Guang-Can Guo

Hybrid quantum networks offer a promising architecture for scalable quantum information processing and a future quantum internet, as they can combine the complementary strengths of disparate physical platforms. While single-atom systems provide deterministic quantum logic gates, atomic ensembles enable large-capacity quantum storage. However, generating entanglement between such heterogeneous systems has remained an open challenge, primarily due to fundamental spectral mismatches and system complexity. Here, we demonstrate a hybrid quantum network that entangles a single trapped $\mathrm{^{171}Yb^{+}}$ ion and a quantum memory based on $\rm ^{153}Eu^{3+}\colon\!Y_2SiO_5$ crystal over a 75-m separation. Using polarization-maintaining quantum frequency conversion, we map spin-photon entanglement onto a hybrid entanglement between a single spin qubit and a collective excitation of the quantum memory. The resulting entangled state achieves a fidelity of $(89.21 \pm 2.23)\%$ and violates the CHSH-Bell inequality by 6 standard deviations ($S = 2.328 \pm 0.055$), confirming nonlocality between two heterogeneous nodes. This work establishes entanglement between a quantum processing module with a multiplexed quantum memory node, representing a key step toward a scalable, multifunctional quantum internet.

Quantum information processing platforms based on array of matter qubits, such as neutral atoms, trapped ions, and quantum dots, face significant challenges in scalable addressing and readout as system sizes increase. Here, we propose the "Volcano" architecture that establishes a new quantum processing unit implementation method based on optical channel mapping on a arbitrarily arranged static qubit array. To support the feasibility of Volcano architecture, we show a proof-of-principle demonstration by employing a photonic chip that leverages custom-designed three-dimensional waveguide structures to transform one-dimensional beam arrays into arbitrary two-dimensional output patterns matching qubit array geometries. We demonstrate parallel and independent control of 49-channel with negligible crosstalk and high uniformity. This architecture addresses the challenges in scaling up quantum processors, including both the classical link for parallel qubit control and the quantum link for efficient photon collection, and holds the potential for interfacing with neutral atom arrays and trapped ion crystals, as well as networking of heterogeneous quantum systems.

Trapped ions in micro-cavities constitute a key platform for advancing quantum information processing and quantum networking. By providing an efficient light-matter interface within a compact architecture, they serve as highly efficient quantum nodes with strong potential for scalable quantum network. However, in such systems, ion trapping stability is often compromised by surface charging effects, and nearby dielectric materials are known to cause a dramatic increase in the ion heating rate by several orders of magnitude. These challenges significantly hinder the practical implementation of ion trap systems integrated with micro-cavities. To overcome these limitations, we present the design and fabrication of metal-shielded micro-cavity mirrors, enabling the stable realization of ion trap systems integrated with micro cavities. Using this method, we constructed a needle ion trap integrated with fiber Fabry-Perot cavity and successfully achieved stable trapping of a single ion within the cavity. The measured ion heating rate was reduced by more than an order of magnitude compared with unshielded configurations. This work establishes a key technique toward fully integrated ion-photon interfaces for scalable quantum network.

The construction of entangling gates with individual addressing capability represents a crucial approach for implementing quantum computation in trapped ion crystals. Conventional entangling gate schemes typically rely on laser beam wave vectors to couple the ions' spin and motional degrees of freedom. Here, we experimentally demonstrate an alternative method that employs a polarization gradient field generated by a tightly focused laser beam, previously proposed as a Magnus-type quantum logic gate. Using this technique, we perform Raman operations on nuclear spin qubits encoded in 171Yb+ ions, generating spin-dependent forces along axial motional modes in a linear trap. By utilizing an acousto-optic deflector to create arbitrary spot pairs for individual ion addressing in two-ion (four-ion) chains, we achieve MS gates with fidelities exceeding 98.5% (97.2%). Further improvements in numerical aperture and laser power could reduce gate durations while enhancing fidelity. This method is compatible with, and can significantly simplify, optical tweezer gate proposals, where motional mode engineering enables scalable trapped-ion quantum computation. The technique can be extended to two-dimensional ion crystals, representing a key step toward large-scale trapped-ion quantum processors.

The quantum to classical transition (QCT) is one of the central mysteries in quantum physics. This process is generally interpreted as state collapse from measurement or decoherence from interacting with the environment. Here we define the quantumness of a Hamiltonian by the free energy difference between its quantum and classical descriptions, which vanishes during QCT. We apply this criterion to the many-body Rabi model and study its scaling law across the phase transition, finding that not only the temperature and Planck constant, but also all the model parameters are important for this transition. We show that the Jaynes-Cummings and anti Jaynes-Cummings models exhibit greater quantumness than the Rabi model. Moreover, we show that the rotating wave and anti-rotating wave terms in this model have opposite quantumness in QCT. We demonstrate that the quantumness may be enhanced or suppressed at the critical point. Finally, we estimate the quantumness of the Rabi model in current trapped ion experiments. The quantumness provides an important tool to characterize the QCT in a vast number of many-body models.

Advances in research such as quantum information and quantum chemistry require subtle methods for trapping particles (including ions, neutral atoms, molecules, etc.). Here we propose a hybrid ion trapping method by combining a Paul trap with optical tweezers. The trap combines the advances of the deep-potential feature for the Paul trap and the micromotion-free feature for the optical dipole trap. By modulating the optical-dipole trap synchronously with the radio frequency voltage of the Paul trap, the alternating electrical force in the trap center is fully counteracted, and the micromotion temperature of a cold trapped ion can reach the order of nK while the trap depth is beyond 300K. These features will enable cold collisions between an ion and an atom in the $s$-wave regime and stably trap the produced molecular ion in the cold hybrid system. This will provide a unique platform for probing the interactions between the ions and the surrounding neutral particles and enable the investigation of new reaction pathways and reaction products in the cold regime.

Large-scale programmable trapped ion hardware, featuring high gate fidelity and long coherence times, is promising for realizing a practical fault-tolerant quantum computer (FTQC). However, individual addressing (IA) methods, which are important for implementing programmable gates in near-term quantum devices, can lead to undesired errors between the target ions and neighboring ions. In this work, we present a low-crosstalk optical addressing system based on multiple optical objectives and acousto-optic deflectors (AODs) with a symmetrical configuration. Two counter-propagating Raman operation beams are both tightly focused, generating an overlapping spot with a waist radius of approximately $1~\upmu\mathrm{m}$, to address the target ion. As a result, IA crosstalk, characterized by Rabi rate crosstalk on the spectator ion, is measured to be $1.19(5)\times10^{-3}$, with the two ions separated by approximately 5.5~$\upmu\mathrm{m}$. This low-crosstalk optical addressing system holds promise for high-fidelity entangling operations, and the symmetrically-configured AODs in our method can be readily extended to two dimensions to address a two-dimensional ion crystal.

Quantum networks play an extremely important role in quantum information science, with application to quantum communication, computation, metrology and fundamental tests. One of the key challenges for implementing a quantum network is to distribute entangled flying qubits to spatially separated nodes, at which quantum interfaces or transducers map the entanglement onto stationary qubits. The stationary qubits at the separated nodes constitute quantum memories realized in matter while the flying qubits constitute quantum channels realized in photons. Dedicated efforts around the world for more than twenty years have resulted in both major theoretical and experimental progress towards entangling quantum nodes and ultimately building a global quantum network. Here, we review the development of quantum networks and the experimental progress over the past two decades leading to the current state of the art for generating entanglement of quantum nodes based on various physical systems such as single atoms, cold atomic ensembles, trapped ions, diamonds with Nitrogen-Vacancy centers, solid-state host doped with rare-earth ions, etc. Along the way we discuss the merits and compare the potential of each of these systems towards realizing a quantum network.

In cold atomic systems, fast and high-resolution microscopy of individual atoms is crucial, since it can provide direct information on the dynamics and correlations of the system. Here, we demonstrate nanosecond-scale two-dimensional stroboscopic pictures of a single trapped ion beyond the optical diffraction limit, by combining the main idea of ground-state depletion microscopy with quantum state transition control in cold atoms. We achieve a spatial resolution up to 175~nm using an NA = 0.1 objective in the experiment, which represents a more than tenfold improvement compared with direct fluorescence imaging. To show the potential of this method, we apply it to observe the secular motion of the trapped ion, we demonstrate a temporal resolution up to 50~ns with a displacement detection sensitivity of 10~nm. Our method provides a powerful tool for probing particle positions, momenta, and correlations, as well as their dynamics in cold atomic systems.

The non-trivial zeros of the Riemann zeta function are central objects in number theory. In particular, they enable one to reproduce the prime numbers. They have also attracted the attention of physicists working in Random Matrix Theory and Quantum Chaos for decades. Here we present an experimental observation of the lowest non-trivial Riemann zeros by using a trapped ion qubit in a Paul trap, periodically driven with microwave fields. The waveform of the driving is engineered such that the dynamics of the ion is frozen when the driving parameters coincide with a zero of the real component of the zeta function. Scanning over the driving amplitude thus enables the locations of the Riemann zeros to be measured experimentally to a high degree of accuracy, providing a physical embodiment of these fascinating mathematical objects in the quantum realm.

Robust and high-precision quantum control is crucial but challenging for scalable quantum computation and quantum information processing. Traditional adiabatic control suffers severe limitations on gate performance imposed by environmentally induced noise because of a quantum system's limited coherence time. In this work, we experimentally demonstrate an alternative approach {to quantum control} based on deep reinforcement learning (DRL) on a trapped $^{171}\mathrm{Yb}^{+}$ ion. In particular, we find that DRL leads to fast and robust {digital quantum operations with running time bounded by shortcuts to adiabaticity} (STA). Besides, we demonstrate that DRL's robustness against both Rabi and detuning errors can be achieved simultaneously without any input from STA. Our experiments reveal a general framework of digital quantum control, leading to a promising enhancement in quantum information processing.

For circuit-based quantum computation, experimental implementation of universal set of quantum logic gates with high-fidelity and strong robustness is essential and central. Quantum gates induced by geometric phases, which depend only on global properties of the evolution paths, have built-in noise-resilience features. Here, we propose and experimentally demonstrate nonadiabatic holonomic single-qubit quantum gates on two dark paths in a trapped $^{171}\mathrm{Yb}^{+}$ ion based on four-level systems with resonant drives. We confirm the implementation with measured gate fidelity through both quantum process tomography and randomized benchmarking methods. Meanwhile, we find that nontrivial holonomic two-qubit quantum gates can also be realized within current experimental technologies. Compared with previous implementations on three-level systems, our experiment share both the advantage of fast nonadiabatic evolution and the merit of robustness against systematic errors, and thus retains the main advantage of geometric phases. Therefore, our experiment confirms a promising method for fast and robust holonomic quantum computation.

Entanglement detection is one of the most conventional tasks in quantum information processing. While most experimental demonstrations of high-dimensional entanglement rely on fidelity-based witnesses, these are powerless to detect entanglement within a large class of entangled quantum states, the so-called unfaithful states. In this paper, we introduce a highly flexible automated method to construct optimal tests for entanglement detection given a bipartite target state of arbitrary dimension, faithful or unfaithful, and a set of local measurement operators. By restricting the number or complexity of the considered measurement settings, our method outputs the most convenient protocol which can be implemented using a wide range of experimental techniques such as photons, superconducting qudits, cold atoms or trapped ions. With an experimental quantum optics setup that can prepare and measure arbitrary high-dimensional mixed states, we implement some $3$-setting protocols generated by our method. These protocols allow us to experimentally certify 2- and 3-unfaithful entanglement in 4-dimensional photonic states, some of which contain well above 50% of noise.

The quantum walk (QW), as the quantum analog of classical random walk, provides a feasible platform to study the topological phenomenon and non-equilibrium dynamics. Here, we propose a novel scheme to realize the quantum walk with a single trapped ion where the Fock states provides the walk space and zero phonon state $\left|n=0\right\rangle $ serves as its natural boundary. Thus, our scheme offers the unique opportunity to investigate the dynamics of the bound states of the corresponding topological systems. Particularly, the quench dynamics of the bound states can be extensively studied by tuning the bulk parameters and the local boundary operator, which are experimentally accessible. Our proposal not only offers a new approach to exploring the character of the bound states of the topological systems, but also offers a way to determine different phases through the dynamical processes.

Kibble-Zurek mechanism (KZM) is a universal framework which could in principle describe phase transition phenomenon in any system with required symmetry properties. However, a conflicting observation termed anti-KZ behavior has been reported in the study of ferroelectric phase transition, in which slower driving results in more topological defects [S. M. Griffin, et al. Phys. Rev. X. 2, 041022 (2012)]. Although this research is significant, its experimental simulations have been scarce until now. In this work, we experimentally demonstrate anti-KZ behavior under noisy control field in three kinds of quantum phase transition protocols using a single trapped Yb ion. The density of defects is studied as a function of the quench time and the noise intensity. We experimentally verify that the optimal quench time to minimize excitation scales as a universal power law of the noise intensity. Our research sets a stage for quantum simulation of such anti-KZ behavior in two-level systems and reveals the limitations of the adiabatic protocols such as quantum annealing.

Quantum computation with quantum gates induced by geometric phases is regarded as a promising strategy in fault tolerant quantum computation, due to its robustness against operational noises. However, because of the parametric restriction of previous schemes, the main robust advantage of holonomic quantum gates is smeared. Here, we experimentally demonstrate a solution scheme, demonstrating nonadiabatic holonomic single qubit quantum gates with optimal control in a trapped Yb ion based on three level systems with resonant drives, which also hold the advantages of fast evolution and convenient implementation. Compared with corresponding previous geometric gates and conventional dynamic gates, the superiority of our scheme is that it is more robust against control amplitude errors, which is confirmed by the measured gate infidelity through both quantum process tomography and random benchmarking methods. In addition, we also outline that nontrivial two qubit holonomic gates can also be realized within current experimental technologies. Therefore, our experiment validates the feasibility for this robust and fast holonomic quantum computation strategy.

Suppressing undesired nonunitary effects is a major challenge in quantum computation and quantum control. In this work, by considering the adiabatic dynamics in presence of a surrounding environment, we theoretically and experimentally analyze the robustness of adiabaticity in open quantum systems. More specifically, by considering a decohering scenario, we exploit the validity conditions of the adiabatic approximation as well as its sensitiveness to the resonance situation, which typically harm adiabaticity in closed systems. As an illustration, we implement an oscillating Landau-Zener Hamiltonian, which shows that decoherence may drive the resonant system with high fidelities to the adiabatic behavior of open systems. Moreover we also implement the adiabatic quantum algorithm for the Deutsch problem, where a distinction is established between the open system adiabatic density operator and the target pure state expected in the computation process. Preferred time windows for obtaining the desired outcomes are then analyzed. We experimentally realize these systems through a single trapped Ytterbium ion $^{171}$Yb$^+$, where the ion hyperfine energy levels are used as degrees of freedom of a two-level system, with both driven field and decohering strength efficiently controllable.

We experimentally probe the distribution of kink pairs resulting from driving a one-dimensional quantum Ising chain through the paramagnet-ferromagnet quantum phase transition, using a single trapped ion as a quantum simulator in momentum space. The number of kink pairs after the transition follows a Poisson binomial distribution, in which all cumulants scale with a universal power-law as a function of the quench time in which the transition is crossed. We experimentally verified this scaling for the first cumulants and report deviations due to noise-induced dephasing of the trapped ion. Our results establish that the universal character of the critical dynamics can be extended beyond the paradigmatic Kibble-Zurek mechanism, which accounts for the mean kink number, to characterize the full probability distribution of topological defects.

An experiment based on a trapped Ytterbium ion validates the inertial theorem for the SU(2) algebra. The qubit is encoded within the hyperfine states of the atom and controlled by RF fields. The inertial theorem generates analytical solutions for non-adiabatically driven systems that are `accelerated' slowly, bridging the gap between the sudden and adiabatic limits. These solutions are shown to be stable to small deviations, both experimentally and theoretically. As a result, the inertial solutions pave the way to rapid quantum control of closed, as well as open quantum systems. For large deviations from the inertial condition, the amplitude diverges while the phase remains accurate.

Quantum thermodynamics aims at investigating both the emergence and the limits of the laws of thermodynamics from a quantum mechanical microscopic approach. In this scenario, thermodynamic processes with no heat exchange, namely, adiabatic transformations, can be implemented through quantum evolutions in closed systems, even though the notion of a closed system is always an idealization and approximation. Here, we begin by theoretically discussing thermodynamic adiabatic processes in open quantum systems, which evolve non-unitarily under decoherence due to its interaction with its surrounding environment. From a general approach for adiabatic non-unitary evolution, we establish heat and work in terms of the underlying Liouville superoperator governing the quantum dynamics. As a consequence, we derive the conditions that an adiabatic open-system quantum dynamics implies in the absence of heat exchange, providing a connection between quantum and thermal adiabaticity. Moreover, we determine families of decohering systems exhibiting the same maximal heat exchange, which imply in classes of thermodynamic adiabaticity in open systems. We then approach the problem experimentally using a hyperfine energy-level quantum bit of an Ytterbium $^{171}$Yb$^+$ trapped ion, which provides a work substance for thermodynamic processes, allowing for the analysis of heat and internal energy throughout a controllable engineered dynamics.

In this work, we introduce machine learning methods to implement readout of a single qubit on $^{171}\mathrm{Yb^{+}}$ trapped-ion system. Different machine learning methods including convolutional neural networks and fully-connected neural networks are compared with traditional methods in the tests. The results show that machine learning methods have higher fidelity, more robust readout results in relatively short time. To obtain a 99% readout fidelity, neural networks only take half of the detection time needed by traditional threshold or maximum likelihood methods. Furthermore, we implement the machine learning algorithms on hardware-based field-programmable gate arrays and an ARM processor. An average readout fidelity of 99.5% (with $10^5$ magnitude trials) within 171 $μ$s is demonstrated on the embedded hardware system for $^{171}\mathrm{Yb^{+}}$ ion trap.

Validity conditions for the adiabatic approximation are useful tools to understand and predict the quantum dynamics. Remarkably, the resonance phenomenon in oscillating quantum systems has challenged the adiabatic theorem. In this scenario, inconsistencies in the application of quantitative adiabatic conditions have led to a sequence of new approaches for adiabaticity. Here, by adopting a different strategy, we introduce a validation mechanism for the adiabatic approximation by driving the quantum system to a non-inertial reference frame. More specifically, we begin by considering several relevant adiabatic approximation conditions previously derived and show that all of them fail by introducing a suitable oscillating Hamiltonian for a single quantum bit (qubit). Then, by evaluating the adiabatic condition in a rotated non-inertial frame, we show that all of these conditions, including the standard adiabatic condition, can correctly describe the adiabatic dynamics in the original frame, either far from resonance or at a resonant point. Moreover, we prove that this validation mechanism can be extended for general multi-particle quantum systems, establishing the conditions for the equivalence of the adiabatic behavior as described in inertial or non-inertial frames. In order to experimentally investigate our method, we consider a hyperfine qubit through a single trapped Ytterbium ion $^{171}$Yb$^{+}$, where the ion hyperfine energy levels are used as degrees of freedom of a two-level system. By monitoring the quantum evolution, we explicitly show the consistency of the adiabatic conditions in the non-inertial frame.

It is known that high intensity fields are usually required to implement shortcuts to adiabaticity via Transitionless Quantum Driving (TQD). Here, we show that this requirement can be relaxed by exploiting the gauge freedom of generalized TQD, which is expressed in terms of an arbitrary phase when mimicking the adiabatic evolution. We experimentally investigate the performance of generalized TQD in comparison with both traditional TQD and adiabatic dynamics. By using a $^{171}$Yb$^+$ trapped ion hyperfine qubit, we implement a Landau-Zener adiabatic Hamiltonian and its (traditional and generalized) TQD counterparts. We show that the generalized theory provides optimally implementable Hamiltonians for TQD, with no additional fields required. In addition, the energetically optimal TQD Hamiltonian for the Landau-Zener model is investigated under dephasing. Remarkably, even using less intense fields, optimal TQD exhibits fidelities that are more robust against a decohering environment, with performance superior than that provided by the adiabatic dynamics.

The hybrid quantum network, a universal form of quantum network which is aimed for quantum communication and distributed quantum computation, is that the quantum nodes in it are realized with different physical systems. This universal form of quantum network can combine the advantages and avoid the inherent defects of the different physical system. However, one obstacle standing in the way is the compatible photonic quantum interface. One possible solution is using non-degenerate, narrow-band, entangled photon pairs as the photonic interface. Here, for the first time, we generate nondegenrate narrow-band polarization-entangled photon pairs in cavity-enhanced spontaneous parametric down-conversion process. The bandwidths and central wavelengths of the signal and idler photons are 9 MHz at 935 nm and 9.5 MHz at 880 nm, which are compatible with trapped ion system and solid-state quantum memory system. The entanglement of the photon source is certified by quantum state tomography, showing a fidelity of 89.6% between the generated quantum state with a Bell state. Besides, a strong violation against Bell inequality with 2.36+/-0.03 further confirms the entanglement property of the photon pairs. Our method is suitable for the hybrid quantum network and will take a big step in this field.

Full quantum state tomography (FQST) plays a unique role in the estimation of the state of a quantum system without \emph{a priori} knowledge or assumptions. Unfortunately, since FQST requires informationally (over)complete measurements, both the number of measurement bases and the computational complexity of data processing suffer an exponential growth with the size of the quantum system. A 14-qubit entangled state has already been experimentally prepared in an ion trap, and the data processing capability for FQST of a 14-qubit state seems to be far away from practical applications. In this paper, the computational capability of FQST is pushed forward to reconstruct a 14-qubit state with a run time of only 3.35 hours using the linear regression estimation (LRE) algorithm, even when informationally overcomplete Pauli measurements are employed. The computational complexity of the LRE algorithm is first reduced from $O(10^{19})$ to $O(10^{15})$ for a 14-qubit state, by dropping all the zero elements, and its computational efficiency is further sped up by fully exploiting the parallelism of the LRE algorithm with parallel Graphic Processing Unit (GPU) programming. Our result can play an important role in quantum information technologies with large quantum systems.

In a hybrid quantum network, linking two kinds of quantum nodes through photonic channels requires excellent matching of central frequency and bandwidth between both nodes and their interfacing photons. However, pre-existing photon sources can not fulfill this requirement. Using a novel conjoined double-cavity strategy, we report the generation of nondegenerate narrow-band photon pairs by cavity-enhanced spontaneous parametric down-conversion. The central frequencies and bandwidths of the signal and idler photons are independently set to match with trapped ions and solid-state quantum memories. With this source we achieve the bandwidths and central frequencies of 4 MHz at 935 nm and 5 MHz at 880 nm for the signal and idler photons respectively, with a normalized spectrum brightness of 4.9/s/MHz/mW. Due to the ability of being independently locked to two different wavelenghts, the conjoined double-cavity is universally suitable for hybrid quantum network consisting of various quantum nodes.

We propose a new dark-state cooling method of trapped ion systems in the Lamb-Dicke limit. With application of microwave dressing the ion, we can obtain two electromagnetically induced transparency structures. The heating effects caused by the carrier and the blue sideband transition vanish due to the EIT effects and the final mean phonon numbers can be much less than the recoil limit. Our scheme is robust to fluctuations of microwave power and laser intensities which provides a broad cooling bandwidth to cool motional modes of a linear ion chain. Moreover, it is more suitable to cool four-level ions on a large-scale ion chip.

The Kibble-Zurek mechanism is the paradigm to account for the nonadiabatic dynamics of a system across a continuous phase transition. Its study in the quantum regime is hindered by the requisite of ground state cooling. We report the experimental quantum simulation of critical dynamics in the transverse-field Ising model by a set of Landau-Zener crossings in pseudo-momentum space, that can be probed with high accuracy using a single trapped ion. We test the Kibble-Zurek mechanism in the quantum regime in the momentum space and find the measured scaling of excitations is in accordance with the theoretical prediction.

A scheme is presented for realizing a quantum phase gate with three-level atoms, solid-state qubits--often called artificial atoms, or ions that share a quantum data bus such as a single mode field in cavity QED system or a collective vibrational state of trapped ions. In this scheme, the conditional phase shift is tunable and controllable via the total effective interaction time. Furthermore, we show that the method can be used for effective preparation of graph-state entanglement, which are important resources for quantum computation, quantum error correction, studies of multiparticle entanglement, fundamental tests of non-locality and decoherence.