R. F. Garcia Ruiz

Molecules containing short-lived isotopes, namely radioactive molecules, are among the most promising candidates for probing new physics beyond the Standard Model, although their production and spectroscopic measurements remain technically challenging. Here, we demonstrate an integrated methodology that combines formation of molecular ion beams in a radiofrequency quadrupole cooler-buncher with collinear laser spectroscopy. As a proof-of-principle experiment, we successfully produce molecular ions such as $\rm BaF^+$ and $\rm YbF^+$ via in-trap ion-molecule reactions and perform high-resolution laser spectroscopy of the target molecule $\rm ^{138}BaF$. Vibrational and rotational structures of $\rm ^{138}BaF$ across different electronic states are obtained using resonance-enhanced multiphoton ionization schemes, confirming the feasibility of the proposed methodology. This work establishes a practical route for future formation and spectroscopic studies of short-lived radioactive molecules, such as those containing $\rm ^{225}Ra$, at radioactive ion beam facilities.

A wide range of quantum sensing technologies are rapidly being integrated into the experimental portfolio of the high energy physics community. Here we focus on sensing with atomic interferometers; mechanical devices read out with optical or microwave fields; precision spectroscopic methods with atomic, nuclear, and molecular systems; and trapped atoms and ions. We give a variety of detection targets relevant to particle physics for which these systems are uniquely poised to contribute. This includes experiments at the precision frontier like measurements of the electron dipole moment and electromagnetic fine structure constant and searches for fifth forces and modifications of Newton's law of gravity at micron-to-millimeter scales. It also includes experiments relevant to the cosmic frontier, especially searches for gravitional waves and a wide variety of dark matter candidates spanning heavy, WIMP-scale, light, and ultra-light mass ranges. We emphasize here the need for more developments both in sensor technology and integration into the broader particle physics community.