Jason Nguyen

High-rate quantum low-density parity-check (qLDPC) codes are a leading candidate for fault-tolerant quantum computing. They feature higher encoding rates than planar alternatives such as the surface code, but their implementation often entails significant hardware hurdles like the need for long-range couplers. We leverage the flexibility of a trapped-ion quantum computer to demonstrate nine quantum error-correcting codes with starkly different qubit connectivity requirements on a single device without any hardware reconfiguration. These experiments span three families of quantum error-correcting codes: qLDPC codes, topological codes, and concatenated codes. With a qLDPC code encoding 4 logical qubits into 18 physical qubits, we achieve a logical error rate up to $9\times$ better than a previous demonstration of a similar code on superconducting solid-state qubits. Moreover, our implementation exhibits breakeven performance, with some instances achieving qubit lifetimes comparable to or slightly exceeding that of our trapped-ion qubits. We use a novel implementation of the optical-metastable-ground (OMG) architecture for addressable mid-circuit measurement and reset, which enables us to perform these experiments without any ion transport or dedicated coolant ions, requirements that typically consume a large fraction of the runtime or ion count of trapped-ion quantum computers.

Large quantum computers promise to solve some critical problems not solvable otherwise. However, modern quantum technologies suffer various imperfections such as control errors and qubit decoherence, inhibiting their potential utility. The overheads of quantum error correction are too great for near-term quantum computers, whereas error-mitigation strategies that address specific device imperfections may lose relevance as devices improve. To enhance the performance of quantum computers with high-quality qubits, we introduce a strategy based on symmetrization and nonlinear aggregation. On a commercial trapped-ion quantum computer, it improves performance of multiple practical algorithms by 100x with no qubit or gate overhead.

Variational quantum eigensolvers (VQE) are among the most promising approaches for solving electronic structure problems on near-term quantum computers. A critical challenge for VQE in practice is that one needs to strike a balance between the expressivity of the VQE ansatz versus the number of quantum gates required to implement the ansatz, given the reality of noisy quantum operations on near-term quantum computers. In this work, we consider an orbital-optimized pair-correlated approximation to the unitary coupled cluster with singles and doubles (uCCSD) ansatz and report a highly efficient quantum circuit implementation for trapped-ion architectures. We show that orbital optimization can recover significant additional electron correlation energy without sacrificing efficiency through measurements of low-order reduced density matrices (RDMs). In the dissociation of small molecules, the method gives qualitatively accurate predictions in the strongly-correlated regime when running on noise-free quantum simulators. On IonQ's Harmony and Aria trapped-ion quantum computers, we run end-to-end VQE algorithms with up to 12 qubits and 72 variational parameters - the largest full VQE simulation with a correlated wave function on quantum hardware. We find that even without error mitigation techniques, the predicted relative energies across different molecular geometries are in excellent agreement with noise-free simulators.

Amplitude estimation is a fundamental quantum algorithmic primitive that enables quantum computers to achieve quadratic speedups for a large class of statistical estimation problems, including Monte Carlo methods. The main drawback from the perspective of near term hardware implementations is that the amplitude estimation algorithm requires very deep quantum circuits. Recent works have succeeded in somewhat reducing the necessary resources for such algorithms, by trading off some of the speedup for lower depth circuits, but high quality qubits are still needed for demonstrating such algorithms. Here, we report the results of an experimental demonstration of amplitude estimation on a state-of-the-art trapped ion quantum computer. The amplitude estimation algorithms were used to estimate the inner product of randomly chosen four-dimensional unit vectors, and were based on the maximum likelihood estimation (MLE) and the Chinese remainder theorem (CRT) techniques. Significant improvements in accuracy were observed for the MLE based approach when deeper quantum circuits were taken into account, including circuits with more than ninety two-qubit gates and depth sixty, achieving a mean additive estimation error on the order of $10^{-2}$. The CRT based approach was found to provide accurate estimates for many of the data points but was less robust against noise on average. Last, we analyze two more amplitude estimation algorithms that take into account the specifics of the hardware noise to further improve the results.

Modeling joint probability distributions is an important task in a wide variety of fields. One popular technique for this employs a family of multivariate distributions with uniform marginals called copulas. While the theory of modeling joint distributions via copulas is well understood, it gets practically challenging to accurately model real data with many variables. In this work, we design quantum machine learning algorithms to model copulas. We show that any copula can be naturally mapped to a multipartite maximally entangled state. A variational ansatz we christen as a `qopula' creates arbitrary correlations between variables while maintaining the copula structure starting from a set of Bell pairs for two variables, or GHZ states for multiple variables. As an application, we train a Quantum Generative Adversarial Network (QGAN) and a Quantum Circuit Born Machine (QCBM) using this variational ansatz to generate samples from joint distributions of two variables for historical data from the stock market. We demonstrate our generative learning algorithms on trapped ion quantum computers from IonQ for up to 8 qubits and show that our results outperform those obtained through equivalent classical generative learning. Further, we present theoretical arguments for exponential advantage in our model's expressivity over classical models based on communication and computational complexity arguments.

Ion-trap quantum computers offer a large number of possible qubit couplings, each of which requires individual calibration and can be misconfigured. To enhance the duty cycle of an ion trap, we develop a strategy that diagnoses individual miscalibrated couplings using only log-many tests. This strategy is validated on a commercial ion-trap quantum computer, where we illustrate the process of debugging faulty quantum gates. Our methodology provides a scalable pathway towards fault detections on a larger scale ion-trap quantum computers, confirmed by simulations up to 32 qubits.