Weiwei Zhang

The slowest Liouvillian mode often bottlenecks the relaxation of an open quantum system to its steady state. Standard strategies circumvent this bottleneck by selecting special initial states or engineering the dissipator. Here we show that neither is necessary. We introduce a pre-dissipative geometric steering protocol that reshapes any given pure or mixed state before relaxation begins -- coherent rotations interleaved with nonselective projective measurements -- at fixed Lindblad generator. By steering the state's Bloch direction along geodesic paths, the protocol suppresses its overlap with the slowest Liouvillian modes. The prepared state then starts farther from equilibrium yet relaxes faster, realizing the quantum Mpemba effect, whenever two computable conditions hold: reduced slow-mode overlap and a larger initial distance to stationarity. Our framework treats real and complex spectral gaps uniformly, and we demonstrate robust Mpemba acceleration in driven qubit and multiqubit systems using operations available in trapped-ion and superconducting platforms.

Besides buckminsterfullerene (C60), other fullerenes and their derivatives may also reside in space. In this work, we study the formation and photo-dissociation processes of astronomically relevant fullerene/anthracene (C14H10) cluster cations in the gas phase. Experiments are carried out using a quadrupole ion trap (QIT) in combination with time-of-flight (TOF) mass spectrometry. The results show that fullerene (C60, and C70)/anthracene (i.e., [(C14H10)nC60]+ and [(C14H10)nC70]+), fullerene (C56 and C58)/anthracene (i.e., [(C14H10)nC56]+ and [(C14H10)nC58]+) and fullerene (C66 and C68)/anthracene (i.e., [(C14H10)nC66]+ and [(C14H10)nC68]+) cluster cations, are formed in the gas phase through an ion-molecule reaction pathway. With irradiation, all the fullerene/anthracene cluster cations dissociate into mono$-$anthracene and fullerene species without dehydrogenation. The structure of newly formed fullerene/anthracene cluster cations and the bonding energy for these reaction pathways are investigated with quantum chemistry calculations. Our results provide a growth route towards large fullerene derivatives in a bottom-up process and insight in their photo-evolution behavior in the ISM, and clearly, when conditions are favorable, fullerene/PAH clusters can form efficiently. In addition, these clusters (from 80 to 154 atoms or ~ 2 nm in size) offer a good model for understanding the physical-chemical processes involved in the formation and evolution of carbon dust grains in space, and provide candidates of interest for the DIBs that could motivate spectroscopic studies.