E. Krishnakumar

We present the design and fabrication of an endcap-type Paul trap. The trap is designed for studies with Ca$^{+}$ and Yb$^{+}$. The design, fabrication process, and characterization are presented in detail with a focus on trapping a single compensated ion at the rf node. A custom-built imaging system of $NA = 0.14$ and magnification $\approx 22 \times$ performs close to diffraction-limit and resolves multi-ion clusters. Controlled ion loading and characterization of the trap are performed using $^{40}$Ca$^{+}$. The experimentally determined quadrupole coefficient of the trap is $\approx 0.3$, which is very close to the design value. The relative frequency shift along the spectroscopy beam due to excess micromotion (EMM) is at the level of $3.5\times 10^{-18}$ for $^{40}$Ca$^{+}$. Applications of this trap encompass single-ion-based optical frequency standards, tests of fundamental physics, the study of mesoscopic Coulomb clusters, and the controlled interaction of a single ion with co-trapped atoms.

The formation of Li$_2^+$ and subsequently Li$^+$ ions, during the excitation of $^7$Li atoms to the $3S_{1/2}$ state in a $^7$Li magneto optical trap (MOT), is probed in an ion-atom hybrid trap. Associative ionization occurs during the collision of Li($2P_{3/2}$) and Li($3S_{1/2}$) ultracold atoms, creating Li$_2^+$ ions. Photodissociation of Li$_2^+$ by the MOT lasers is an active channel for the conversion of Li$_2^+$ to Li$^+$. A fraction of the Li$_2^+$ ions is long lived even in the presence of MOT light. Additionally, rapid formation of Li$^+$ from Li$_2^+$ in the absence of MOT light is observed. Resonant excitation of ultracold atoms, resulting in intricate molecular dynamics, reveals important processes in ultracold dilute gases.