Shiqian Ding

The low-energy isomeric transition in Thorium-229 offers a unique interface between nuclear and atomic physics, presenting a resource for quantum technologies that is notably resilient to environmental decoherence. While early experiments focused on nuclei in solid-state crystals, the recent advent of a continuous-wave vacuum ultraviolet laser at 148.4~nm now enables direct coherent control of individual trapped Th-229 ions. Building on this breakthrough, we present a theoretical framework for utilizing trapped Th-229^{3+} ions as high-fidelity nuclear-level qubits, wherein quantum state preparation, single-qubit control, and entangling operations based on nuclear energy levels can all be efficiently realized. We analyze a scheme to generate entanglement between the nuclear isomeric states of two ions through phonon-mediated coupling, driven by optimized red- and blue-detuned laser sideband pulses. Our analysis, grounded in realistic experimental parameters, also demonstrates that high-fidelity entanglement is achievable, leveraging the nucleus's intrinsically long coherence times. These results provide a practical roadmap for developing nuclear-based quantum information processors and suggest that entangled nuclear-level qubits could potentially unlock new frontiers in precision metrology.

While laser excitation of the nuclear isomeric transition in $^{229}$Th has been recently achieved for thorium atoms embedded in large-bandgap crystals, laser excitation and characterization of the nuclear transition in trapped $^{229}$Th$^{3+}$ ions has not yet been accomplished. To address these experiments, a cryogenic Paul trap setup has been designed, built, and commissioned at LMU Munich. Here, we present the specifications of the new experimental platform and demonstrate its successful operation, showing the extraction, subsequent ion-guiding, mass-purification, and trapping of $^{229}$Th$^{3+}$ and $^{229\text{m}}$Th$^{3+}$ ions from a newly designed buffer-gas stopping cell as well as of $^{88}$Sr$^{+}$ ions from laser ablation of a solid target. Further, we show sympathetic laser cooling of $^{229\text{(m)}}$Th$^{3+}$ by Doppler-cooled $^{88}$Sr$^{+}$ ions and the formation of mixed-species Coulomb crystals.

Interaction among harmonic oscillators described by a trilinear Hamiltonian $\hbar ξ(a^{\dagger} b c + a b^{\dagger} c^{\dagger}$) is one of the most fundamental models in quantum optics. By employing the anharmonicity of the Coublomb potential in a linear trapped three-ion crystal, we experimentally implement it among three normal modes of motion in the strong-coupling regime, where the coupling strength is much larger than the decoherence rate of the ions motion. We use it to simulate the interaction of atom and light as described by the Tavis-Cummings model and the process of nondegenerate parametric down conversion in the regime of depleted pump.

State measurement of a quantum harmonic oscillator is essential in quantum optics and quantum information processing. In a system of trapped ions, we experimentally demonstrate the projective measurement of the state of the ions' motional mode via an effective cross-Kerr coupling to another motional mode. This coupling is induced by the intrinsic nonlinearity of the Coulomb interaction between the ions. We spectroscopically resolve the frequency shift of the motional sideband of the first mode due to presence of single phonons in the second mode and use it to reconstruct the phonon number distribution of the second mode.

Thermodynamics is one of the oldest and well-established branches of physics that sets boundaries to what can possibly be achieved in macroscopic systems. While it started as a purely classical theory, it was realized in the early days of quantum mechanics that large quantum devices, such as masers or lasers, can be treated with the thermodynamic formalism. Remarkable progress has been made recently in the miniaturization of heat engines all the way to the single Brownian particle as well as to a single atom. However, despite several theoretical proposals, the implementation of heat machines in the fully quantum regime remains a challenge. Here, we report an experimental realization of a quantum absorption refrigerator in a system of three trapped ions, with three of its normal modes of motion coupled by a trilinear Hamiltonian such that heat transfer between two modes refrigerates the third. We investigate the dynamics and steady-state properties of the refrigerator and compare its cooling capability when only thermal states are involved to the case when squeezing is employed as a quantum resource. We also study the performance of such a refrigerator in the single shot regime, and demonstrate cooling below both the steady-state energy and the benchmark predicted by the classical thermodynamics treatment.

A system of harmonic oscillators coupled via nonlinear interaction is a fundamental model in many branches of physics, from biophysics to electronics and condensed matter physics. In quantum optics, weak nonlinear interaction between light modes has enabled, for example, the preparation of squeezed states of light and generation of entangled photon pairs. While strong nonlinear interaction between the modes has been realized in circuit QED systems, achieving significant interaction strength on the level of single quanta in other physical systems remains a challenge. Here we experimentally demonstrate such interaction that is equivalent to photon up- and down-conversion using normal modes of motion in a system of two Yb ions. The nonlinearity is induced by the intrinsic anharmonicity of the Coulomb interaction between the ions and can be used to simulate fully quantum operation of a degenerate optical parametric oscillator. We exploit this interaction to directly measure the parity and Wigner functions of ion motional states. The nonlinear coupling, combined with near perfect control of internal and motional states of trapped ions, can be applied to quantum computing, quantum thermodynamics, and even shed some light on the quantum information aspects of Hawking radiation.

We present a quantum logic scheme to detect atomic and molecular ions in different states of angular momentum based on their magnetic $g$-factors. The state-dependent magnetic $g$-factors mean that electronic, rotational or hyperfine states may be distinguished by their Zeeman splittings in a given magnetic field. Driving motional sidebands of a chosen Zeeman splitting enables reading out the corresponding state of angular momentum with an auxillary logic ion. As a proof-of-principle demonstration, we show that we can detect the ground electronic state of a ${^{174}}$Yb$^+$ ion using ${^{171}}$Yb$^+$ as the logic ion. Further, we can distinguish between the ${^{174}}$Yb$^+$ ion being in its ground electronic state versus the metastable ${^{2}}D_{3/2}$ state. We discuss the suitability of this scheme for the detection of rotational states in molecular ions.

We experimentally demonstrate microwave control of the motional state of a trapped ion placed in a state-dependent potential generated by a running optical lattice. Both the optical lattice depth and the running lattice frequency provide tunability of the spin-motion coupling strength. The spin-motional coupling is exploited to demonstrate sideband cooling of a Yb171 ion to the ground state of motion.