooling for sufficiently large excess micromotion.

We present experimental results and a theoretical model that illustrate how competing eigenbases can determine the dynamics of a fluorescing atom. In the absence of a magnetic field, the atom can get trapped in a dark state, which inhibits fluorescence. In general, this will happen when the magnetic degeneracy of the ground state is greater than the one of the excited state. A canonical way to avoid optical pumping to dark states is to apply a magnetic field at an angle with respect to the polarization of the exciting light. This generates a competition of eigenbases which manifests as a crossover between two regimes dominated either by the laser or the magnetic field. We illustrate this crossover with fluorescence measurements on a single laser-cooled calcium ion in a Paul trap and find that it occurs at a critical laser intensity that is proportional to the external magnetic field. We contrast our results with numerical simulations of the atomic levels involved and also present a simple theoretical model that provides excellent agreement with experimental results and facilitates the understanding of the dynamics.

In this paper we present a method to measure transient fluorescent dynamics with single trapped ions in a Paul trap. We use $^{40}$Ca$^+$ ions which exhibit a $Λ$-type three-level system and measure the characteristic optical pumping times between the ground $S_{1/2}$ and the meta-stable $D_{3/2}$ levels. We prepare one of these states, then pump it to the opposite via the excited $P_{1/2}$ state. By measuring the scattered photons of the ion, we retrieve transient curves of the atomic fluorescence. These curves provide fundamental information about the atomic system, such as branching fractions and excited-state lifetimes, as well as experimental parameters like the efficiency of the detection system and the saturation parameter of one of the transitions. Finally, we study the time dependent fluorescence as a function of optical power and detuning of the lasers and find a very good agreement with simulating the dynamics via a three-level open quantum system through a set of optical Bloch equations. Being able to record time dependent fluorescence is of particular interest as it contains information about the temperature, cooling and heating dynamics of the ion.

We present theoretical and experimental results of coherent population trapping spectra on a multi-level $^{40}$Ca$^+$-type configuration, adding a third beam to the standard two-laser $Λ$ system to avoid undesired optical pumping. We show that the extra laser can preserve the nature of the dark resonances or introduce decoherence depending on its power. Experiments are carried out using a single trapped $^{40}$Ca$^+$ ion in the $S_{1/2}-P_{1/2}-D_{3/2}$ manifold. Theoretically, the problem is solved with a Floquet-like expansion of the Liouvillian that correctly predicts all of the measured spectra without the need of full time integration. As a first application of the multilaser technique, we show that the richer spectra obtained can be used as a vectorial polarimeter of one of the beams, allowing one to measure the electrical field at the ion position in any spatial direction. We also explain how our setup could realize a thermometer with tunable sensitivity and no laser-linewidth dependence.

We show that the motion of a cold trapped ion can be squeezed by modulating the intensity of a phase-stable optical lattice placed inside the trap. As this method is reversible and state selective it effectively implements a controlled-squeeze gate. We show how to use this resource, that can be useful for quantum information processing with continuous variables, in order to prepare coherent superpositions of states which are squeezed along complementary quadratures. We show that these states, which we denote as "${\mathcal X}$-states", exhibit high sensitivity to small displacements along two complementary quadratures which make them useful for quantum metrology.

We study the interaction of a light beams carrying angular momentum with a single, trapped and well localized ion. We provide a detailed calculation of selection rules and excitation probabilities for quadrupole transitions. The results show the dependencies on the angular momentum and polarization of the laser beam as well as the direction of the quantization magnetic field. In order to observe optimally the specific effects, focusing the angular momentum beam close to the diffraction limit is required. We discuss a protocol for examining experimentally the effects on the S$_{1/2}$ to D$_{5/2}$ transition using a $^{40}$Ca$^+$ ion. Various applications and advantages are expected when using light carrying angular momentum: In quantum information processing, where qubit states of ion crystals are controlled, parasitic light shifts could be avoided as the ion is excited in the dark zone of the beam at zero electric field amplitude. Such interactions also open the door to high dimensional entanglement between light and matter. In spectroscopy one might access transitions which have escaped excitation so far due to vanishing transition dipole moments.