C. S. Sumithrarachchi

Although it is known that the $N=28$ spherical shell closure erodes, the strength of the closure with decreasing proton number $Z<20$ is an open question in nuclear structure. In this region of interest, direct high-precision mass measurements of neutron-rich $^{43-45}$Cl isotopes were performed at the Low Energy Beam and Ion Trap (LEBIT) when coupled to the National Superconducting Cyclotron Lab. The resulting mass excesses (MEs) are ME($^{43}$Cl) = -24114.4(1.7) keV, ME($^{44}$Cl) = -20450.8(10.6) keV, and ME($^{45}$Cl) = -18240.1(3.7) keV, and improve the uncertainty of these masses by up to a factor of ~40 compared to the previous values reported in the 2020 Atomic Mass Evaluation. Comparison to $\textit{ab initio}$ calculations using the Valence-Space In-Medium Similarity Renormalization Group (VS-IMSRG) shows good agreement up to and including the closure.

We present a high-precision mass measurement of the proton-rich nucleus 23Si, performed with the LEBIT Penning trap at the Facility for Rare Isotope Beams (FRIB) utilizing the time-of-flight ion cyclotron resonance (TOF-ICR) technique. We determined a mass excess of 23362.9(5.8) keV, which agrees with a recent storage-ring measurement from CSRe but has a factor 20 improved precision. 23Si is hence the nucleus with the most precisely known mass of all nuclei with an isospin projection of Tz =-5/2. We performed shell-model calculations with the USDC and USDCm Hamiltonians to study binding energy differences and Thomas-Ehrmann shifts in mirror systems with an isospin up to T = 5/2. Our experimental result and other recently reported masses of neutron-deficient sd-shell nuclei agree well with the theoretical predictions, demonstrating that isospin symmetry breaking in sd-shell nuclei, even at high isospin values, is well described by modern shell-model calculations.

As a step towards the ultimate goal of a high-precision mass measurement of doubly-magic $^{100}$Sn, the mass of $^{103}$Sn was measured at the Low Energy Beam and Ion Trap (LEBIT) located at the Facility for Rare Isotope Beams (FRIB). Utilizing the time-of-flight ion cyclotron resonance (ToF-ICR) technique, a mass uncertainty of 3.7~keV was achieved, an improvement by more than an order of magnitude compared to a recent measurement performed in 2023 at the Cooler Storage Ring (CSRe) in Lanzhou. Although the LEBIT and CSRe mass measurements of $^{103}$Sn are in agreement, they diverge from the experimental mass value reported in the 2016 version of the Atomic Mass Evaluation (AME2016), which was derived from the measured $Q_{β^+}$ value and the mass of $^{103}$In. In AME2020, this indirectly measured $^{103}$Sn mass was classified as a `seriously irregular mass' and replaced with an extrapolated value, which aligns with the most recent measured values from CSRe and LEBIT. As such, the smoothness of the mass surface is confidently reestablished for $^{103}$Sn. Furthermore, LEBIT's mass measurement of $^{103}$Sn enabled a significant reduction in the mass uncertainties of five parent isotopes which are now dominated by uncertainties in their respective $Q$-values.

We report the first direct measurement of the nuclear electron capture (EC) decay $Q$-value of $^{7}$Be $\rightarrow$ $^{7}$Li via high-precision Penning trap mass spectrometry (PTMS). This was performed using the LEBIT Penning trap located at the National Superconducting Cyclotron Laboratory/Facility for Rare Isotope Beams (NSCL/FRIB) using the newly commissioned Batch-Mode Ion-Source (BMIS) to deliver the unstable $^{7}$Be$^{+}$ samples. With a measured value of $Q_{EC}$ = 861.963(23) keV this result is also three times more precise than any previous determination of this quantity. This improved precision, and accuracy of the $^7$Be EC decay $Q$-value is critical for ongoing experiments that measure the recoiling nucleus in this system as a signature to search for beyond Standard Model (BSM) neutrino physics using $^7$Be-doped superconducting sensors.

Background: Low energy $β$ and electron capture (EC) decays are important systems in neutrino mass determination experiments. An isotope with an ultra-low Q value $β$-decay to an excited state in the daughter with Qes < 1 keV could provide a promising alternative candidate for future experiments. $^{75}$Se EC and $^{75}$Ge $β$-decay represent such candidates, but a more precise determination of the mass of the common daughter, $^{75}$As, is required to evaluate whether their potential decay branches are energetically allowed and ultra-low. Purpose: Perform a precise atomic mass measurement of $^{75}$As and combine the result with the precisely known atomic masses of $^{75}$Se and $^{75}$Ge, along with nuclear energy level data for $^{75}$As to evaluate potential ultra-low Q value decay branches in the EC decay of $^{75}$Se and the $β$-decay of $^{75}$Ge. Method: The LEBIT Penning trap mass spectrometer at the Facility for Rare Isotope Beams was used to perform a high-precision measurement of the atomic mass of $^{75}$As via cyclotron frequency ratio measurements of $^{75}$As$^{+}$ to a $^{12}$C$_{6}^{+}$ reference ion. Results: The $^{75}$As mass excess was determined to be ME($^{75}$As)= -73 035.98(43) keV, from which the ground-state to ground-state Q values for $^{75}$Se EC and $^{75}$Ge $β$-decay were determined to be 866.50(44) keV and 1179.01(44) keV, respectively. These results were compared to energies of excited states in $^{75}$As at 865.4(5) keV and 1172.0(6) keV to determine Q values of 1.1(7) keV and 7.0(7) keV for the potential ultra-low EC and $β$-decay branches of $^{75}$Se and $^{75}$Ge, respectively. Conclusion: The $^{75}$Se EC decay to the 865.4 keV excited state in $^{75}$As is potentially ultra-low with Qes $\approx$ 1 keV. However, a more precise determination of the 865.4(5) keV level in $^{75}$As is required.

Isobaric quintets provide the best test of the isobaric multiplet mass equation (IMME) and can uniquely identify higher order corrections suggestive of isospin symmetry breaking effects in the nuclear Hamiltonian. The Generalized IMME (GIMME) is a novel microscopic interaction theory that predicts an extension to the quadratic form of the IMME. Only the $A=20, 32$ $T=2$ quintets have the exotic $T_z = -2$ member ground state mass determined to high-precision by Penning trap mass spectrometry. In this work, we establish $A=36$ as the third high-precision $T=2$ isobaric quintet with the $T_z = -2$ member ground state mass measured by Penning trap mass spectrometry and provide the first test of the predictive power of the GIMME. A radioactive beam of neutron-deficient $^{36}$Ca was produced by projectile fragmentation at the National Superconducting Cyclotron Laboratory. The beam was thermalized and the mass of $^{36}$Ca$^+$ and $^{36}$Ca$^{2+}$ measured by the Time of Flight - Ion Cyclotron Resonance method in the LEBIT 9.4 T Penning trap. We measure the mass excess of $^{36}$Ca to be ME$ = -6483.6(56)$ keV, an improvement in precision by a factor of 6 over the literature value. The new datum is considered together with evaluated nuclear data on the $A=36$, $T=2$ quintet. We find agreement with the quadratic form of the IMME given by isospin symmetry, but only coarse qualitative agreement with predictions of the GIMME. A total of three isobaric quintets have their most exotic members measured by Penning trap mass spectrometry. The GIMME predictions in the $T = 2$ quintet appear to break down for $A = 32$ and greater.

The region near Z=28, N=40 is a subject of great interest for nuclear structure studies due to spectroscopic signatures in $^{68}$Ni suggesting a subshell closure at N=40. Trends in nuclear masses and their derivatives provide a complementary approach to shell structure investigations via separation energies. Penning trap mass spectrometry has provided precise measurements for a number of nuclei in this region, however a complete picture of the mass surfaces has so far been limited by the large uncertainty remaining for nuclei with N > 40 along the iron and cobalt chains. Here we present the first Penning trap measurements of $^{68,69}$Co, performed at the Low-Energy Beam and Ion Trap facility at the National Superconducting Cyclotron Laboratory. In addition, we perform ab initio calculations of ground state and two-neutron separation energies of cobalt isotopes with the valence-space in-medium similarity renormalization group approach based on a particular set of two- and three-nucleon forces which predict saturation in infinite matter. We discuss the importance of these measurements and calculations for understanding the evolution of nuclear structure near $^{68}$Ni.