Fernande Vedel

A scheme for a THz frequency standard based on three-photon coherent population trapping in stored ions is proposed. Assuming the propagation directions of the three lasers obey the phase matching condition, we show that stability of few 10$^{-14}$ at one second can be reached with a precision limited by power broadening to $10^{-11}$ in the less favorable case. The referenced THz signal can be propagated over long distances, the useful information being carried by the relative frequency of the three optical photons.

A recent evaluation of the frequency uncertainty expected for an optical frequency standard based on a single trapped $^{43}$Ca$^+$ ion was published in Phys. Rev. A {\bf 72} (2005) 043404. The paper contains some interesting information like systematic frequency shifts but fails to depict their uncertainty, leading to confuse accuracy and precision. The conclusions about the major contribution to the frequency shift are not consistent with the presented calculations and omit comparisons with data published previously.

The lifetime of the 3d^2D_5/2-level in singly-ionized calcium has been measured by the electron-shelving technique on different samples of rf trapped ions. The metastable state has been directly populated by exciting the dipole-forbidden 4S_1/2 - 3D_5/2 transition. In ion clouds, the natural lifetime of this metastable level has been measured to be (1095+-27) ms. For the single-ion case, we determined a lifetime of (1152+-20) ms. The 1sigma-error bars at the 2%-level have different origins for the two kinds of experiments: data fitting methods for lifetime measurements in an ion cloud and control of experimental parameters for a single ion. De-shelving effects are extensively discussed. The influence of differing approaches for the processing of the single-ion quantum jump data on the lifetime values is shown. Comparison with recent measurements shows excellent agreement when evaluated from a given method.