Yue Li

Temporal non-analyticities in the rate function of the Loschmidt echo manifests a class of dynamical quantum phase transitions (DQPTs) that has emerged as a powerful framework for understanding far-from-equilibrium many-body dynamics. While such DQPT has been extensively studied theoretically in spin-boson systems such as the Dicke model, their experimental observation remains elusive. In particular, the dynamics of DQPT in asymmetric spin subspaces and under the influence of spin dissipation are largely unexplored. Here, we report an experimental study of temporal DQPT in a generalized Dicke model using a trapped-ion quantum simulator. By coupling a linear chain of $\rm{^{40}Ca^{+}}$ ions to a collective center-of-mass motional mode, we probe the quench dynamics starting from both symmetric and asymmetric initial states. We extract the rate function and identify temporal turn-around points that are in quantitative agreement with theoretical predictions. Additionally, we investigate the impact of spin dissipation on these dynamics. Our results establish an experimental platform for probing complex many-body out-of-equilibrium phenomena and advance the development of hybrid oscillator-spin quantum simulators.

Aharonov-Bohm (AB) caging is a complete localization phenomenon in two-dimensional lattices due to destructive interference induced by the background gauge fields. However, current investigations of AB caging are mostly restricted to the Abelian gauge field case, and the observation of AB caging under non-Abelian gauge fields in a quantum system still remains elusive. Here, we report experimental realization of tunable synthetic non-Abelian SU(2) gauge fields in a rhombic lattice, engineered within the synthetic dimensions of a vibrating trapped ion with multiple levels. We realize AB caging under both Abelian and non-Abelian gauge fields and systematically investigate the distinctive transport properties of the non-Abelian case. In particular, we observe typical emergent quantum dynamics unique to non-Abelian AB caging, including initial-state-dependent dynamics, second-order effects, and asymmetric caging behavior. These observations demonstrate the trapped ion system as a powerful platform for simulating emergent phenomena in high-dimensional quantum systems with exotic synthetic gauge fields.

The Unruh effect predicts an astonishing phenomenon that an accelerated detector would detect counts despite being in a quantum field vacuum in the rest frame. Since the required detector acceleration for its direct observation is prohibitively large, recent analog studies on quantum simulation platforms help to reveal various properties of the Unruh effect and explore the not-yet-understood physics of quantum gravity. To further reveal the quantum aspect of the Unruh effect, analogous experimental exploration of the correlation between the detector and the field, and the consequences for coherent quantum trajectories of the detector without classical counterparts, are essential steps but are currently missing. Here, we utilize a laser-controlled trapped ion to experimentally simulate an oscillating detector coupled with a cavity field. We observe joint excitation of both the detector and the field in the detector's frame, coincide with the coordinated dynamics predicted by the Unruh effect. Particularly, we simulate the detector moving in single and superposed quantum trajectories, where the latter case shows coherent interference of excitation. Our demonstration reveals properties of quantum coherent superposition of accelerating trajectories associated with quantum gravity theories that have no classical counterparts, and may offer a new avenue to investigate phenomena in quantum field theory and quantum gravity. We also show how a generalization of the method and results in this work may be beneficial for direct observation of the Unruh effect.

Atomic interface engineering (AIE) is critical for advancing technologies in energy storage, catalysis, and microelectronics. In anode-less lithium metal batteries (ALLMBs), AIE is essential for controlling interfacial chemistry governing lithium deposition and solid electrolyte interphase (SEI) formation on copper current collectors. However, native copper surfaces readily oxidize, forming electronically insulating oxides that degrade performance and obscure failure mechanisms. Here, we report a scalable ion implantation strategy to create an atomically clean and robust copper interface. By implanting copper ions into commercial foils, we simultaneously remove the native oxide and introduce subsurface vacancy clusters that act as oxygen traps, yielding an oxidation-resistant and conductive surface. Experimental characterization and multiscale simulations reveal that these engineered vacancies suppress reoxidation and guide the formation of an ultrathin Li2O-enriched solid electrolyte interphase. When applied in ALLMBs, the current collectors enable uniform lithium deposition, suppress parasitic reactions, and deliver a Coulombic efficiency of 99.0% over 400 cycles under lean electrolyte conditions. This work presents a generalizable and industry-compatible approach for stabilizing electrochemical interfaces.

Trapped-ion systems are one of the leading platforms for quantum information processing, where a key challenge is to scale up system size while maintaining high-fidelity two-qubit operations. A promising approach is to build high-performance modules interconnected via strong coupling. In particular, axial motional modes provide a feasible means of coupling short ion chains. However, previous implementations of fully connected 5-ion modules based on axial modes have been limited to fidelities of $96.6-98.0\%$. Here, we demonstrate two-qubit quantum logic gates in a 5-ion $^{40}$Ca$^{+}$ chain using axial modes, achieving fidelities exceeding $99\%$ for adjacent pairs and over $98\%$ for arbitrary pairs by carefully tackling dominant error sources. Our results are beneficial to the development of scalable ion-trap quantum processors, quantum simulation and quantum-enhanced metrology.

In the lattice system, when the synthetic flux reaches a $π$ phase along a closed loop under the synthetic gauge field, destructive interference occurs and gives rise to the localization phenomenon. This is known as the Aharonov-Bohm (AB) caging effect. It provides a powerful tool for the study of quantum transportation and dynamical effects. In the system where lattice sites possess internal structure and the underlying gauge field is non-Abelian, localization can also occur, forming the non-Abelian AB caging. Here, we propose an experimental scheme to synthesize non-Abelian gauge fields with a single trapped ion by coupling multiple internal levels and Fock states in its motion via laser fields. In contrast to the Abelian AB caging, we numerically observe that the non-Abelian AB caging occurs either when the interference matrix is nilpotent, or when the initial state is specifically set. Our experimental scheme broadens the study of localization phenomena and provides a novel tool for the study of non-Abelian physics.

Quantum error correction (QEC) is essential for practical quantum computing, as it protects fragile quantum information from errors by encoding it in high-dimensional Hilbert spaces. Conventional QEC protocols typically require repeated syndrome measurements, real-time feedback, and the use of multiple physical qubits for encoding. Such implementations pose significant technical complexities, particularly for trapped-ion systems, with high demands on precision and scalability. Here, we realize autonomous QEC with a logical qubit encoded in multiple internal spin states of a single trapped ion, surpassing the break-even point for qubit lifetime. Our approach leverages engineered spin-motion couplings to transfer error-induced entropy into motional modes, which are subsequently dissipated through sympathetic cooling with an ancilla ion, fully eliminating the need for measurement and feedback. By repetitively applying this autonomous QEC protocol under injected low-frequency noise, we extend the logical qubit lifetime to approximately 11.6 ms, substantially outperforming lifetime for both the physical qubit ($\simeq$0.9 ms) and the uncorrected logical qubit ($\simeq$0.8 ms), thereby beating the break-even point with autonomous protection of quantum information without measurement or post-selection. This work presents an efficient approach to fault-tolerant quantum computing that harnesses the intrinsic multi-level structure of trapped ions, providing a distinctive path toward scalable architectures and robust quantum memories with reduced overhead.

Symmetry is crucial for gaining insights into the fundamental properties of physical systems, bringing possibilities in studying exotic phenomena such as quantum phase transitions and ground state entanglement. Here, we experimentally simulate a highly controllable extended quantum Rabi model, capable of tuning into the ultra-strong or deep coupling regime, in a spin-motion-coupled trapped ion. We observe that the phonon driven by such a model with parity symmetry preserved (broken) would experience double (single) excitation in the ultra-strong coupling regime. Quantum phenomena such as strong ground state entanglement and quantum superposition in systems occur with parity symmetry, and these phenomena disappear following the symmetry breaking. We also find sensitive responses for the two-level system entropy and phonon Wigner function in the deep coupling regime, depending on the parameter across the symmetry transition point. This work offers the prospect of exploring symmetry-controlled quantum phenomena and their applications in high-precision quantum technologies.

The nontrivial degeneracies in non-Hermitian systems, exceptional points (EPs), have attracted extensive attention due to intriguing phenomena. Compared with commonly observed second-order EPs, high-order EPs show rich physics due to their extended dimension and parameter space, ranging from the coalescence of EPs into higher order to potential applications in topological properties. However, these features also pose challenges in controlling multiple coherent and dissipative elements in a scaled system. Here we experimentally demonstrate a native programmable control to simulate a high-order non-Hermitian Hamiltonian in a multi-dimensional trapped ion system. We simulate a series of non-Hermitian systems with varied parameters and observe the coalescence of second-order EPs into a fourth-order EP. Our results pave the way for scalable quantum simulation of high-dimensional dissipative systems and can be beneficial for the application of high-order EPs in quantum sensing and quantum control.

Quantum friction, a quantum analog of classical friction, reduces the performance of quantum machines, such as heat engines, and makes them less energy efficient. We here report the experimental realization of an energy efficient quantum engine coupled to a quantum battery that stores the produced work, using a single ion in a linear Paul trap. We first establish the quantum nature of the device by observing nonclassical work oscillations with the number of cycles as verified by energy measurements of the battery. We moreover successfully apply shortcut-to-adiabaticity techniques to suppress quantum friction and improve work production. While the average energy cost of the shortcut protocol is only about $3\%$, the work output is enhanced by up to approximately 33$\%$, making the machine significantly more energy efficient. In addition, we show that the quantum engine consistently outperforms its classical counterpart in this regime. Our results pave the way for energy efficient machines with quantum-enhanced performance.

Squeezing a quantum state along a specific direction has long been recognized as a crucial technique for enhancing the precision of quantum metrology by reducing parameter uncertainty. However, practical quantum metrology often involves the simultaneous estimation of multiple parameters, necessitating the use of high-quality squeezed states along multiple orthogonal axes to surpass the standard quantum limit for all relevant parameters. In addition, a temporally stabilized squeezed state can provide an event-ready probe for parameters, regardless of the initial state, and robust to the timing of the state preparation process once stabilized. In this work, we generate and stabilize a two-mode squeezed state along two secular motional modes in a vibrating trapped ion with reservoir engineering, despite starting from a thermal state of the motion. Leveraging this resource, we demonstrate an estimation of two simultaneous collective displacements along the squeezed axes, achieving improvements surpassing the classical limit by up to 6.9(3) and 7.0(3) decibels (dB), respectively. Our demonstration can be readily scaled to squeezed states with even more modes. The practical implications of our findings span a wide range of applications, including quantum sensing, quantum imaging, and various fields that demand precise measurements of multiple parameters.

Quantum information processing with multi-level systems (qudits) provides additional features and applications than the two-level systems. However, qudits are more prone to dephasing and dynamical decoupling for qudits has never been experimentally demonstrated. Here, as a proof-of-principle demonstration, we experimentally apply dynamical decoupling to protect superpositions with three levels of a trapped $^9\rm{Be}^+$ ion from ambient noisy magnetic field, prolonging coherence by up to approximately an order of magnitude. Our demonstration, straightforwardly scalable to more levels, may open up a path toward long coherence quantum memory, metrology and information processing with qudits.

Triply degenerate points (TDPs), which correspond to new types of topological semimetals, can support novel quasiparticles possessing effective integer spins while preserving Fermi statistics. Here by mapping the momentum space to the parameter space of a three-level system in a trapped ion, we experimentally explore the transitions between different types of TDPs driven by spin-tensor--momentum couplings. We observe the phase transitions between TDPs with different topological charges by measuring the Berry flux on a loop surrounding the gap-closing lines, and the jump of the Berry flux gives the jump of the topological charge (up to a $2π$ factor) across the transitions. For the Berry flux measurement, we employ a new method by examining the geometric rotations of both spin vectors and tensors, which lead to a generalized solid angle equal to the Berry flux. The controllability of multi-level ion offers a versatile platform to study high-spin physics and our work paves the way to explore novel topological phenomena therein.

Along with the scaling of dimensions in quantum systems, transitions between the system's energy levels would become close in frequency, which are conventionally resolved by weak and lengthy pulses. Here, we extend and experimentally demonstrate analytically based swift quantum control techniques on a four-level trapped ion system, where we perform individual or simultaneous control over two pairs of spectrally nearby transitions with tailored time-varied drive, achieving operational fidelities ranging from 99.2(3)\% to 99.6(3)\%. Remarkably, we achieve approximately an order of magnitude speed up comparing with the case of weak square pulse for a general control. Therefore, our demonstration may be beneficial to a broad range of quantum systems with crowded spectrum, for spectroscopy, quantum information processing and quantum simulation.