V. Vedral

Most non-equilibrium processes in thermodynamics are quantified only by inequalities, however the Jarzynski relation presents a remarkably simple and general equality relating non-equilibrium quantities with the equilibrium free energy, and this equality holds in both classical and quantum regimes. We report a single-spin test and confirmation of the Jarzynski relation in quantum regime using a single ultracold $^{40}Ca^{+}$ ion trapped in a harmonic potential, based on a general information-theoretic equality for a temporal evolution of the system sandwiched between two projective measurements. By considering both initially pure and mixed states, respectively, we verify, in an exact and fundamental fashion, the non-equilibrium quantum thermodynamics relevant to the mutual information and Jarzynski equality.

Here we respond to a comment [arXiv:1802.01382] submitted recently on 'Experimental Verification of a Jarzynski-Related Information-Theoretic Equality by a Single Trapped Ion' PRL 120 010601 (2018). We consider that the argument is the thermalization in a quantum system, which is different from the counterpart in conventional thermodynamics.

Quantum systems in mixed states can be unentangled and yet still correlated in a way that is not possible for classical systems. These correlations can be quantified by the quantum discord and might provide a resource for certain mixed-state quantum information processing tasks. Here we report on the generation of discordant states of two trapped atomic ions via Markovian decoherence processes. While entanglement is strictly non-increasing under such operations, discord can be generated in various forms. Firstly we show that, starting from two classically correlated qubits, it is possible to generate discord by applying decoherence to just one of them. Secondly, even when starting with completely uncorrelated systems, we show that discord can be generated via classically correlated decoherence processes. Finally, the Werner states are created. The generated states can be used as a resource state for quantum information transmission and could be readily extended to more ions.

We propose an experimental scheme to verify the quantum non-equilibrium fluctuation relations using current technology. Specifically, we show that the characteristic function of the work distribution for a non-equilibrium quench of a general quantum system can be extracted from Ramsey interferometry of a single probe qubit. Our scheme paves the way for the full characterisation of non-equilibrium processes in a variety of complex quantum systems ranging from single particles to many-body atomic systems and spin chains. We demonstrate our idea using a time-dependent quench of the motional state of a trapped ion, where the internal pseudo-spin provides a convenient probe qubit.

Quantum information processing rests on our ability to manipulate quantum superpositions through coherent unitary transformations, and to establish entanglement between constituent quantum components of the processor. The quantum information processor (a linear ion trap, or a cavity confining the radiation field for example) exists in a dissipative environment. We discuss ways in which entanglement can be established within such dissipative environments. We can even make use of a strong interaction of the system with its environment to produce entanglement in a controlled way.

We propose a scheme for measuring the Berry phase in the vibrational degree of freedom of a trapped ion. Starting from the ion in a vibrational coherent state we show how to reverse the sign of the coherent state amplitude by using a purely geometric phase. This can then be detected through the internal degrees of freedom of the ion. Our method can be applied to preparation of Schrödinger cat states.

Quantum information processing rests on our ability to manipulate quantum superpositions through coherent unitary transformations. In reality the quantum information processor (a linear ion trap, or cavity qed implementation for example) exists in a dissipative environment. Dephasing, and other technical sources of noise, as well as more fundamental sources of dissipation severely restrict quantum processing capabilities. The strength of the coherent coupling needed to implement quantum logic is not always independent of dissipation. The limitations these dissipative influences present will be described and the need for efficient error correction noted. Even if long and involved quantum computations turn out to be hard to realize, one can perform interesting manipulations of entanglement involving only a few gates and qubits, of which we give examples. Quantum communication also involves manipulations of entanglement which are simpler to implement than elaborate computations. We briefly analyse the notion of the capacity of a quantum communication channel.