D. N. Stacey

We describe a simple approach to the problem of incorporating the response time of an atom or ion being Doppler-cooled into the theory of the cooling process. The system being cooled does not in general respond instantly to the changing laser frequencies it experiences in its rest frame, and this "dynamic effect" can affect significantly the temperatures attainable. It is particularly important for trapped ions when there is a slow decay out of the cooling cycle requiring the use of a repumping beam. We treat the cases of trapped ions with two and three internal states, then apply the theory to $^{40}{\rm Ca}^+$. For this ion experimental data exist showing the ion to be cold under conditions for which heating is predicted if the dynamic effect is neglected. The present theory accounts for the observed behaviour.

We demonstrate simple and robust methods for Doppler cooling and obtaining high fluorescence from trapped 43Ca+ ions at a magnetic field of 146 Gauss. This field gives access to a magnetic-field-independent "atomic clock" qubit transition within the ground level hyperfine structure of the ion, but also causes the complex internal structure of the 64 states relevant to Doppler cooling to be spread over many times the atomic transition line-width. Using a time-dependent optical Bloch equation simulation of the system we develop a simple scheme to Doppler-cool the ion on a two-photon dark resonance, which is robust to typical experimental variations in laser intensities, detunings and polarizations. We experimentally demonstrate cooling to a temperature of 0.3 mK, slightly below the Doppler limit for the corresponding two-level system, and then use Raman sideband laser cooling to cool further to the ground states of the ion's radial motional modes. These methods will enable two-qubit entangling gates with this ion, which is one of the most promising qubits so far developed.

Entanglement is one of the most fundamental properties of quantum mechanics, and is the key resource for quantum information processing. Bipartite entangled states of identical particles have been generated and studied in several experiments, and post-selected or heralded entangled states involving pairs of photons, single photons and single atoms, or different nuclei in the solid state, have also been produced. Here, we use a deterministic quantum logic gate to generate a "hybrid" entangled state of two trapped-ion qubits held in different isotopes of calcium, perform full tomography of the state produced, and make a test of Bell's inequality with non-identical atoms. We use a laser-driven two-qubit gate, whose mechanism is insensitive to the qubits' energy splittings, to produce a maximally-entangled state of one Ca-40 qubit and one Ca-43 qubit, held 3.5 microns apart in the same ion trap, with 99.8(6)% fidelity. We test the Clauser-Horne-Shimony-Holt (CHSH) version of Bell's inequality for this novel entangled state and find that it is violated by 15 standard deviations; in this test, we close the detection loophole but not the locality loophole. Mixed-species quantum logic is a powerful technique for the construction of a quantum computer based on trapped ions, as it allows protection of memory qubits while other qubits undergo logic operations, or are used as photonic interfaces to other processing units. The entangling gate mechanism used here can also be applied to qubits stored in different atomic elements; this would allow both memory and logic gate errors due to photon scattering to be reduced below the levels required for fault-tolerant quantum error correction, which is an essential pre-requisite for general-purpose quantum computing.

We implement all single-qubit operations with fidelities significantly above the minimum threshold required for fault-tolerant quantum computing, using a trapped-ion qubit stored in hyperfine "atomic clock" states of $^{43}$Ca$^+$. We measure a combined qubit state preparation and single-shot readout fidelity of 99.93%, a memory coherence time of $T^*_2=50$ seconds, and an average single-qubit gate fidelity of 99.9999%. These results are achieved in a room-temperature microfabricated surface trap, without the use of magnetic field shielding or dynamic decoupling techniques to overcome technical noise.

We describe the design, fabrication and testing of a surface-electrode ion trap, which incorporates microwave waveguides, resonators and coupling elements for the manipulation of trapped ion qubits using near-field microwaves. The trap is optimised to give a large microwave field gradient to allow state-dependent manipulation of the ions' motional degrees of freedom, the key to multiqubit entanglement. The microwave field near the centre of the trap is characterised by driving hyperfine transitions in a single laser-cooled 43Ca+ ion.

We demonstrate a Doppler cooling and detection scheme for ions with low-lying D levels which almost entirely suppresses scattered laser light background, while retaining a high fluorescence signal and efficient cooling. We cool a single ion with a laser on the 2S1/2 to 2P1/2 transition as usual, but repump via the 2P3/2 level. By filtering out light on the cooling transition and detecting only the fluorescence from the 2P_3/2 to 2S1/2 decays, we suppress the scattered laser light background count rate to 1 per second while maintaining a signal of 29000 per second with moderate saturation of the cooling transition. This scheme will be particularly useful for experiments where ions are trapped in close proximity to surfaces, such as the trap electrodes in microfabricated ion traps, which leads to high background scatter from the cooling beam.

We describe the fabrication and characterization of a new surface-electrode Paul ion trap designed for experiments in scalable quantum information processing with Ca+. A notable feature is a symmetric electrode pattern which allows rotation of the normal modes of ion motion, yielding efficient Doppler cooling with a single beam parallel to the planar surface. We propose and implement a technique for micromotion compensation in all directions using an infrared repumper laser beam directed into the trap plane. Finally, we employ an alternate repumping scheme that increases ion fluorescence and simplifies heating rate measurements obtained by time-resolved ion fluorescence during Doppler cooling.

We demonstrate sympathetic cooling of a 43Ca+ trapped-ion "memory" qubit by a 40Ca+ "coolant" ion near the ground state of both axial motional modes, whilst maintaining coherence of the qubit. This is an essential ingredient in trapped-ion quantum computers. The isotope shifts are sufficient to suppress decoherence and phase shifts of the memory qubit due to the cooling light which illuminates both ions. We measure the qubit coherence during 10 cycles of sideband cooling, finding a coherence loss of 3.3% per cooling cycle. The natural limit of the method is O(0.01%) infidelity per cooling cycle.

We demonstrate long-lived coherence in internal hyperfine states of a single \Ca{43} trapped-ion qubit $[T_2=1.2(2)\s]$, and in external motional states of a single \Ca{40} trapped-ion qubit $[T_2'=0.18(4)\s]$, in the same apparatus. The motional decoherence rate is consistent with the heating rate, which was measured to be 3(1) quanta/sec. Long coherence times in the external motional states are essential for performing high-fidelity quantum logic gates between trapped-ion qubits. The internal-state $T_2$ time that we observe in \Ca{43}, which has not previously been used as a trapped-ion qubit, is about one thousand times longer than that of physical qubits based on \Ca{40} ions. Using a single spin-echo pulse to ``re-phase'' the internal state, we can detect no decoherence after 1\s, implying an effective coherence time $T_2^{\mbox{\tiny SE}} \gtish 45\s$. This compares with timescales in this trap for single-qubit operations of \ish 1\us, and for two-qubit operations of \ish 10\us.

We create entangled states of the spin and motion of a single $^{40}$Ca$^+$ ion in a linear ion trap. The motional part consists of coherent states of large separation and long coherence time. The states are created by driving the motion using counterpropagating laser beams. We theoretically study and experimentally observe the behaviour outside the Lamb-Dicke regime, where the trajectory in phase space is modified and the coherent states become squeezed. We directly observe the modification of the return time of the trajectory, and infer the squeezing. The mesoscopic entanglement is observed up to $Δα= 5.1$ with coherence time 170 microseconds and mean phonon excitation $\nbar = 16$.

We have implemented a universal quantum logic gate between qubits stored in the spin state of a pair of trapped calcium 40 ions. An initial product state was driven to a maximally entangled state deterministically, with 83% fidelity. We present a general approach to quantum state tomography which achieves good robustness to experimental noise and drift, and use it to measure the spin state of the ions. We find the entanglement of formation is 0.54.

We present studies of resonance-enhanced photo-ionization for isotope-selective loading of Ca+ into a Paul trap. The 4s^2 ^1S_0 <-> 4s4p ^1P_1 transition of neutral calcium is driven by a 423nm laser and the atoms are photo-ionized by a second laser at 389nm. Isotope-selectivity is achieved by using crossed atomic and laser beams to reduce the Doppler width significantly below the isotope shifts in the 423nm transition. The loading rate of ions into the trap is studied under a range of experimental parameters for the abundant isotope 40Ca+. Using the fluorescence of the atomic beam at 423nm as a measure of the Ca number density, we estimate a lower limit for the absolute photo-ionization cross-section. We achieve loading and laser-cooling of all the naturally occurring isotopes, without the need for enriched sources. Laser-heating/cooling is observed to enhance the isotope-selectivity. In the case of the rare species 43Ca+ and 46Ca+, which have not previously been laser-cooled, the loading is not fully isotope-selective but we show that pure crystals of 43Ca+ may nevertheless be obtained. We find that for loading 40Ca+ the 389nm laser may be replaced by an incoherent source.

We report a precise search for correlation effects in linear chains of 2 and 3 trapped Ca+ ions. Unexplained correlations in photon emission times within a linear chain of trapped ions have been reported, which, if genuine, cast doubt on the potential of an ion trap to realize quantum information processing. We observe quantum jumps from the metastable 3d 2D_{5/2} level for several hours, searching for correlations between the decay times of the different ions. We find no evidence for correlations: the number of quantum jumps with separations of less than 10 ms is consistent with statistics to within errors of 0.05%; the lifetime of the metastable level derived from the data is consistent with that derived from independent single-ion data at the level of the experimental errors 1%; and no rank correlations between the decay times were found with sensitivity to rank correlation coefficients at the level of |R| = 0.024.

We report a measurement of the lifetime of the 3d 2D_{5/2} metastable level in 40Ca+, using quantum jumps of a single cold calcium ion in a linear Paul trap. The 4s S_{1/2} - 3d D_{5/2} transition is significant for single-ion optical frequency standards, astrophysical references, and tests of atomic structure calculations. We obtain tau = 1.168 +- 0.007 s from observation of nearly 64,000 quantum jumps during approximately 32 hours. Our result is more precise and significantly larger than previous measurements. Experiments carried out to quantity systematic effects included a study of a previously unremarked source of systematic error, namely excitation by the broad background of radiation emitted by a semiconductor diode laser. Combining our result with atomic structure calculations yields 1.20 +- 0.01 s for the lifetime of 3d D_{3/2}. We also use quantum jump observations to demonstrate photon anti-bunching, and to estimate background pressure and heating rates in the ion trap.