Kihwan Kim

Trapped-ion systems have emerged as a leading platform for scalable quantum information processing owing to their high-fidelity operations and long-range entangling capabilities. As the number of ions in a trap increases, the growing density of collective motional modes makes the synthesis of multimode entangling gates increasingly challenging. Designing large-scale gates requires simultaneously realizing the desired spin-spin interactions, suppressing residual spin-motion entanglement, and limiting experimental control resources, leading to a high-dimensional non-convex optimization problem. Here we develop a numerical framework for multi-tone gate synthesis that directly searches for control fields satisfying these competing requirements. By employing an alternating-minimization strategy, the framework improves numerical stability and remains effective for large systems with many motional modes and target interactions. As representative demonstrations, we synthesize gates implementing all-to-all and nearest-neighbor interaction patterns in ion chains of up to N = 1000, using only global laser control. Across the parameter regimes explored here, the control resources required to maintain high-fidelity interactions do not exhibit rapid growth with system size. We extend the framework to individual addressing using a structured qLDPC target at N = 512 as an example. These results identify multimode gate synthesis as a viable route toward programmable interaction engineering in large-scale trapped-ion quantum processors.

Quantum systems promise to revolutionize information processing science and technology [1-3]. The preservation of quantum coherence, the defining property of qubits, fundamentally constrains the performance of quantum information processing with quantum memories [4]. While trapped atomic ions theoretically support million-year coherence based on spontaneous emission [5-7], experimental demonstrations have reached far less, only about an hour [8-13]. Here we combine clock-state qubits with decoherence-free subspace (DFS) encoding to achieve coherence exceeding ten hours. Using correlation-based phase tracking in 171Yb+ ion pairs sympathetically cooled by 138Ba+ ion, we demonstrate this without magnetic shielding or enhanced microwave phase stabilization that previously limited coherence times. DFS encoding references the qubit phase to the inter-ion energy difference to reject microwave phase noise and common-mode magnetic fluctuations, while clock states provide environmental insensitivity. Throughout measurements extended to 1600 seconds, we observe minimal coherence decay, with exponential fits yielding a coherence time of (3.77 +/- 1.09) x 10^4 seconds. Our results establish DFS encoding as a form of passive error correction that eliminates technical noise constraints, unlocking the million-year coherence potential of atomic ions for scalable quantum information processing.

Probing quantum dynamics in the strong-field regime is critical for advancing our understanding of controlled quantum systems and developing robust quantum technologies. In this work, we experimentally investigate the dynamics of a trapped ion where the Rabi frequency (Omega) approaches the vibrational mode frequency (nu), pushing the system beyond the weak-field regime, where non-trivial quantum correlations emerge. We begin by setting the detuning (delta) - the frequency offset between the qubit transition and the driving field - to zero and varying Omega from low to high values, eventually reaching the vibrational frequency. Using quantum state tomography, we reconstruct the density matrix and track its evolution to assess non-Markovianity, revealing significant memory effects governed by the interplay between internal and motional degrees of freedom. Furthermore, by exploring the dynamics across various parameter pairs (Omega, delta), we find that non-Markovianity does not always increase monotonically with Omega for a fixed delta. Strikingly, when the condition delta squared plus Omega squared equals nu squared is met, the non-Markovianity exhibits a circular pattern of maxima. At this parameter combination, the system's Hamiltonian takes a form similar to the Jaynes-Cummings model, enabling the possibility of analytical insights into the observed dynamics. These results go beyond the conventional carrier and sideband regimes, uncovering novel features of strong-field quantum dynamics. Our findings establish a pathway for using trapped-ion platforms to investigate non-Markovianity, coherent control, and the fundamental behavior of open quantum systems in extreme regimes.

Vibrational modes of trapped ions have traditionally served as quantum buses to mediate internal qubits. However, with recent advances in quantum control, it has become possible to use these vibrational modes directly as quantum computational resources, such as bosonic qubits. Here, we propose a dual-rail encoding scheme in which a dual-rail qubit is encoded by two vibrational modes that share a single phonon. We present the preparation, measurement, and implementation of single- and two-qubit gates, enabling universal quantum computation. The dual-rail qubit system offers scalability and all-to-all connectivity. Moreover, we extend the dual-rail qubit system to a logical internal qubit--dual-rail qubit hybrid system by incorporating internal qubits into the dual-rail qubit system as another type of logical qubit. The hybrid system nearly doubles the number of available logical qubits compared to conventional trapped-ion quantum computers while maintaining all-to-all connectivity. Additionally, we propose a method for implementing multi-qubit controlled gates and discuss potential applications that can leverage the advantages of the hybrid system. Our scheme provides a practical framework for an internal qubit-boson qubit hybrid system.

Trapped-ion qubits are among the most promising candidates for quantum computing, quantum information processing, and quantum simulation. In general, trapped ions are considered to have sufficiently long coherence times, which are mainly characterized under laser-free conditions. However, in reality, essential laser fields for quantum manipulation introduce residual light shift, which seriously degrades the coherence due to power fluctuations. Here, we present a comprehensive study of AC Stark shifts in the hyperfine energy levels of the $^{171}\mathrm{Yb}^+$ ion, revealing an asymmetric light shift between two circular polarizations in the clock qubit and pronounced vector light shifts in the Zeeman qubits. By precisely tuning these polarizations, a remarkable enhancement in coherence time is observed, reaching over a hundredfold for the clock qubit and more than tenfold for the Zeeman qubits, when comparing conditions of maximum and minimum shifts. These findings advance the practical realization of scalable trapped-ion quantum processors, enabling deep quantum circuit execution and long duration adiabatic operations.

Information engines produce mechanical work through measurement and adaptive control. For information engines, the principal challenge lies in how to store the generated work for subsequent utilization. Here, we report an experimental demonstration where quantized mechanical motion serves as a quantum battery and gets charged in repeated cycles by a single trapped-ion information engine. This is enabled by a key technological advancement in rapid state discrimination, allowing us to suppress measurement-induced disturbances. Consequently, we were able to obtain a charging efficiency over 50\% of the theoretical limit at the optimal temperature. The experimental results substantiate that this approach can render trapped ions a promising platform for microscopic information engines with potential applications in the future upon scaling up.

A promising paradigm of quantum computing for achieving practical quantum advantages is quantum annealing or quantum approximate optimization algorithm, where the classical problems are encoded in Ising interactions. However, it is challenging to build a quantum system that can efficiently map any structured problems. Here, we present a programmable trapped-ion quantum simulator of an Ising model with all-to-all connectivity with up to four spins. We implement the spin-spin interactions by using the coupling of trapped ions to multiple collective motional modes and realize the programmability through phase modulation of the Raman laser beams that are individually addressed on ions. As an example, we realize several Ising lattices with different interaction connectivities, where the interactions can be ferromagnetic or anti-ferromagnetic. We confirm the programmed interaction geometry by observing the ground states of the corresponding models through quantum state tomography. Our experimental demonstrations serve as an important basis for realizing practical quantum advantages with trapped ions.

Quantum error mitigation has been extensively explored to increase the accuracy of the quantum circuits in noisy-intermediate-scale-quantum (NISQ) computation, where quantum error correction requiring additional quantum resources is not adopted. Among various error-mitigation schemes, probabilistic error cancellation (PEC) has been proposed as a general and systematic protocol that can be applied to numerous hardware platforms and quantum algorithms. However, PEC has only been tested in two-qubit systems and a superconducting multi-qubit system by learning a sparse error model. Here, we benchmark PEC using up to four trapped-ion qubits. For the benchmark, we simulate the dynamics of interacting fermions with or without spins by applying multiple Trotter steps. By tomographically reconstructing the error model and incorporating other mitigation methods such as positive probability and symmetry constraints, we are able to increase the fidelity of simulation and faithfully observe the dynamics of the Fermi-Hubbard model, including the different behavior of charge and spin of fermions. Our demonstrations can be an essential step for further extending systematic error-mitigation schemes toward practical quantum advantages.

The trapped-ion system has been a leading platform for practical quantum computation and quantum simulation since the first scheme of a quantum gate was proposed by Cirac and Zoller in 1995. Quantum gates with trapped ions have shown the highest fidelity among all physical platforms. Recently, sophisticated schemes of quantum gates such as amplitude, phase, frequency modulation, or multi-frequency application, have been developed to make the gates fast, robust to many types of imperfections, and applicable to multiple qubits. Here, we review the basic principle and recent development of quantum gates with trapped ions.

Controllable bosonic systems can provide post-classical computational power with sub-universal quantum computational capability. A network that consists of a number of bosons evolving through beam-splitters and phase-shifters between different modes, has been proposed and applied to demonstrate quantum advantages. While the network has been implemented mostly in optical systems with photons, recently alternative realizations have been explored, where major limitations in photonic systems such as photon loss, and probabilistic manipulation can be addressed. Phonons, the quantized excitations of vibrational modes, of trapped ions can be a promising candidate to realize the bosonic network. Here, we experimentally demonstrate a minimal-loss phononic network that can be programmed and in which any phononic states are deterministically prepared and detected. We realize the network with up to four collective-vibrational modes, which can be straightforwardly extended to reveal quantum advantage. We benchmark the performance of the network with an exemplary algorithm of tomography for arbitrary multi-mode states with a fixed total phonon number. We obtain reconstruction fidelities of 94.5 $\pm$ 1.95 % and 93.4 $\pm$ 3.15 % for single-phonon and two-phonon states, respectively. Our experiment demonstrates a clear and novel pathway to scale up a phononic network for various quantum information processing beyond the limitations of classical and other quantum systems.

Measurement-induced state disturbance is a major challenge in obtaining quantum statistics at multiple time points. We propose a method to extract dynamic information from a quantum system at intermediate time points, namely snapshotting quantum dynamics. To this end, we apply classical post-processing after performing the ancilla-assisted measurements to cancel out the impact of the measurements at each time point. Based on this, we reconstruct a multi-time quasi-probability distribution (QPD) that correctly recovers the probability distributions at the respective time points. Our approach can also be applied to simultaneously extract exponentially many correlation functions with various time-orderings. We provide a proof-of-principle experimental demonstration of the proposed protocol using a dual-species trapped-ion system by employing $^{171}\rm{Yb}^+$ and $^{138}\rm{Ba}^+$ ions as the system and the ancilla, respectively. Multi-time measurements are performed by repeated initialization and detection of the ancilla state without directly measuring the system state. The two- and three-time QPDs and correlation functions are reconstructed reliably from the experiment, negativity and complex values in the QPDs clearly indicate a contribution of the quantum coherence throughout dynamics.

Two-dimensional (2D) quantum magnetism is a paradigm in strongly correlated many-body physics. The understanding of 2D quantum magnetism can be expedited by employing a controllable quantum simulator that faithfully maps 2D-spin Hamiltonians. The 2D quantum simulators can exhibit exotic phenomena such as frustrated quantum magnetism and topological order and can be used to show quantum computational advantages. Many experimental platforms are being developed, including Rydberg atoms and superconducting annealers. However, with trapped-ion systems, which showed the most advanced controllability and quantum coherence, quantum magnetism was explored in one-dimensional chains. Here, we report simulations of frustrated quantum magnetism with 2D ion crystals. We create a variety of spin-spin interactions for quantum magnets, including those that exhibit frustration by driving different vibrational modes and adiabatically prepare the corresponding ground states. The experimentally measured ground states are consistent with the theoretical predictions and are highly degenerate for geometrically frustrated spin models in two dimensions. Quantum coherence of the ground states is probed by reversing the time evolution of the B-field to the initial value and then measuring the extent to which the remaining state coincides with the initial state. Our results open the door for quantum simulations with 2D ion crystals.

We propose and study ways speeding up of the entangling operations in the trapped ions system with high fidelity. First, we find a scheme to increase the speed of a two-qubit gate without the limitation of trap frequency, which was considered as the fundamental limit. Second, we study the fast gate scheme for entangling more than two qubits simultaneously. We apply the method of applying multiple frequency components on laser beams for the gate operations. In particular, in order to avoid infinite terms from the coupling to carrier transition, we focus on the phase-insensitive gate scheme here. We carefully study the effect of large excitation of motional mode beyond the limit of Lamb-Dicke approximation by including up to second order terms of the Lamb-Dicke parameter. We study the speed limit of multi-qubit global entangling gates without individual addressing requirements. Furthermore, our gates can be made insensitive to the fluctuation of initial motional phases which are difficult to stabilise in the phase-insensitive gate scheme.

Quantum measurements cannot be thought of as revealing preexisting results, even when they do not disturb any other measurement in the same trial. This feature is called contextuality and is crucial for the quantum advantage in computing. Here, we report the first observation of quantum contextuality simultaneously free of the detection, sharpness and compatibility loopholes. The detection and sharpness loopholes are closed by adopting a hybrid two-ion system and highly efficient fluorescence measurements offering a detection efficiency of $100\%$ and a measurement repeatability $>98\%$. The compatibility loophole is closed by targeting correlations between observables for two different ions in a Paul trap, a $^{171}\mathrm{Yb}^{+}$ ion and a $^{138}\mathrm{Ba}^{+}$ ion, chosen so measurements on each ion use different operation laser wavelengths, fluorescence wavelengths, and detectors. The experimental results show a violation of the bound for the most adversarial noncontextual models and open a new way to certify quantum systems.

Vibrational degrees of freedom in trapped-ion systems have recently been gaining attention as a quantum resource, beyond the role as a mediator for entangling quantum operations on internal degrees of freedom, because of the large available Hilbert space. The vibrational modes can be represented as quantum harmonic oscillators and thus offer a Hilbert space with infinite dimension. Here we review recent theoretical and experimental progress in the coherent manipulation of the vibrational modes, including bosonic encoding schemes in quantum information, reliable and efficient measurement techniques, and quantum operations that allow various quantum simulations and quantum computation algorithms. We describe experiments using the vibrational modes, including the preparation of non-classical states, molecular vibronic sampling, and applications in quantum thermodynamics. We finally discuss the potential prospects and challenges of trapped-ion vibrational-mode quantum information processing.

We theoretically and experimentally investigate double electromagnetically induced transparency (double-EIT) cooling of two-dimensional ion crystals confined in a Paul trap. The double-EIT ground-state cooling is observed for \Yb ions with clock state, for which EIT cooling has not been realized like many other ions with a simple $Λ$-scheme. A cooling rate of $\dot{\bar n}=34~(\pm1.8)~\rm{ms}^{-1}$ and a cooling limit of $\bar n=0.06~(\pm 0.059)$ are observed for a single ion. The measured cooling rate and limit are consistent with theoretical predictions. We apply double-EIT cooling to the transverse modes of two-dimensional (2D) crystals with up to 12 ions. In our 2D crystals, the micromotion and the transverse mode directions are perpendicular, which makes them decoupled. Therefore, the cooling on transverse modes is not disturbed by micromotion, which is confirmed in our experiment. For the center of mass mode of a 12 ions crystal, we observe a cooling rate and a cooling limit that are consistent with those of a single ion, including heating rates proportional to the number of ions. This method can be extended to other hyperfine qubits, and near ground-state cooling of stationary 2D crystals with large numbers of ions may advance the field of quantum information sciences.

We present a simple Paul trap that stably accommodates up to a couple of dozens of \ensuremath{^{171}\mathrm{Yb}^+~} ions in a stationary two-dimensional lattice. The trap is constructed on a single plate of gold-plated laser-machined alumina and can produce a pancake-like pseudo-potential that makes ions form a self-assembly two-dimensional crystal which locates on the plane composed of axial and one of the transverse axes with around 5 $μ$m spacing. We use Raman laser beams to coherently manipulate these ion-qubits where the net propagation direction is perpendicular to the plane of the crystal and micromotion. We perform the coherent operations and study the spectrum of vibrational modes through globally addressed Raman laser-beams on a dozen of ions in the two-dimensional crystal. We measure the amplitude of micro-motion by comparing the strengths of carrier and micro-motion sideband transitions with three ions, where the micro-motion amplitude is similar to that of a single ion. The spacings of ions are small enough for large coupling strengths, which is a favorable condition for two-dimensional quantum simulation.

Modern computation relies crucially on modular architectures, breaking a complex algorithm into self-contained subroutines. A client can then call upon a remote server to implement parts of the computation independently via an application programming interface (API). Present APIs relay only classical information. Here we implement a quantum API that enables a client to estimate the absolute value of the trace of a server-provided unitary $U$. We demonstrate that the algorithm functions correctly irrespective of what unitary $U$ the server implements or how the server specifically realizes $U$. Our experiment involves pioneering techniques to coherently swap qubits encoded within the motional states of a trapped \Yb ion, controlled on its hyperfine state. This constitutes the first demonstration of modular computation in the quantum regime, providing a step towards scalable, parallelization of quantum computation.

Various quantum applications can be reduced to estimating expectation values, which are inevitably deviated by operational and environmental errors. Although errors can be tackled by quantum error correction, the overheads are far from being affordable for near-term technologies. To alleviate the detrimental effects of errors, quantum error mitigation techniques have been proposed, which require no additional qubit resources. Here, we benchmark the performance of a quantum error mitigation technique based on probabilistic error cancellation in a trapped-ion system. Our results clearly show that effective gate fidelities exceed physical fidelities, i.e. we surpass the break-even point of eliminating gate errors, by programming quantum circuits. The error rates are effectively reduced from $(1.10\pm 0.12)\times10^{-3}$ to $(1.44\pm 5.28)\times10^{-5}$ and from $(0.99\pm 0.06)\times10^{-2}$ to $(0.96\pm 0.10)\times10^{-3}$ for single- and two-qubit gates, respectively. Our demonstration opens up the possibility of implementing high-fidelity computations on a near-term noisy quantum device.

In this chapter, we illustrate how a trapped ion system can be used for the experimental study of quantum thermodynamics, in particular, quantum fluctuation of work. As technology of nano/micro scale develops, it becomes critical to understand thermodynamics at the quantum mechanical level. The trapped ion system is a representative physical platform to experimentally demonstrate quantum phenomena with excellent control and precision. We provide a basic introduction of the trapped ion system and present the theoretical framework for the experimental study of quantum thermodynamics. Then we bring out two concrete examples of the experimental demonstrations. Finally, we discuss the results and the future of the experimental study of quantum thermodynamics with trapped ion systems.

The output randomness from a random number generator can be certified by observing the violation of quantum contextuality inequalities based on the Kochen-Specker theorem. Contextuality can be tested in a single quantum system, which significantly simplifies the experimental requirements to observe the violation comparing to the ones based on nonlocality tests. However, it is not yet resolved how to ensure compatibilities for sequential measurements that is required in contextuality tests. Here, we employ a modified Klyachko-Can-Binicioğlu-Shumovsky contextuality inequality, which can ease the strict compatibility requirement on measurements. On a trapped single \Ba ion system, we experimentally demonstrate violation of the contextuality inequality and realize self-testing quantum random number expansion by closing detection loopholes. We perform $1.29 \times 10^8$ trials of experiments and extract the randomness of $8.06 \times 10^5$ bits with a speed of 270 bits s$^{-1}$. Our demonstration paves the way for the practical high-speed spot-checking quantum random number expansion and other secure information processing applications.

A quantum algorithm can be decomposed into a sequence consisting of single qubit and 2-qubit entangling gates. To optimize the decomposition and achieve more efficient construction of the quantum circuit, we can replace multiple 2-qubit gates with a single global entangling gate. Here, we propose and implement a scalable scheme to realize the global entangling gates on multiple $\yb$ ion qubits by coupling to multiple motional modes through external fields. Such global gates require simultaneously decoupling of multiple motional modes and balancing of the coupling strengths for all the qubit-pairs at the gate time. To satisfy the complicated requirements, we develop a trapped-ion system with fully-independent control capability on each ion, and experimentally realize the global entangling gates. As examples, we utilize them to prepare the Greenberger-Horne-Zeilinger (GHZ) states in a single entangling operation, and successfully show the genuine multi-partite entanglements up to four qubits with the state fidelities over $93.4\%$.

Quantum simulation of complex quantum systems and their properties often requires the ability to prepare initial states in an eigenstate of the Hamiltonian to be simulated. In addition, to compute the eigenvalues of a Hamiltonian is in general a non-trivial problem. Here, we propose a hybrid quantum-classical probabilistic method to compute eigenvalues and prepare eigenstates of Hamiltonians which are simulatable with a trapped-ion quantum processor.

The optical manipulation of Ba$^{+}$ ions is mainly performed by a 493 nm laser for the S$_{1/2}$-P$_{1/2}$ transition and a 650 nm laser for the P$_{1/2}$-D$_{3/2}$ transition. Since the branching ratio between the 493 nm and 650 nm transitions of a single Ba$^{+}$ ion is comparable, stabilization systems of both lasers are equally important for Doppler cooling, sub-Doppler cooling, optical pumping and state detection. The stabilization system of a 493 nm laser to an absolute Te$_2$ reference has been well established. However, the stabilization of a 650 nm laser has not been presented before. Here we report twenty spectral lines of I$_{2}$ in the range of 0.9 GHz above the resonance of the P$_{1/2}$-D$_{3/2}$ transition. We stabilize the 650 nm laser through the optical cavity to the lowest one among these lines, which is about 350 MHz apart, as the absolute frequency reference. Furthermore, we measure the frequency differences between these iodine lines and the Ba$^+$ resonance through fluorescence excitation spectrum with well-resolved dark states, which is in agreement with the theoretical expectation. The presented stabilization scheme enables us to perform precise experiments with Ba$^{+}$ ions.

The NOT gate that flips a classical bit is ubiquitous in classical information processing. However its quantum analogue, the universal NOT (UNOT) gate that flips a quantum spin in any alignment into its antipodal counterpart is strictly forbidden. Here we explore the connection between this discrepancy and how UNOT gates affect classical and quantum correlations. We show that while a UNOT gate always preserves classical correlations between two spins, it can non-locally increase or decrease their shared discord in ways that allow violation of the data processing inequality. We experimentally illustrate this using a multi-level trapped \Yb ion that allows simulation of anti-unitary operations.

The quantum Rabi model, involving a two-level system and a bosonic field mode, is arguably the simplest and most fundamental model describing quantum light-matter interactions. Historically, due to the restricted parameter regimes of natural light-matter processes, the richness of this model has been elusive in the lab. Here, we experimentally realize a quantum simulation of the quantum Rabi model in a single trapped ion, where the coupling strength between the simulated light mode and atom can be tuned at will. The versatility of the demonstrated quantum simulator enables us to experimentally explore the quantum Rabi model in detail, including a wide range of otherwise unaccessible phenomena, as those happening in the ultrastrong and deep strong coupling regimes. In this sense, we are able to adiabatically generate the ground state of the quantum Rabi model in the deep strong coupling regime, where we are able to detect the nontrivial entanglement between the bosonic field mode and the two-level system. Moreover, we observe the breakdown of the rotating-wave approximation when the coupling strength is increased, and the generation of phonon wave packets that bounce back and forth when the coupling reaches the deep strong coupling regime. Finally, we also measure the energy spectrum of the quantum Rabi model in the ultrastrong coupling regime.

Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult. For systems that undergo decoherence but not dissipation, we argue that it is natural to define quantum work exactly as for isolated quantum systems, using the two-point measurement protocol. Complementing previous theoretical analysis using quantum channels, we show that the nonequilibrium work relation remains valid in this situation, and we test this assertion experimentally using a system engineered from an optically trapped ion. Our experimental results reveal the work relation's validity over a variety of driving speeds, decoherence rates, and effective temperatures and represent the first confirmation of the work relation for non-unitary dynamics.

Molecules are the most demanding quantum systems to be simulated by quantum computers because of their complexity and the emergent role of quantum nature. The recent theoretical proposal of Huh et al. (Nature Photon., 9, 615 (2015)) showed that a multi-photon network with a Gaussian input state can simulate a molecular spectroscopic process. Here, we report the first experimental demonstration of molecular vibrational spectroscopy of SO$_{2}$ with a trapped-ion system. In our realization, the molecular scattering operation is decomposed to a series of elementary quantum optical operations, which are implemented through Raman laser beams, resulting in a multimode Gaussian (Bogoliubov) transformation. The molecular spectroscopic signal is reconstructed from the collective projection measurements on phonon modes of the trapped-ion system. Our experimental demonstration would pave the way to large-scale molecular quantum simulations, which are classically intractable.

A standard method to obtain information on a quantum state is to measure marginal distributions along many different axes in phase space, which forms a basis of quantum state tomography. We theoretically propose and experimentally demonstrate a general framework to manifest nonclassicality by observing a single marginal distribution only, which provides a novel insight into nonclassicality and a practical applicability to various quantum systems. Our approach maps the 1-dim marginal distribution into a factorized 2-dim distribution by multiplying the measured distribution or the vacuum-state distribution along an orthogonal axis. The resulting fictitious Wigner function becomes unphysical only for a nonclassical state, thus the negativity of the corresponding density operator provides an evidence of nonclassicality. Furthermore, the negativity measured this way yields a lower bound for entanglement potential---a measure of entanglement generated using a nonclassical state with a beam splitter setting that is a prototypical model to produce continuous-variable (CV) entangled states. Our approach detects both Gaussian and non-Gaussian nonclassical states in a reliable and efficient manner. Remarkably, it works regardless of measurement axis for all non-Gaussian states in finite-dimensional Fock space of any size, also extending to infinite-dimensional states of experimental relevance for CV quantum informatics. We experimentally illustrate the power of our criterion for motional states of a trapped ion confirming their nonclassicality in a measurement-axis independent manner. We also address an extension of our approach combined with phase-shift operations, which leads to a stronger test of nonclassicality, i.e. detection of genuine non-Gaussianity under a CV measurement.

A long-time quantum memory capable of storing and measuring quantum information at the single-qubit level is an essential ingredient for practical quantum computation and com-munication. Recently, there have been remarkable progresses of increasing coherence time for ensemble-based quantum memories of trapped ions, nuclear spins of ionized donors or nuclear spins in a solid. Until now, however, the record of coherence time of a single qubit is on the order of a few tens of seconds demonstrated in trapped ion systems. The qubit coherence time in a trapped ion is mainly limited by the increasing magnetic field fluctuation and the decreasing state-detection efficiency associated with the motional heating of the ion without laser cooling. Here we report the coherence time of a single qubit over $10$ minutes in the hyperfine states of a \Yb ion sympathetically cooled by a \Ba ion in the same Paul trap, which eliminates the heating of the qubit ion even at room temperature. To reach such coherence time, we apply a few thousands of dynamical decoupling pulses to suppress the field fluctuation noise. A long-time quantum memory demonstrated in this experiment makes an important step for construction of the memory zone in scalable quantum computer architectures or for ion-trap-based quantum networks. With further improvement of the coherence time by techniques such as magnetic field shielding and increase of the number of qubits in the quantum memory, our demonstration also makes a basis for other applications including quantum money.

Multi-party entangled states have important applications in quantum metrology and quantum computation. Experimental preparation of large entangled state, in particular, the NOON states, however, remains challenging as the particle number $N$ increases. Here we develop a deterministic method to generate arbitrarily high NOON states for phonons and experimentally create the states up to $N=9$ phonons in two radial modes of a single trapped \Yb ion. We demonstrate that the fidelity of the NOON states are significantly above the classical limit by measuring the interference contrast and the population through the projective phonon measurement of two motional modes. We also measure the quantum Fisher information of the generated NOON state and observe the Heisenberg scaling in the lower bounds of the phase sensitivity as the $N$ increases. Our scheme is generic and applicable to other photonic or phononic systems.

Quantum field theories describe a wide variety of fundamental phenomena in physics. However, their study often involves cumbersome numerical simulations. Quantum simulators, on the other hand, may outperform classical computational capacities due to their potential scalability. Here, we report an experimental realization of a quantum simulation of fermion-antifermion scattering mediated by bosonic modes, using a multilevel trapped ion, which is a simplified model of fermion scattering in both perturbative and nonperturbative quantum electrodynamics. The simulated model exhibits prototypical features in quantum field theory including particle pair creation and annihilation, as well as self-energy interactions. These are experimentally observed by manipulating four internal levels of a $^{171}\mathrm{Yb}^{+}$ trapped ion, where we encode the fermionic modes, and two motional degrees of freedom that simulate the bosonic modes. Our experiment establishes an avenue towards the efficient implementation of fermionic and bosonic quantum field modes, which may prove useful in scalable studies of quantum field theories in perturbative and nonperturbative regimes.

The application of adiabatic protocols in quantum technologies is severely limited by environmental sources of noise and decoherence. Shortcuts to adiabaticity by counterdiabatic driving constitute a powerful alternative that speed up time-evolution while mimicking adiabatic dynamics. Here we present the first experimental implementation of counterdiabatic driving in a continuous variable system, a shortcut to the adiabatic transport of a trapped ion in the phase space. The resulting dynamics is equivalent to a "fast-motion video" of the adiabatic trajectory. The robustness of this protocol is shown to surpass that of competing schemes based on classical local controls and Fourier optimization methods. Our results demonstrate that shortcuts to adiabaticity provide a robust speedup of quantum protocols of wide applicability in quantum technologies.

Quantum theory is based on a mathematical structure totally different from conventional arithmetic. Due to the symmetric nature of bosonic particles, annihilation or creation of single particles translates a quantum state depending on how many bosons are already in the given quantum system. This proportionality results in a variety of non-classical features of quantum mechanics including the bosonic commutation relation. The annihilation and creation operations have recently been implemented in photonic systems. However, this feature of quantum mechanics does not preclude the possibility of realizing conventional arithmetic in quantum systems. We implement conventional addition and subtraction of single phonons for a trapped \Yb ion in a harmonic potential. In order to realize such operations, we apply the transitionless adiabatic passage scheme on the anti-Jaynes-Cummings coupling between the internal energy states and external motion states of the ion. By performing the operations on superpositions of Fock states, we realize the hybrid computation of classical arithmetic in quantum parallelism, and show that our operations are useful to engineer quantum states. Our single-phonon operations are nearly deterministic and robust against parameter changes, enabling handy repetition of the operations independently from the initial state of the atomic motion. We demonstrate the transform of a classical state to a nonclassical one of highly sub-Poissonian phonon statistics and a Gaussian state to a non-Gaussian state, by applying a sequence of the operations. The operations implemented here are the Susskind-Glogower phase operators, whose non-commutativity is also demonstrated.

In classical computational chemistry, the coupled-cluster ansatz is one of the most commonly used $ab~initio$ methods, which is critically limited by its non-unitary nature. The unitary modification as an ideal solution to the problem is, however, extremely inefficient in classical conventional computation. Here, we provide the first experimental evidence that indeed the unitary version of the coupled cluster ansatz can be reliably performed in physical quantum system, a trapped ion system. We perform a simulation on the electronic structure of a molecular ion (HeH$^+$), where the ground-state energy surface curve is probed, energies of excited-states are studied and the bond-dissociation is simulated non-perturbatively. Our simulation takes advantages from quantum computation to overcome the intrinsic limitations in classical computation and our experimental results indicate that the method is promising for preparing molecular ground-states for quantum simulation.

The past two decades witnessed important developments in the field of non-equilibrium statistical mechanics. Among these developments, the Jarzynski equality, being a milestone following the landmark work of Clausius and Kelvin, stands out. The Jarzynski equality relates the free energy difference between two equilibrium states and the work done on the system through far from equilibrium processes. While experimental tests of the equality have been performed in classical regime, the verification of the quantum Jarzynski equality has not yet been fully demonstrated due to experimental challenges. Here, we report an experimental test of the quantum Jarzynski equality with a single \Yb ion trapped in a harmonic potential. We perform projective measurements to obtain phonon distributions of the initial thermal state. Following that we apply the laser induced force on the projected energy eigenstate, and find transition probabilities to final energy eigenstates after the work is done. By varying the speed of applying the force from equilibrium to far-from equilibrium regime, we verified the quantum Jarzynski equality in an isolated system.

The understanding of symmetry operations has brought enormous advancements in physics, ranging from elementary particle to condensed matter systems. In quantum mechanics, symmetry operations are described by either unitary or antiunitary operators, where the latter are unphysical transformations that cannot be realized in physical systems. So far, quantum simulators of unitary and dissipative processes, the only allowed physical dynamics, have been realized in key experiments. Here, we present an embedding quantum simulator able to encode unphysical operations in a multilevel single trapped ion. In this sense, we experimentally observe phenomena associated with the nonunitary Majorana dynamics and implement antiunitary symmetry operations, i.e., time reversal and charge conjugation, at arbitrary evolution times. These experiments enhance the toolbox of quantum simulations towards applications involving unphysical operations.

We report the first experimental realization of the geometric Landau-Zener-Stückelberg (LZS) interferometry proposed by [Phys. Rev. Lett. 107, 207002 (2011)] in a single trapped ion system. Different from a conventional LZS interferometer, the interference fringes of our geometric interferometer originate solely from geometric phase. We also observe the robustness of the interference contrast against noise or fluctuation in the experimental parameters. Our scheme can be applied to other complex systems subject to relatively large errors in system control.

We experimentally observed state-independent violations of Kochen-Specker inequalities for the simplest indivisible quantum system manifesting quantum contextuality, a three-level (qutrit) system. We performed the experiment with a single trapped ^{171}Yb^{+} ion, by mapping three ground states of the ^{171}Yb^{+} ion to a qutrit system and carrying out quantum operatations by applying microwaves resonant to the qutrit transition frequencies. Our results are free from the detection loophole and cannot be explained by the non-contextual hidden variable models.

A collection of trapped atomic ions represents one of the most attractive platforms for the quantum simulation of interacting spin networks and quantum magnetism. Spin-dependent optical dipole forces applied to an ion crystal create long-range effective spin-spin interactions and allow the simulation of spin Hamiltonians that possess nontrivial phases and dynamics. Here we show how appropriate design of laser fields can provide for arbitrary multidimensional spin-spin interaction graphs even for the case of a linear spatial array of ions. This scheme uses currently existing trap technology and is scalable to levels where classical methods of simulation are intractable.

We consider interactions that generate a universal set of quantum gates on logical qubits encoded in a collective-dephasing-free subspace, and discuss their implementations with trapped ions. This allows for the removal of the by-far largest source of decoherence in current trapped-ion experiments, collective dephasing. In addition, an explicit parametrization of all two-body Hamiltonians able to generate such gates without the system's state ever exiting the protected subspace is provided.