Charles W Clark

Ising models, and the physical systems described by them, play a central role in generating entangled states for use in quantum metrology and quantum information. In particular, ultracold atomic gases, trapped ion systems, and Rydberg atoms realize long-ranged Ising models, which even in the absence of a transverse field can give rise to highly non-classical dynamics and long-range quantum correlations. In the first part of this paper, we present a detailed theoretical framework for studying the dynamics of such systems driven (at time t=0) into arbitrary unentangled non-equilibrium states, thus greatly extending and unifying the work of Ref. [1]. Specifically, we derive exact expressions for closed-time-path ordered correlation functions, and use these to study experimentally relevant observables, e.g. Bloch vector and spin-squeezing dynamics. In the second part, these correlation functions are then used to derive closed-form expressions for the dynamics of arbitrary spin-spin correlation functions in the presence of both T_1 (spontaneous spin relaxation/excitation) and T_2 (dephasing) type decoherence processes. Even though the decoherence is local, our solution reveals that the competition between Ising dynamics and T_1 decoherence gives rise to an emergent non-local dephasing effect, thereby drastically amplifying the degradation of quantum correlations. In addition to identifying the mechanism of this deleterious effect, our solution points toward a scheme to eliminate it via measurement-based coherent feedback.

The blackbody radiation (BBR) shift of the 5s - 4d_{5/2} clock transition in 88Sr+ is calculated to be 0.250(9) Hz at room temperature, T=300K, using the relativistic all-order method where all single and double excitations of the Dirac-Fock wave function are included to all orders of perturbation theory. The BBR shift is a major component in the uncertainty budget of the optical frequency standard based on the 88Sr+ trapped ion. The scalar polarizabilities of the 5s and 4d_{5/2} levels, as well as the tensor polarizability of the 4d_{5/2} level, are presented together with the evaluation of their uncertainties. The lifetimes of the 4d_{3/2}, 4d_{5/2}, 5p_{1/2}, and 5p_{3/2} states are calculated and compared with experimental values.

Stark shifts of potassium and rubidium D1 lines have been measured with high precision by Miller et al [1]. In this work, we combine these measurements with our all-order calculations to determine the values of the electric-dipole matrix elements for the 4p_j-3d_j' transitions in K and for the 5p_j-4d_j' transitions in Rb to high precision. The 4p_1/2-3d_3/2 and 5p_1/2-4d_3/2 transitions contribute on the order of 90% to the respective polarizabilities of the np_1/2 states in K and Rb, and the remaining 10% can be accurately calculated using the relativistic all-order method. Therefore, the combination of the experimental data and theoretical calculations allows us to determine the np-(n-1)d matrix elements and their uncertainties. We compare these values with our all-order calculations of the np-(n-1)d matrix elements in K and Rb for a benchmark test of the accuracy of the all-order method for transitions involving nd states. Such matrix elements are of special interest for many applications, such as determination of magic wavelengths in alkali-metal atoms for state-insensitive cooling and trapping and determination of blackbody radiation shifts in optical frequency standards with ions.