Y. Y. Xu

We propose how to explore the Franck-Condon (FC) physics via a single ion confined in a spin-dependent potential, formed by the combination of a Paul trap and a magnetic field gradient. The correlation between electronic and vibrational degrees of freedom, called as electron-vibron coupling, is induced by a nonzero gradient. For a sufficiently strong electron-vibron coupling, the FC blockade of low-lying vibronic transitions takes place. We analyze the feasibility of observing the FC physics in a single trapped ion, and demonstrate various potential applications of the ionic FC physics in quantum state engineering and quantum information processing.

Physical systems must fulfill a number of conditions to qualify as useful quantum bits (qubits) for quantum information processing, including ease of manipulation, long decoherence times, and high fidelity readout operations. Since these conditions are hard to satisfy with a single system, it may be necessary to combine different degrees of freedom. Here we discuss a possible system, based on electronic and nuclear spin degrees of freedom in trapped ions. The nuclear spin yields long decoherence times, while the electronic spin, in a magnetic field gradient, provides efficient manipulation, and the optical transitions of the ions assure a selective and efficient initialization and readout.