Wesley C. Campbell

Trapped ions provide a high-fidelity platform for quantum information processing, yet delivery of multiple, distinct wavelengths across large networks of interaction zones remains a bottleneck. Conventional free-space light delivery lacks scalability, while on-chip grating couplers suffer from narrow operational bandwidth that increases circuit footprint and optical interfacing complexity. Here we show a broadband photonic integrated circuit capable of addressing individual ions. The circuit combines a planar waveguide lens with a micromirror fabricated using two-photon polymerization at wafer scale. This implementation can address three individual ions from $λ$ = 405 - 880 nm with -27 dB average intensity crosstalk at $5\,μ\mathrm{m}$ pitch. We trap $^{40}\mathrm{Ca}^{+}$ and $^{138}\mathrm{Ba}^{+}$ ions above such devices, characterize optical crosstalk with barium ions, and demonstrate individual repumping of calcium ions. This monolithic photonic architecture brings broadband addressing in an on-chip modality to trapped-ion technology. More generally, integrating additive manufacturing into quantum devices is poised to unlock expanded design space for implementing novel quantum architectures.

In the presence of a magnetic field, hyperfine clock qubits can acquire a vector differential light shift that can be tuned via polarization to suppress the total differential light shift of high-power, off-resonant laser light. We experimentally measure this "magic" polarization condition, suppressing differential light shifts in both the ${}^2\mathrm{S}_{1/2}$ ground and ${}^2\mathrm{F}_{7/2}^o$ metastable clock qubits of $^{171}\mathrm{Yb}^+$. We present calculations of the minimum bias magnetic fields required to suppress differential light shifts in the ground state clock qubits of commonly trapped ion species, finding that they are below the strengths of fields already typically present in experiments. We further present methods for metastable clock-qubit control in $^{171}\mathrm{Yb}^+$, demonstrating a state preparation and measurement infidelity of $2.9^{+3.0}_{-1.5}\times10^{-4}$ ($-35 \pm 4 \, \mathrm{dB}$).

We present a spectroscopic investigation of $^{169}\mathrm{Tm}^+$ that provides two key foundations for its use as a platform for advanced quantum applications. First, we establish the complete spectroscopic road map for optical cycling (including laser cooling) by performing high-resolution spectroscopy on $^{169}\mathrm{Tm}^+$ ions in an ion trap. We characterize the primary $313\,\mathrm{nm}$ and complementary $448/453\,\mathrm{nm}$ cycling transitions, identify the essential near-infrared repumping frequencies, and determine the magnetic-dipole hyperfine $A$ constants for all relevant levels. Second, we report a detailed characterization of a metastable state as a candidate for hosting a robust qubit, performing lifetime measurements and Zeeman-resolved microwave hyperfine spectroscopy with $\mathrm{kHz}$ precision.

We report a theoretical and experimental investigation of autoionizing resonances from the $5d6p\,{}^3\mathrm{D}_1^o$ manifold in neutral barium for efficient loading of ion traps. Our calculations predict large resonant cross sections for many narrow autoionizing resonances, but we find experimentally that for most of these, Doppler broadening during trap loading depresses the effective cross sections that can be achieved in practice. We identify and demonstrate a strong, broad transition at $531\,\mathrm{nm}$, and show that it furnishes an order-of-magnitude increase in trap loading efficiency compared to other demonstrated resonances.

Modular trapped-ion (TI) architectures offer a scalable quantum computing (QC) platform, with native transport behaviors that closely resemble the Single Instruction Multiple Data (SIMD) paradigm. We present FluxTrap, a SIMD-aware compiler framework that establishes a hardware-software co-design interface for TI systems. FluxTrap introduces a novel abstraction that unifies SIMD-style instructions -- including segmented intra-trap shift SIMD (S3) and global junction transfer SIMD (JT-SIMD) operations -- with a SIMD-enriched architectural graph, capturing key features such as transport synchronization, gate-zone locality, and topological constraints. It applies two passes -- SIMD aggregation and scheduling -- to coordinate grouped ion transport and gate execution within architectural constraints. On NISQ benchmarks, FluxTrap reduces execution time by up to $3.82 \times$ and improves fidelity by several orders of magnitude. It also scales to fault-tolerant workloads under diverse hardware configurations, providing feedback for future TI hardware design.

We present a quantum averaging theory (QAT) for analytically modeling unitary gate dynamics in driven quantum systems beyond the rotating-wave approximation. QAT addresses the simultaneous presence of distinct timescales by generating a rotating frame with a dynamical phase operator that toggles with the high-frequency dynamics and yields an effective Hamiltonian for the slow degree of freedom. By accounting for the fast-varying effects, we demonstrate that high-fidelity two-qubit gates in strongly driven systems are achievable by going beyond the validity of first-order approximations. The QAT results rapidly converge with numerical calculations of a fast-entangling Mølmer-Sørensen trapped-ion-qubit gate in the strong coupling regime, illustrating QAT's ability to simultaneously provide both an intuitive, effective-Hamiltonian model and high accuracy.

We perform entanglement of spin and motional degrees of freedom of a single, ground-state trapped ion through the application of a $16$ ps laser pulse. The duration of the interaction is significantly shorter than both the motional timescale ($30$ $μ$s) and spin precession timescale ($1$ ns) , demonstrating that neither sets a fundamental speed limit on this operation for quantum information processing. Entanglement is demonstrated through the collapse and revival of spin coherence as the spin components of the wavefunction separate and recombine in phase space. We infer the fidelity of these single qubit operations to be $(97^{+3}_{-4})\%$.

Cooling of systems to sub-kelvin temperatures is usually done using either a cold bath of particles or spontaneous photon scattering from a laser field; in either case, cooling is driven by interaction with a well-ordered, cold (i.e. low entropy) system. However, there have recently been several schemes proposed for ``cooling by heating,'' in which raising the temperature of some mode drives the cooling of the desired system faster. We discuss how to cool a trapped ion to its motional ground state using unfiltered sunlight at $5800\,\mathrm{K}$ to drive the cooling. We show how to treat the statistics of thermal light in a single-mode fiber for delivery to the ion, and show experimentally how the black-body spectrum is strongly modified by being embedded in quasi-one-dimension. Quantitative estimates for the achievable cooling rate with our measured fiber-coupled, low-dimensional sunlight show promise for demonstrating this implementation of cooling by heating.

Erasures, or errors with known locations, are a more favorable type of error for quantum error-correcting codes than Pauli errors. Converting physical noise into erasures can significantly improve the performance of quantum error correction. Here we apply the idea of performing erasure conversion by encoding qubits into metastable atomic states, proposed by Wu, Kolkowitz, Puri, and Thompson [Nat. Comm. 13, 4657 (2022)], to trapped ions. We suggest an erasure-conversion scheme for metastable trapped-ion qubits and develop a detailed model of various types of errors. We then compare the logical performance of ground and metastable qubits on the surface code under various physical constraints, and conclude that metastable qubits may outperform ground qubits when the achievable laser power is higher for metastable qubits.

Trapped Be+ ions are a leading platform for quantum information science [1], but reactions with background gas species, such as H2 and H2O, result in qubit loss. Our experiment reveals that the BeOH+ ion is the final trapped ion species when both H2 and H2O exist in a vacuum system with cold, trapped Be+. To understand the loss mechanism, low-temperature reactions between sympathetically cooled BeD+ ions and H2O molecules have been investigated using an integrated, laser-cooled Be+ ion trap and high-resolution Time-of-Flight (TOF) mass spectrometer (MS) [2]. Among all the possible products,BeH2O+, H2DO+, BeOD+, and BeOH+, only the BeOH+ molecular ion was observed experimentally, with the assumed co-product of HD. Theoretical analyses based on explicitly correlated restricted coupled cluster singles, doubles, and perturbative triples (RCCSD(T)-F12) method with the augmented correlation-consistent polarized triple zeta (AVTZ) basis set reveal that two intuitive direct abstraction product channels, Be + H2DO+ and D + BeH2O+, are not energetically accessible at the present reaction temperature (~150 K). Instead, a double displacement BeOH+ + HD product channel is accessible due to a large exothermicity of 1.885 eV through a submerged barrier in the reaction pathway. While the BeOD+ + H2 product channel has a similar exothermicity, the reaction pathway is dynamically unfavourable, as suggested by a Sudden Vector Projection analysis. This work sheds light on the origin of the loss and contaminations of the laser-cooled Be+ ions in quantum-information experiments.

Internal states of polar molecules can be controlled by microwave-frequency electric dipole transitions. If the applied microwave electric field has a spatial gradient, these transitions also affect the motion of these dipolar particles. This capability can be used to engineer phonon-mediated quantum gates between e.g. trapped polar molecular ion qubits without laser illumination and without the need for cooling near the motional ground state. The result is a high-speed quantum processing toolbox for dipoles in thermal motion that combines the precision microwave control of solid-state qubits with the long coherence times of trapped ion qubits.

Dipole-phonon quantum logic (DPQL) leverages the interaction between polar molecular ions and the motional modes of a trapped-ion Coulomb crystal to provide a potentially scalable route to quantum information science. Here, we study a class of candidate molecular ions for DPQL, the cationic alkaline-earth monoxides and monosulfides, which possess suitable structure for DPQL and can be produced in existing atomic ion experiments with little additional complexity. We present calculations of DPQL operations for one of these molecules, CaO$^+$, and discuss progress towards experimental realization. We also further develop the theory of DPQL to include state preparation and measurement and entanglement of multiple molecular ions.

High quality, fully-programmable quantum processors are available with small numbers (<1000) of qubits, and the scientific potential of these near term machines is not well understood. If the small number of physical qubits precludes practical quantum error correction, how can these error-susceptible processors be used to perform useful tasks? We present a strategy for developing quantum error detection for certain gate imperfections that utilizes additional internal states and does not require additional physical qubits. Examples for adding error detection are provided for a universal gate set in the trapped ion platform. Error detection can be used to certify individual gate operations against certain errors, and the irreversible nature of the detection allows a result of a complex computation to be checked at the end for error flags.

Laser-controlled entanglement between atomic qubits (`spins') and collective motion in trapped ion Coulomb crystals requires conditional momentum transfer from the laser. Since the spin-dependent force is derived from a spatial gradient in the spin-light interaction, this force is typically longitudinal -- parallel and proportional to the average laser $k$-vector (or two beams' $k$-vector difference), which constrains both the direction and relative magnitude of the accessible spin-motion coupling. Here, we show how momentum can also be transferred perpendicular to a single laser beam due to the gradient in its transverse profile. By controlling the transverse gradient at the position of the ion through beam shaping, the relative strength of the sidebands and carrier can be tuned to optimize the desired interaction and suppress undesired, off-resonant effects that can degrade gate fidelity. We also discuss how this effect may already be playing an unappreciated role in recent experiments.

Short pulses from mode-locked lasers can produce background-free atomic fluorescence by allowing temporal separation of the prompt incidental scatter from the subsequent atomic emission. We use this to improve quantum state detection of optical-frequency and electron-shelved trapped ion qubits by more than 2 orders of magnitude. For direct detection of qubits defined on atomic hyperfine structure, however, the large bandwidth of short pulses is greater than the hyperfine splitting, and repeated excitation is not qubit state selective. Here, we show that the state resolution needed for projective quantum measurement of hyperfine qubits can be recovered by applying techniques from coherent control to the orbiting valence electron of the queried ion. We demonstrate electron wavepacket interference to allow readout of the original qubit state using broadband pulses, even in the presence of large amounts of background laser scatter.

The interaction between the electric dipole moment of a trapped molecular ion and the configuration of the confined Coulomb crystal couples the orientation of the molecule to its motion. We consider the practical feasibility of harnessing this interaction to initialize, process, and read out quantum information encoded in molecular ion qubits without optically illuminating the molecules. We present two schemes wherein a molecular ion can be entangled with a co-trapped atomic ion qubit, providing, among other things, a means for molecular state preparation and measurement. We also show that virtual phonon exchange can significantly boost range of the intermolecular dipole-dipole interaction, allowing strong coupling between widely-separated molecular ion qubits.

We consider the practical feasibility of using the direct, electric dipole-dipole interaction between co-trapped molecular ions for robust quantum logic without the need for static polarizing fields. The use of oscillating dipole moments, as opposed to static electric dipoles, dynamically decouples the dipoles from laboratory fields, including the electric fields of the trap itself. Further, this implementation does not require quantum control of motion, potentially removing a major roadblock to ion trap quantum computing scalability. Since the polarizing field is electromagnetic radiation, even pairs of states with splittings in the THz regime can be fully polarized.

An atomic transition can be addressed by a single tooth of an optical frequency comb if the excited state lifetime ($τ$) is significantly longer than the pulse repetition period ($T_\mathrm{r}$). In the crossover regime between fully-resolved and unresolved comb teeth ($τ\lessapprox T_\mathrm{r}$), we observe Doppler cooling of a pre-cooled trapped atomic ion by a single tooth of a frequency-doubled optical frequency comb. We find that for initially hot ions, a multi-tooth effect gives rise to lasing of the ion's harmonic motion in the trap, verified by acoustic injection locking. The gain saturation of this phonon laser action leads to a comb of steady-state oscillation amplitudes, allowing hot ions to be loaded directly into the trap and laser cooled to crystallization despite the presence of hundreds of blue-detuned teeth.

$^{133}\text{Ba}^+$ has been identified as an attractive ion for quantum information processing due to the unique combination of its spin-1/2 nucleus and visible wavelength electronic transitions. Using a microgram source of radioactive material, we trap and laser-cool the synthetic $A$ = 133 radioisotope of barium II in a radio-frequency ion trap. Using the same, single trapped atom, we measure the isotope shifts and hyperfine structure of the $6^2 \text{P}_{1/2}$ $\leftrightarrow$ $6^2 \text{S}_{1/2}$ and $6^2 \text{P}_{1/2}$ $\leftrightarrow$ $5^2 \text{D}_{3/2}$ electronic transitions that are needed for laser cooling, state preparation, and state detection of the clock-state hyperfine and optical qubits. We also report the $6^2 \text{P}_{1/2}$ $\leftrightarrow$ $5^2 \text{D}_{3/2}$ electronic transition isotope shift for the rare $A$ = 130 and 132 barium nuclides, completing the spectroscopic characterization necessary for laser cooling all long-lived barium II isotopes.