Sunghyun Kim

We investigate the formation of a barrier to evaporation that develops when levitated nanoscale Au nanoparticles are exposed to pulses of 532 nm laser radiation in a high vacuum (pressure $p=10^{-8}-10^{-7}$ Torr) environment. Our data are derived from precision measurements of the charge to mass ratio ($Q/M$) of $\sim$200 nm diameter Au particles confined in a quadrupole ion trap. We characterize the development of the barrier over time as the particle is repeatedly heated with laser pulses and determine the impact of variations of the interval between pulses and of exposure to several gases added to the vacuum chamber. We observe a slow increase in the mass of particles upon prolonged exposure to the vacuum, which we attribute to the growth of a barrier layer. For particles that have acquired a barrier during exposure to CO, we observe a rapid decrease in their mass upon subsequent exposure to O$_2$. These findings are consistent with the growth and subsequent oxidation of a graphene layer on the Au that forms the barrier to evaporation. However, we have not found that the rate of formation of the barrier depends on the pressure of carbon-containing gases (CO, C$_2$H$_4$, CO$_2$) we have added to the chamber. We hypothesize that a rare surface state on the solid Au particle catalyzes the reaction that introduces C to the particle. Repeated laser pulse heating is necessary--either to enable diffusion away from this state or to create fresh states that allow continued C uptake--to facilitate the growth of the surface graphene layer.

We describe apparatus and experimental procedures for high stability precision measurements of levitated nanoscale particles confined in an ion trap in high vacuum. We discuss methods for particle generation and collection using electrospray emission, for rapid characterization by direct imaging of thermal motion, and for transfer of the particle from the trap where it is collected to a separate analysis trap in order to achieve better vacuum and lower noise. In the analysis trap at high vacuum (pressure $p\simeq10^{-8}$ Torr), we employ thermostatic control of the trapped particle oscillation amplitudes, allowing long-term, precision measurements of oscillation frequencies, from which the charge to mass ratio ($Q/M$) can be deduced. Under these conditions, we achieve $Q/M$ measurement precision approaching $10^{-5}$. This sensitivity will enable, for example, investigations of the surface chemistry of $μ$m-scale levitated materials in ultra-high vacuum environments.