J. -W. Zhang

Quantum signal processing (QSP), which enables systematic polynomial transformations on quantum data through sequences of qubit rotations, has emerged as a fundamental building block for quantum algorithms and data re-uploading quantum neural networks. While recent experiments have demonstrated the feasibility of shallow QSP circuits, the inherent limitations in scaling QSP to achieve complex transformations on quantum hardware remain an open and critical question. Here we report the first experimental realization of deep QSP circuits in a trapped-ion quantum simulator. By manipulating the qubit encoded in a trapped $^{43}\textrm{Ca}^{+}$ ion, we demonstrate high-precision simulation of some prominent functions used in quantum algorithms and machine learning, with circuit depths ranging from 15 to 360 layers and implementation time significantly longer than coherence time of the qubit. Our results reveal a crucial trade-off between the precision of function simulation and the concomitant accumulation of hardware noise, highlighting the importance of striking a balance between circuit depth and accuracy in practical QSP implementation. This work addresses a key gap in understanding the scalability and limitations of QSP-based algorithms on quantum hardware, providing valuable insights for developing quantum algorithms as well as practically realizing quantum singular value transformation and data re-uploading quantum machine learning models.

The approach of shortcuts to adiabaticity enables the effective execution of adiabatic dynamics in quantum information processing with enhanced speed. Owing to the inherent trade-off between dynamical speed and the cost associated with the transitionless driving field, executing arbitrarily fast operations becomes impractical. To understand the accurate interplay between speed and energetic cost in this process, we propose theoretically and verify experimentally a new trade-off, which is characterized by a tightly optimized bound within $s$-parameterized phase spaces. Our experiment is carried out in a single ultracold $^{40}$Ca$^{+}$ ion trapped in a harmonic potential. By exactly operating the quantum states of the ion, we execute the Landau-Zener model as an example, where the quantum speed limit as well as the cost are governed by the spectral gap. We witness that our proposed trade-off is indeed tight in scenarios involving both initially eigenstates and initially thermal equilibrium states. Our work helps understanding the fundamental constraints in shortcuts to adiabaticity and illuminates the potential of under-utilized phase spaces that have been traditionally overlooked.

We reported the realization of a $^{174}\mathrm{Yb}^+$-$^{113}\mathrm{Cd}^+$ bi-species Coulomb crystal comprising $^{174}\mathrm{Yb}^+$ ions as coolant and verified its potential for application as a $^{113}\mathrm{Cd}^+$ microwave frequency standard employing sympathetic cooling.The two species of massive ions stably trapped in a Paul trap make up this large two-component crystal. The $^{113}\mathrm{Cd}^+$ ions are trapped in the center, which reduces considerably RF heating and excess micromotion to which the $^{113}\mathrm{Cd}^+$ ions are subjected. Under this scheme, the uncertainty due to the second-order Doppler effect is reduced to $5\times10^{-16}$, which represents an order of magnitude improvement over sympathetic cooled $^{40}\mathrm{Ca}^+$-$^{113}\mathrm{Cd}^+$ crystal. The uncertainty from the second-order Zeeman effect, which contributes the largest uncertainty to the microwave-ion frequency standard, is reduced to $4\times10^{-16}$. The relevant AC Stark shift uncertainty is estimated to be $4\times10^{-19}$. These results indicate using $^{174}\mathrm{Yb}^+$ as coolant ions for $^{113}\mathrm{Cd}^+$ is far superior and confirm the feasibility of a sympathetic-cooled cadmium-ion microwave clock system employing a $^{174}\mathrm{Yb}^+$-$^{113}\mathrm{Cd}^+$ two-component crystal.

The accurate evaluation of the second-order Doppler frequency shift (SODFS) of trapped ions in a linear Paul trap has been studied with experiments and molecular dynamics (MD) simulations. The motion of trapped ions in the trap has three contributions, and we focus on the ion excess micromotion, which is rarely discussed when evaluating the SODFS. Based on the hypothesis that the ion density is uniformly distributed in the radial direction, we propose a new model to accurately evaluate the total SODFS for ion microwave clocks. The effectiveness of the model has been verified both in simulation and experiment, especially for ion ensemble with temperature less than 100 mK. We believe that our new model offers advantages in accurately evaluating the SODFS for the ion trap, especially those of laser-cooled ion microwave clocks based on large ion clouds.

The ion microwave frequency standard is a candidate for the next generation of microwave frequency standard with the potential for very wide applications. The Dick effect and second-order Doppler frequency shift (SODFS) limit the performance of ion microwave frequency standards. The introduction of sympathetic cooling technology can suppress the Dick effect and SODFS and improve the stability and accuracy of the frequency standard. However, the sympathetically-cooled ion microwave frequency standard has seldom been studied before. This paper reports the first sympathetically-cooled ion microwave frequency standard in a Paul trap. Using laser-cooled ${}^{40}\mathrm{Ca}^{+}$ as coolant ions, ${}^{113}\mathrm{Cd}^{+}$ ion crystal is cooled to below 100 mK and has a coherence lifetime of over 40 s. The short-term frequency stability reached $3.48 \times 10^{-13}/τ^{1/2}$, which is comparable to that of the mercury ion frequency standard. Its uncertainty is $1.5\times 10^{-14}$, which is better than that of directly laser-cooled cadmium ion frequency standard.

Regarding trapped-ion microwave-frequency standards, we report on the determination of hyperfine splittings and Landé $g_J$ factors of $^{111,113}$Cd$^+$. The hyperfine splittings of the $5p~^2P_{3/2}$ state of $^{111,113}$Cd$^+$ ions were measured using laser-induced fluorescence spectroscopy. The Cd$^+$ ions were confined in a linear Paul trap and sympathetically cooled by Ca$^+$ ions. Furthermore, the hyperfine splittings and Landé $g_J$ factors of the $5s~^2S_{1/2}$ and $5p~^2P_{1/2,3/2}$ levels of $^{111,113}$Cd$^+$ were calculated with greater accuracy using the multiconfiguration Dirac--Hartree--Fock scheme. The measured hyperfine splittings and the Dirac--Hartree--Fock calculation values were cross-checked, thereby further guaranteeing the reliability of our results. The results provided in this work can improve the signal-to-noise ratio of the clock transition and the accuracy of the second-order Zeeman shift correction, and subsequently the stability and accuracy of the microwave frequency standard based on trapped Cd$^+$ ions.

We have sympathetically cooled and crystallized ${}^{113}\mathrm{Cd}^{+}$ ions with laser-cooled ${}^{40}\mathrm{Ca}^{+}$ ions, and directly observed the complete large bicrystal structure in a linear Paul trap. The large two-component crystal contains up to $3.5\times10^3$ ${}^{40}\mathrm{Ca}^{+}$ ions and $6.8\times10^3$ ${}^{113}\mathrm{Cd}^{+}$ ions. The temperature of the crystallized ${}^{113}\mathrm{Cd}^{+}$ ions was measured to be as low as 41 mK with a large mass ratio. Moreover, we have studied several properties and structures of the ultracold sample. The factors affecting the sympathetic cooling effect were studied, including the electrical parameters and the number ratio between laser-cooled ions and sympathetically-cooled ions. The results of this paper enrich the experimental research of large two-component ion crystals, and the ultracold sample of ${}^{113}\mathrm{Cd}^{+}$ ions makes it possible to further improve the accuracy of the cadmium-ion microwave frequency standard.

We report on progress towards a microwave frequency standard based on a laser-cooled 171Yb+ ion trap system. The electronics, lasers, and magnetic shields are integrated into a single physical package. With over 1E5 ions are stably trapped, the system offers a high signal-to-noise ratio Ramsey line-shape. In comparison with previous work, the frequency instability of a 171Yb+ microwave clock was further improved to $8.5 \times {10^{ - 13}}/\sqrt τ$ for averaging times between 10 and 1000 s.

We measured the ground-state hyperfine splitting of trapped ${}^{113}$Cd${}^{+}$ ions to be 15199862855.02799(27) Hz with a fractional uncertainty of $1.8\times10^{-14}$. The ions were trapped and laser-cooled in a linear quadrupole Paul trap. The fractional frequency stability was measured to be ${4.2} \times 10^{-13}/\sqrtτ $, obtained from Ramsey fringes of high signal-to-noise ratio and taken over a measurement time of nearly 5 hours, which is close to the short-term stability limit estimated from the Dick effect. Our result is consistent with previous reported values, but the measurement precision is four times better than the best result obtained to date.

Quantum gates induced by geometric phases are intrinsically robust against noise due to their global properties of the evolution paths. Compared to conventional nonadiabatic geometric quantum computation (NGQC), the recently proposed nonadiabatic noncyclic geometric quantum computation (NNGQC) works in a faster fashion, while still remaining the robust feature of the geometric operations. Here, we experimentally implement the NNGQC in a single trapped ultracold $^{40}$Ca$^{+}$ ion for verifying the noise-resilient and fast feature. By performing unitary operations under imperfect conditions, we witness the advantages of the NNGQC with measured fidelities by quantum process tomography in comparison with other two quantum gates by conventional NGQC and by straightforwardly dynamical evolution. Our results provide the first evidence confirming the possibility of accelerated quantum information processing with limited systematic errors even in the imperfect situation.

Quantitative measure of disorder or randomness based on the entropy production characterizes thermodynamical irreversibility, which is relevant to the conventional second law of thermodynamics. Here we report, in a quantum mechanical fashion, the first theoretical prediction and experimental exploration of an information-theoretical bound on the entropy production. Our theoretical model consists of a simplest two-level dissipative system driven by a purely classical field, and under the Markovian dissipation, we find that such an information-theoretical bound, not fully validating quantum relaxation processes, strongly depends on the drive-to-decay ratio and the initial state. Furthermore, we carry out experimental verification of this information-theoretical bound by means of a single spin embedded in an ultracold trapped $^{40}$Ca$^{+}$ ion. Our finding, based on a two-level model, is fundamental to any quantum thermodynamical process and indicates much difference and complexity in quantum thermodynamics with respect to the conventionally classical counterpart.

We report sympathetic cooling of $^{113}$Cd$^+$ by laser-cooled $^{40}$Ca$^+$ in a linear Paul trap for microwave clocks. Long-term low-temperature confinement of $^{113}$Cd$^+$ ions was achieved. The temperature of these ions was measured at $90(10)$ mK, and the corresponding uncertainty arising from the second-order Doppler shifts was estimated to a level of $2\times10^{-17}$. Up to $4.2\times10^5$ Cd$^+$ ions were confined in the trap, and the confinement time constant was measured to be 84 hours. After three hours of confinement, there were still $10^5$ Cd$^+$ ions present, indicating that this Ca$^+$--Cd$^+$ dual ion system is surprisingly stable. The ac Stark shift was induced by the Ca$^+$ lasers and fluorescence, which was carefully estimated to an accuracy of $5.4(0.5)\times10^{-17}$ using a high-accuracy \textit{ab initio} approach. The Dick-effect-limited Allan deviation was also deduced because deadtimes were shorter. These results indicate that a microwave clock based on this sympathetic cooling scheme holds promise in providing ultra-high frequency accuracy and stability.

This paper reports the direct temperature determination of sympathetically cooled 113Cd+ ions with laser-cooled 24Mg+ in a linear Paul trap. The sympathetically cooled ion species distribute in the outer shell of the large ensembles, which contain up to 3.3E5 ions. With optimized parameters, the minimum temperature of the sympathetically cooled 113Cd+ ions was measured to be tens of mK. These results indicate promising performance for microwave atomic clocks. The second order Doppler frequency shift is two orders of magnitudes lower and the Dick effect is suppressed.