Xinhua Peng

Electron transfer through chiral structures can exhibit spin asymmetry, known as the chiral-induced spin selectivity effect, whose microscopic origin remains an open question. While path-interference within the chiral moiety has been proposed as a key mechanism, its experimental validation requires precise and versatile tunability of system parameters. Here we implement a programmable quantum simulation of spin-dependent electron transfer in a donor--chiral-bridge--acceptor model using a trapped ion. The bridge is encoded in internal states of the ion with tunable nearest- and next-nearest-neighbor couplings, while donor and acceptor states are coupled via a spectator bosonic motional mode. We observe spin-dependent interference within the bridge, and further reveal spin-dependence in donor-to-acceptor transfer dynamics, controlled by amplitude and phase of the coupling parameter. Our results identify interference among spin-dependent pathways as a microscopic origin of spin-dependent transfer, and open a route toward quantum simulations of complex chiral lattices with multi-level and bosonic degrees of freedom.

Squeezing a quantum state along a specific direction has long been recognized as a crucial technique for enhancing the precision of quantum metrology by reducing parameter uncertainty. However, practical quantum metrology often involves the simultaneous estimation of multiple parameters, necessitating the use of high-quality squeezed states along multiple orthogonal axes to surpass the standard quantum limit for all relevant parameters. In addition, a temporally stabilized squeezed state can provide an event-ready probe for parameters, regardless of the initial state, and robust to the timing of the state preparation process once stabilized. In this work, we generate and stabilize a two-mode squeezed state along two secular motional modes in a vibrating trapped ion with reservoir engineering, despite starting from a thermal state of the motion. Leveraging this resource, we demonstrate an estimation of two simultaneous collective displacements along the squeezed axes, achieving improvements surpassing the classical limit by up to 6.9(3) and 7.0(3) decibels (dB), respectively. Our demonstration can be readily scaled to squeezed states with even more modes. The practical implications of our findings span a wide range of applications, including quantum sensing, quantum imaging, and various fields that demand precise measurements of multiple parameters.