Tommaso Calarco

Hybrid systems of ultracold atoms and trapped ions or Rydberg atoms can be useful for quantum simulation purposes. By tuning the geometric arrangement of the impurities it is possible to mimic solid state and molecular systems. Here we study a single trapped atom interacting with a set of arbitrarily arranged static impurities and show that the problem admits an analytical solution. We analyze in detail the case of two impurities, finding multiple trap-induced resonances which can be used for entanglement generation. Our results serve as a building block for the studies of quantum dynamics of complex systems.

Hybrid systems of laser-cooled trapped ions and ultracold atoms combined in a single experimental setup have recently emerged as a new platform for fundamental research in quantum physics. This paper reviews the theoretical and experimental progress in research on cold hybrid ion-atom systems which aim to combine the best features of the two well-established fields. We provide a broad overview of the theoretical description of ion-atom mixtures and their applications, and report on advances in experiments with ions trapped in Paul or dipole traps overlapped with a cloud of cold atoms, and with ions directly produced in a Bose-Einstein condensate. We start with microscopic models describing the electronic structure, interactions, and collisional physics of ion-atom systems at low and ultralow temperatures, including radiative and non-radiative charge transfer processes and their control with magnetically tunable Feshbach resonances. Then we describe the relevant experimental techniques and the intrinsic properties of hybrid systems. In particular, we discuss the impact of the micromotion of ions in Paul traps on ion-atom hybrid systems. Next, we review recent proposals for using ions immersed in ultracold gases for studying cold collisions, chemistry, many-body physics, quantum simulation, and quantum computation and their experimental realizations. In the last part we focus on the formation of molecular ions via spontaneous radiative association, photoassociation, magnetoassociation, and sympathetic cooling. We discuss applications and prospects of cold molecular ions for cold controlled chemistry and precision spectroscopy.

We propose a protocol for measurement of the phonon number distribution of a harmonic oscillator based on selective mapping to a discrete spin-1/2 degree of freedom. We consider a system of a harmonically trapped ion, where a transition between two long lived states can be driven with resolved motional sidebands. The required unitary transforms are generated by amplitude-modulated polychromatic radiation fields, where the time-domain ramps are obtained from numerical optimization by application of the Chopped RAndom Basis (CRAB) algorithm. We provide a detailed analysis of the scaling behavior of the attainable fidelities and required times for the mapping transform with respect to the size of the Hilbert space. As one application we show how the mapping can be employed as a building block for experiments which require measurement of the work distribution of a quantum process.

We study the crossover from classical to quantum phase transitions at zero temperature within the framework of $φ^4$ theory. The classical transition at zero temperature can be described by the Landau theory, turning into a quantum Ising transition with the addition of quantum fluctuations. We perform a calculation of the transition line in the regime where the quantum fluctuations are weak. The calculation is based on a renormalization group analysis of the crossover between classical and quantum transitions, and is well controlled even for space-time dimensionality $D$ below 4. In particular, for $D=2$ we obtain an analytic expression for the transition line which is valid for a wide range of parameters, as confirmed by numerical calculations based on the Density Matrix Renormalization Group. This behavior could be tested by measuring the phase diagram of the linear-zigzag instability in systems of trapped ions or repulsively-interacting dipoles.

Ions of the same charge inside confining potentials can form crystalline structures which can be controlled by means of the ions density and of the external trap parameters. In particular, a linear chain of trapped ions exhibits a transition to a zigzag equilibrium configuration, which is controlled by the strength of the transverse confinement. Studying this phase transition in the quantum regime is a challenging problem, even when employing numerical methods to simulate microscopically quantum many-body systems. Here we present a compact analytical treatment to map the original long-range problem into a short-range quantum field theory on a lattice. We provide a complete numerical architecture, based on Density Matrix Renormalization Group, to address the effective quantum phi-four model. This technique is instrumental in giving a complete characterization of the phase diagram, as well as pinpoint the universality class of the criticality.

We propose and analyze a scheme for sympathetic cooling of the translational motion of polar molecules in an optical lattice, interacting one by one with laser-cooled ions in a radio-frequency trap. The energy gap between the excitation spectra of the particles in their respective trapping potentials is bridged by means of a parametric resonance, provided by the additional modulation of the RF field. We analyze two scenarios: simultaneous laser cooling and energy exchange between the ion and the molecule, and a scheme when these two processes take place separately. We calculate the lowest final energy of the molecule and the cooling rate depending on the amplitude of the parametric modulation. For small parametric modulation, the dynamics can be solved analytically within the rotating wave approximation.

Trapped, laser-cooled atoms and ions are quantum systems which can be experimentally controlled with an as yet unmatched degree of precision. Due to the control of the motion and the internal degrees of freedom, these quantum systems can be adequately described by a well known Hamiltonian. In this colloquium, we present powerful numerical tools for the optimization of the external control of the motional and internal states of trapped neutral atoms, explicitly applied to the case of trapped laser-cooled ions in a segmented ion-trap. We then delve into solving inverse problems, when optimizing trapping potentials for ions. Our presentation is complemented by a quantum mechanical treatment of the wavepacket dynamics of a trapped ion. Efficient numerical solvers for both time-independent and time-dependent problems are provided. Shaping the motional wavefunctions and optimizing a quantum gate is realized by the application of quantum optimal control techniques. The numerical methods presented can also be used to gain an intuitive understanding of quantum experiments with trapped ions by performing virtual simulated experiments on a personal computer. Code and executables are supplied as supplementary online material (http://kilian-singer.de/ent).

We study ultracold collisions of ions with neutral atoms in traps. Recently, ultracold atom-ion systems are becoming available in experimental setups, where their quantum states can be coherently controlled. This allows for an implementation of quantum information processing combining the advantages of charged and neutral particles. The state-dependent dynamics that is a necessary ingredient for quantum computation schemes is provided in this case by the short-range interaction forces depending on hyperfine states of both particles. In this work we develop a theoretical description of spin-state-dependent trapped atom-ion collisions in the framework of a Multichannel Quantum Defect Theory (MQDT) and formulate an effective single channel model that reduces the complexity of the problem. Based on this description we simulate a two-qubit phase gate between a Ba135+ ion and a Rb87 atom using a realistic combination of the singlet and triplet scattering lengths. We optimize and accelerate the gate process with the help of optimal control techniques. Our result is a gate fidelity 0.999 within 350 microseconds.