J. Goold

We propose an experimental scheme to verify the quantum non-equilibrium fluctuation relations using current technology. Specifically, we show that the characteristic function of the work distribution for a non-equilibrium quench of a general quantum system can be extracted from Ramsey interferometry of a single probe qubit. Our scheme paves the way for the full characterisation of non-equilibrium processes in a variety of complex quantum systems ranging from single particles to many-body atomic systems and spin chains. We demonstrate our idea using a time-dependent quench of the motional state of a trapped ion, where the internal pseudo-spin provides a convenient probe qubit.

In order to study ultracold charge-transfer processes in hybrid atom-ion traps, we have mapped out the potential energy curves and molecular parameters for several low lying states of the Rb, Yb$^+$ system. We employ both a multi-reference configuration interaction (MRCI) and a full configuration interaction (FCI) approach. Turning points, crossing points, potential minima and spectroscopic molecular constants are obtained for the lowest five molecular states. Long-range parameters, including the dispersion coefficients are estimated from our {\it ab initio} data. The separated-atom ionization potentials and atomic polarizability of the ytterbium atom ($α_d=128.4$ atomic units) are in good agreement with experiment and previous calculations. We present some dynamical calculations for (adiabatic) scattering lengths for the two lowest (Yb,Rb$^+$) channels that were carried out in our work. However, we find that the pseudo potential approximation is rather limited in validity, and only applies to nK temperatures. The adiabatic scattering lengths for both the triplet and singlet channels indicate that both are large and negative in the FCI approximation.

We consider a harmonically trapped Tonks-Girardeau gas of impenetrable bosons in the presence of a single embedded ion, which is assumed to be tightly confined in a RF trap. In an ultracold ion-atom collision the ion's charge induces an electric dipole moment in the atoms which leads to an attractive $r^{-4}$ potential asymptotically. We treat the ion as a static deformation of the harmonic trap potential and model its short range interaction with the gas in the framework of quantum defect theory. The molecular bound states of the ionic potential are not populated due to the lack of any possible relaxation process in the Tonks-Girardeau regime. Armed with this knowledge we calculate the density profile of the gas in the presence of a central ionic impurity and show that a density \textit{bubble} of the order of a micron occurs around the ion for typical experimental parameters. From these exact results we show that an ionic impurity in a Tonks gas can be described using a pseudopotential, allowing for significantly easier treatment.