George Tomaras

Monolithic three-dimensional (3D) Paul traps combine the high-precision microfabrication of two-dimensional (2D) chip traps with the deep trapping potentials and low heating rates characteristic of macroscopic 3D Paul traps, which are typically machined by traditional means and mechanically assembled. However, achieving low motional heating rates and optical access with a high numerical aperture (NA) while maintaining the high radio-frequency (RF) voltages required for trapping heavy ionic species, such as Yb$^{+}$ and Ba$^{+}$, remains a significant technical challenge. In this work, we present a fused-silica, monolithic segmented 3D Paul trap with an ion-electrode distance of 250 $μ$m, and stable operation at high RF voltages. We benchmark the performance of the trap using Yb$^{+}$ ions, demonstrating axially homogeneous trapping potentials spanning over 200 $μ$m about the axial center of the trap, high multi-directional optical access (up to 0.7 NA), and radial motional heating as low as $\dot{\bar n}=1.1 \pm 0.1 $ quanta/s at radial trap frequencies about 3 MHz near room temperature. Furthermore, we observe a motional Ramsey coherence time, ${T}_{2}$, of about 95 ms for the radial center-of-mass mode. We demonstrate the generation of a two-qubit Bell state with a parity contrast of ${99.3}^{+0.7} _{-1.5}$% with state preparation and measurement correction. These results establish fused-silica monolithic 3D Paul traps as a scalable, modular platform for quantum simulation, computation, metrology, and networking with heavy ionic species.

We propose and demonstrate an experimental scheme to engineer thermal baths with independently tunable temperatures and dissipation rates for the motional modes of a trapped-ion system. This approach enables robust thermal-state preparation and quantum simulations of open-system dynamics in bosonic and spin-boson models at well-controlled finite temperatures. We benchmark our protocol by experimentally realizing out-of-equilibrium dynamics of a charge-transfer model at different temperatures. We observe that, when the process occurs at a higher temperature, the transfer rate spectrum broadens, with reduced rates at small donor-acceptor energy gaps and enhanced rates at large gaps. We then employ our scheme to study local-temperature effects in a two-mode vibrationally assisted exciton transfer system, where we observe thermally activated interference pathways for excitation transfer.

Quantum simulation offers a route to study open-system molecular dynamics in non-perturbative regimes by programming the interactions among electronic, vibrational, and environmental degrees of freedom on similar energy scales. Trapped-ion systems possess this capability, with their native spins, phonons, and tunable dissipation integrated within a single platform. Here, we demonstrate an open-system quantum simulation of charge and exciton transfer in a multi-mode linear vibronic coupling model. Employing tailored spin-phonon interactions alongside reservoir engineering techniques, we emulate a system with two dissipative vibrational modes coupled to donor and acceptor electronic sites and follow its non-equilibrium dynamics. We continuously tune the system from the charge transfer (CT) regime to the vibrationally assisted exciton transfer (VAET) regime by controlling the vibronic coupling strengths. We find that degenerate modes enhance CT and VAET rates at large energy gaps, while non-degenerate modes activate slow-mode pathways that reduce the energy-gap dependence, thus enlarging the window for efficient transfer. These results show that the presence of one additional vibration introduces interfering vibrationally assisted pathways and reshapes non-perturbative quantum excitation transfer. Our work establishes a scalable and hardware-efficient route to simulating chemically relevant, many-mode vibronic processes with engineered environments, guiding the design of next-generation organic photovoltaics and molecular electronics.