R. Blümel

We present experimental measurements of the steady-state ion number in a linear Paul trap (LPT) as a function of the ion-loading rate. These measurements, taken with (a) constant Paul trap stability parameter $q$, (b) constant radio-frequency (rf) amplitude, or (c) constant rf frequency, show nonlinear behavior. At the loading rates achieved in this experiment, a plot of the steady-state ion number as a function of loading rate has two regions: a monotonic rise (region I) followed by a plateau (region II). Also described are simulations and analytical theory which match the experimental results. Region I is caused by rf heating and is fundamentally due to the time dependence of the rf Paul-trap forces. We show that the time-independent pseudopotential, frequently used in the analytical investigation of trapping experiments, cannot explain region I, but explains the plateau in region II and can be used to predict the steady-state ion number in that region. An important feature of our experimental LPT is the existence of a radial cut-off $\hat R_{\rm cut}$ that limits the ion capacity of our LPT and features prominently in the analytical and numerical analysis of our LPT-loading results. We explain the dynamical origin of $\hat R_{\rm cut}$ and relate it to the chaos border of the fractal of non-escaping trajectories in our LPT. We also present an improved model of LPT ion-loading as a function of time.

The standard second-order pseudo-oscillator potential used in many analytical investigations of the properties of ions stored in a Paul trap has serious limitations. In this paper we show that ion-crystal configurations exhibited by 2, 3, and 4 simultaneously stored ions in a Paul trap are not predicted by the standard pseudo-oscillator potential, but are all captured qualitatively and quantitatively by an extended pseudopotential derived in this paper. The power of our extended pseudopotential extends in particular to the prediction of the border lines between different crystal configurations (morphologies) in the Paul trap's $a$, $q$ stability diagram. In the three- and four-ion cases, several of the ion-crystal structures predicted by our improved pseudopotential have never been observed experimentally before. We present them here as a challenge for experiments.

We predict that the steady-state ion number $N_s$ for radio-frequency (rf) traps, loaded at a rate of $λ$ particles per unit time, shows universal non-monotonic behavior as a function of loading rate $λ$. The shape of $N_s(λ)$, characterized by four dynamical regions, is universal in the sense that it is predicted to manifest itself in all rf traps independently of the details of their construction. For $λ\ll$ 1 particles / rf cycle (Region I), as expected, $N_s(λ)$ increases monotonically with $λ$. However, contrary to intuition, at intermediate $λ\sim 1$ particles / rf cycle (Region II), $N_s(λ)$ reaches a maximum, followed by a minimum of $N_s(λ)$ (Region III). For $λ\gg 1$ particles / rf cycle (Region IV), $N_s(λ)$ again rises monotonically. In Region IV numerical simulations, analytical calculations, and experiments show $N_s(λ)\sim λ^{2/3}$. We confirm this prediction experimentally with MOT-loaded Na$^+$ ions stored in a hybrid ion-neutral trap.

We present measurements of the total elastic and resonant charge-exchange ion-atom collision rate coefficient $k_\mathrm{ia}$ of cold sodium (\ce{Na}) with optically-dark low energy \ce{Na+} ions in a hybrid ion-neutral trap. To determine $k_\mathrm{ia}$, we measured the trap loading and loss from both a \ce{Na} magneto-optical trap (MOT) and a linear radio frequency quadrupole Paul trap. We found the total rate coefficient to be $7.4 \pm 1.9 \times 10^{-8}$ cm$^3$/s for the type I \ce{Na} MOT immersed within an $\approx 140$ K ion cloud and $1.10 \pm 0.25 \times 10^{-7}$ cm$^3$/s for the type II \ce{Na} MOT within an $\approx 1070$ K ion cloud. Our measurements show excellent agreement with previously reported theoretical fully quantal \textit{ab initio} calculations. In the process of determining the total rate coefficient, we demonstrate that a MOT can be used to probe an optically dark ion cloud's spatial distribution within a hybrid trap.