Daniel W. Savin

Solar physicists routinely utilize observations of Ar-like Fe IX and Cl-like Fe X emission to study a variety of solar structures. However, unidentified lines exist in the Fe IX and Fe X spectra, greatly impeding the spectroscopic diagnostic potential of these ions. Here, we present measurements using the Lawrence Livermore National Laboratory EBIT-I electron beam ion trap in the wavelength range 238-258 A. These studies enable us to unambiguously identify the charge state associated with each of the observed lines. This wavelength range is of particular interest because it contains the Fe IX density diagnostic line ratio 241.74 A/244.91 A, which is predicted to be one of the best density diagnostics of the solar corona, as well as the Fe X 257.26 A magnetic-field-induced transition. We compare our measurements to the Fe IX and Fe X lines tabulated in CHIANTI v10.0.1, which is used for modeling the solar spectrum. In addition, we have measured previously unidentified Fe X lines that will need to be added to CHIANTI and other spectroscopic databases.

We report on a cycling scheme for Doppler cooling of trapped OH$^+$ ions using transitions between the electronic ground state $X^3Σ^-$ and the first excited triplet state $A^3Π$. We have identified relevant transitions for photon cycling and repumping, have found that coupling into other electronic states is strongly suppressed, and have calculated the number of photon scatterings required to cool OH$^+$ to a temperature where Raman sideband cooling can take over. In contrast to the standard approach, where molecular ions are sympathetically cooled, our scheme does not require co-trapping of another species and opens the door to the creation of pure samples of cold molecular ions with potential applications in quantum information, quantum chemistry, and astrochemistry. The laser cooling scheme identified for OH$^+$ is efficient despite the absence of near-diagonal Franck-Condon factors, suggesting that broader classes of molecules and molecular ions are amenable to laser cooling than commonly assumed.