Janet Anders

It is known that the equilibrium properties of open classical systems that are strongly coupled to a heat bath are described by a set of thermodynamic potentials related to the system's Hamiltonian of mean force. By adapting this framework to a more general class of non-equilibrium states, we show that the equilibrium properties of the bath can be well-defined, even when the system is arbitrarily far from equilibrium and correlated with the bath. These states, which retain a notion of temperature, take the form of conditional equilibrium distributions. For out-of-equilibrium processes we show that the average entropy production quantifies the extent to which the system-bath state is driven away from the conditional equilibrium distribution. In addition, we show that the stochastic entropy production satisfies a generalised Crooks relation and can be used to quantify time-asymmetry of correlated non-equilibrium processes. These results naturally extend the familiar properties of entropy production in weakly-coupled systems to the strong coupling regime. Experimental measurements of the entropy production at strong coupling could be pursued using optomechanics or trapped ion systems, which allow strong coupling to be engineered.

The entanglement properties of the phase transition in a two dimensional harmonic lattice, similar to the one observed in recent ion trap experiments, are discussed both, for finite number of particles and thermodynamical limit. We show that for the ground state at the critical value of the trapping potential two entanglement measures, the negativity between two neighbouring sites and the block entropy for blocks of size 1, 2 and 3, change abruptly. Entanglement thus indicates quantum phase transitions in general; not only in the finite dimensional case considered in [Phys. Rev. Lett. {\bf 93}, 250404 (2004)]. Finally, we consider the thermal state and compare its exact entanglement with a temperature entanglement witness introduced in [Phys. Rev. A {\bf 77} 062102 (2008)].