Ming Li

High-fidelity operation of quantum computers requires precise knowledge of the physical system through characterization. For motion-mediated entanglement generation in trapped ions, it is crucial to have precise knowledge of the motional-mode parameters such as the mode frequencies and the Lamb-Dicke parameters. Unfortunately, the state-of-the-art mode-characterization schemes do not easily render the mode parameters in a sufficiently scalable and accurate fashion, due to the unwanted excitation of adjacent modes in the frequency space when targeting a single mode, an effect known as the \textit{cross-mode coupling}. Here, we develop an alternative scheme that leverages the degrees of freedom in pulse design for the characterization experiment such that the effects of the cross-mode coupling is actively silenced. Further, we devise stabilization methods to accurately characterize the Lamb-Dicke parameters even when the mode frequencies are not precisely known due to experimental drifts or characterization inaccuracies. We extensively benchmark our scheme in simulations of a three-ion chain and discuss the parameter regimes in which the shaped pulses significantly outperform the traditional square pulses.

Two-qubit gates are a fundamental constituent of a quantum computer and typically its most challenging operation. In a trapped-ion quantum computer, this is typically implemented with laser beams which are modulated in amplitude, frequency, phase, or a combination of these. The required modulation becomes increasingly more complex as the quantum computer becomes larger, complicating the control hardware design. Here, we develop a simple method to essentially remove the pulse-modulation complexity by engineering the normal modes of the ion chain. We experimentally demonstrate the required mode engineering in a three ion chain. This opens up the possibility to trade off complexity between the design of the trapping fields and the optical control system, which will help scale the ion trap quantum computing platform.

To achieve high-fidelity operations on a large-scale quantum computer, the parameters of the physical system must be efficiently characterized with high accuracy. For trapped ions, the entanglement between qubits are mediated by the motional modes of the ion chain, and thus characterizing the motional-mode parameters becomes essential. In this paper, we develop and explore physical models that accurately predict both magnitude and sign of the Lamb-Dicke parameters when the modes are probed {\it in parallel}. We further devise an advanced characterization protocol that shortens the characterization time by more than an order of magnitude, when compared to that of the conventional method that only uses mode spectroscopy. We discuss potential ramifications of our results to the development of a scalable trapped-ion quantum computer, viewed through the lens of system-level resource trade offs.

A global race towards developing a gate-based, universal quantum computer that one day promises to unlock the never before seen computational power has begun and the biggest challenge in achieving this goal arguably is the quality implementation of a two-qubit gate. In a trapped-ion quantum computer, one of the leading quantum computational platforms, a two-qubit gate is typically implemented by modulating the individual addressing beams that illuminate the two target ions, which, together with others, form a linear chain. The required modulation, expectedly so, becomes increasingly more complex, especially as the quantum computer becomes larger and runs faster, complicating the control hardware design. Here, we develop a simple method to essentially remove the pulse-modulation complexity at the cost of engineering the normal modes of the ion chain. We demonstrate that the required mode engineering is possible for a three ion chain, even with a trapped-ion quantum computational system built and optimized for a completely different mode of operations. This indicates that a system, if manufactured to target specifically for the mode-engineering based two-qubit gates, would readily be able to implement the gates without significant additional effort.

Quantum computing is currently limited by the cost of two-qubit entangling operations. In order to scale up quantum processors and achieve a quantum advantage, it is crucial to economize on the power requirement of two-qubit gates, make them robust to drift in experimental parameters, and shorten the gate times. In this paper, we present two methods, one exact and one approximate, to construct optimal pulses for entangling gates on a pair of ions within a trapped ion chain, one of the leading quantum computing architectures. Our methods are direct, non-iterative, and linear, and can construct gate-steering pulses requiring less power than the standard method by more than an order of magnitude in some parameter regimes. The power savings may generally be traded for reduced gate time and greater qubit connectivity. Additionally, our methods provide increased robustness to mode drift. We illustrate these trade-offs on a trapped-ion quantum computer.

We derive a general Hamiltonian that governs the interaction between an $N$-ion chain and an externally controlled laser field, where the ion motion is quantized and the laser field is considered beyond the plane-wave approximation. This general form not only explicitly includes terms that are used to drive ion-ion entanglement, but also a series of unwanted terms that can lead to quantum gate infidelity. We demonstrate the power of our expressivity of the general Hamiltonian by singling out the effect of axial mode heating and confirm this experimentally. We discuss pathways forward in furthering the trapped-ion quantum computational quality, guiding hardware design decisions.

We present experimental evidence of charge exchange between laser-cooled potassium $^{39}$K atoms and calcium $^{40}$Ca$^+$ ions in a hybrid atom-ion trap and give quantitative theoretical explanations for the observations. The $^{39}$K atoms and $^{40}$Ca$^+$ ions are held in a magneto-optical (MOT) and a linear Paul trap, respectively. Fluorescence detection and high resolution time of flight mass spectra for both species are used to determine the remaining number of $^{40}$Ca$^+$ ions, the increasing number of $^{39}$K$^+$ ions, and $^{39}$K number density as functions of time. Simultaneous trap operation is guaranteed by alternating periods of MOT and $^{40}$Ca$^+$ cooling lights, thus avoiding direct ionization of $^{39}$K by the $^{40}$Ca$^+$ cooling light. We show that the K-Ca$^+$ charge-exchange rate coefficient increases linearly from zero with $^{39}$K number density and, surprisingly, the fraction of $^{40}$Ca$^+$ ions in the 4p\,$^2$P$_{1/2}$ electronically-excited state. Combined with our theoretical analysis, we conclude that these data can only be explained by a process that starts with a potassium atom in its electronic ground state and a calcium ion in its excited 4p\,$^2$P$_{1/2}$ state producing ground-state $^{39}$K$^+$ ions and metastable, neutral Ca\,(3d4p$^3$P$_1$) atoms, releasing only 150 cm$^{-1}$ equivalent relative kinetic energy. Charge-exchange between either ground- or excited-state $^{39}$K and ground-state $^{40}$Ca$^+$ is negligibly small as no energetically-favorable product states are available. Our experimental and theoretical rate coefficients of $9\times10^{-10}$ cm$^3$/s are in agreement given the uncertainty budgets.

An important physical process unique to neutral-ion systems is the charge-transfer (CT) reaction. Here, we present measurements of and models for CT processes between co-trapped ultracold Ca atoms and Yb ions under well-controlled conditions. The theoretical analysis reveals the existence of three reaction mechanisms when lasers from a magneto-optical trap (MOT) and an additional catalyst laser are present. Besides the direct CT involving existent excited Ca population in the MOT, the second pathway is controlled by MOT-induced CT, whereas the third one mostly involves the additional red-detuned laser.