G. S. Giri

The center-of-mass position of a single trapped atomic ion is measured and tracked in time with high precision. Employing a near-resonant radio frequency field of wavelength 2.37 cm and a static magnetic field gradient of 19 T/m, the spatial location of the ion is determined with an unprecedented wavelength-relative resolution of 5 $\times$ 10$^{-9}$, corresponding to an absolute precision of 0.12 nm. Measurements of an electrostatic force on a single ion demonstrate a sensitivity of 2.2 $\times$ 10$^{-23} ~\text{N}/\sqrt{\text{Hz}}$. The real-time measurement of an atom's position complements the well-established technique of scanning near-field radio frequency transmission microscopy and opens up a novel route to using this method with path breaking spatial and force resolution.

Optical spectroscopy in the gas phase is a key tool to elucidate the structure of atoms and molecules and of their interaction with external fields. The line resolution is usually limited by a combination of first-order Doppler broadening due to particle thermal motion and of a short transit time through the excitation beam. For trapped particles, suitable laser cooling techniques can lead to strong confinement (Lamb-Dicke regime, LDR) and thus to optical spectroscopy free of these effects. For non-laser coolable spectroscopy ions, this has so far only been achieved when trapping one or two atomic ions, together with a single laser-coolable atomic ion [1,2]. Here we show that one-photon optical spectroscopy free of Doppler and transit broadening can also be obtained with more easily prepared ensembles of ions, if performed with mid-infrared radiation. We demonstrate the method on molecular ions. We trap approximately 100 molecular hydrogen ions (HD$^{+}$) within a Coulomb cluster of a few thousand laser-cooled atomic ions and perform laser spectroscopy of the fundamental vibrational transition. Transition frequencies were determined with lowest uncertainty of 3.3$\times$10$^{-12}$ fractionally. As an application, we determine the proton-electron mass ratio by matching a precise ab initio calculation with the measured vibrational frequency.

We present a design for the experimental integration of ion trapping and superconducting qubit systems as a step towards the realization of a quantum hybrid system. The scheme addresses two key difficulties in realizing such a system; a combined microfabricated ion trap and superconducting qubit architecture, and the experimental infrastructure to facilitate both technologies. Developing upon work by Kielpinski et al. [1] we describe the design, simulation and fabrication process for a microfabricated ion trap capable of coupling an ion to a superconducting microwave LC circuit with a coupling strength in the tens of kHz. We also describe existing difficulties in combining the experimental infrastructure of an ion trapping setup into a dilution fridge with superconducting qubits and present solutions that can be immediately implemented using current technology.

As an important step towards an atomic parity violation experiment in one single trapped Ra$^+$ ion, laser spectroscopy experiments were performed with on-line produced short-lived $^{212,213,214}$Ra$^+$ ions. The isotope shift of the $6\,^2$D$_{3/2}$\,-\,$7\,^2$P$_{1/2}$ and $6\,^2$D$_{3/2}$\,-\,$7\,^2$P$_{3/2}$ transitions and the hyperfine structure constant of the $7\,^2$S$_{1/2}$ and $6\,^2$D$_{3/2}$ states in $^{213}$Ra$^+$ were measured. These values provide a benchmark for the required atomic theory. A lower limit of $232(4)$ ms for the lifetime of the metastable $6\,^2$D$_{5/2}$ state was measured by optical shelving.