Hendrik Bekker

Optical transitions of highly charged ions can be very sensitive to hypothetical beyond-the-Standard-Model phenomena. Those near the $5s-4f$ level crossing, where the $5s$ and $4f$ are degenerate are especially promising. We present predictions from atomic theory and measurements of Os$^{15,16,17+}$ at an electron beam ion trap for identification of several transitions suitable for searches for a hypothetical fifth force and possible violations of local Lorentz invariance. The electric quadrupole (E2) transitions of Os$^{16+}$ that were found are especially suitable for frequency metrology due to their small linewidth of 44 $μ$Hz. Our calculations show the need for including enough inner-shell excitations to predict transition rates between configurations, which can otherwise be overestimated. Ultimately, the predicted interconfiguration transitions were too weak to be detected.

We demonstrate the operation of a dual-frequency Paul trap and characterize its performance by storing either electrons or calcium ions while applying two quadrupole fields simultaneously which oscillate at $Ω_\textrm{fast} = 2π\times 1.6$ GHz and $Ω_\textrm{slow} = 2π\times 2$ MHz. The particles are loaded and stored in the trap under various conditions followed by detection employing an electron multiplier tube. We find that tens of electrons or ions can be trapped for up to ten milliseconds and a small fraction remains trapped even after hundreds of milliseconds. During dual-frequency operation we find that while the number of trapped electrons rapidly decreases with increase of the $Ω_\textrm{slow}$ field amplitude, the number of trapped ions shows no dependence on the $Ω_\textrm{fast}$ field amplitude as supported by our extensive numerical simulations. We aim to use a similar trap for synthesising antihydrogen from antiprotons and positrons. Accordingly, we discuss open challenges such as the co-trapping of oppositely charged species and particle trap duration.

State-of-the-art optical clocks achieve fractional precisions of $10^{-18}$ and below using ensembles of atoms in optical lattices or individual ions in radio-frequency traps. Promising candidates for novel clocks are highly charged ions (HCIs) and nuclear transitions, which are largely insensitive to external perturbations and reach wavelengths beyond the optical range, now becoming accessible to frequency combs. However, insufficiently accurate atomic structure calculations still hinder the identification of suitable transitions in HCIs. Here, we report on the discovery of a long-lived metastable electronic state in a HCI by measuring the mass difference of the ground and the excited state in Re, the first non-destructive, direct determination of an electronic excitation energy. This result agrees with our advanced calculations, and we confirmed them with an Os ion with the same electronic configuration. We used the high-precision Penning-trap mass spectrometer PENTATRAP, unique in its synchronous use of five individual traps for simultaneous mass measurements. The cyclotron frequency ratio $R$ of the ion in the ground state to the metastable state could be determined to a precision of $δR=1\cdot 10^{-11}$, unprecedented in the heavy atom regime. With a lifetime of about 130 days, the potential soft x-ray frequency reference at $ν=4.86\cdot 10^{16}\,\text{Hz}$ has a linewidth of only $Δν\approx 5\cdot 10^{-8}\,\text{Hz}$, and one of the highest electronic quality factor ($Q=\fracν{Δν}\approx 10^{24}$) ever seen in an experiment. Our low uncertainty enables searching for more HCI soft x-ray clock transitions, needed for promising precision studies of fundamental physics in a thus far unexplored frontier.

The excitation of the 8 eV $^{229m}$Th isomer through the electronic bridge mechanism in highly charged ions is investigated theoretically. By exploiting the rich level scheme of open $4f$ orbitals and the robustness of highly charged ions against photoionization, a pulsed high-intensity optical laser can be used to efficiently drive the nuclear transition by coupling it to the electronic shell. We show how to implement a promising electronic bridge scheme in an electron beam ion trap starting from a metastable electronic state. This setup would avoid the need for a tunable vacuum ultraviolet laser. Based on our theoretical predictions, determining the isomer energy with an uncertainty of $10^{-5}$ eV could be achieved in one day of measurement time using realistic laser parameters.