Igor Lesanovsky

Trapped ions excited to high-lying electronic states, so-called Rydberg states, open new opportunities for quantum simulation and quantum computing. Generally, the fidelity of quantum coherent operations critically depends on the longevity of Rydberg states. However, scaling laws predict that the lifetimes of Rydberg states in singly charged alkaline-earth metal ions are 16 times shorter, compared to their neutral atom counterparts. Here, we show that this is not generally the case. We report an anomalous lifetime enhancement of certain low angular momentum ionic Rydberg series by factors larger than eight. The anomaly is present at both zero and finite temperature, although it is caused by different mechanisms. At zero temperature, the anomalously enhanced lifetimes are caused by accidental cancellations of the relevant dipole transition matrix elements, while at room temperature the anomaly originates from the enlarged energetic separation of ionic Rydberg levels with respect to neutral-atom levels.

Quanta emitted by an open quantum system carry information about intrinsic parameters, enabling their estimation via continuous monitoring. In practice, however, only a fraction of the emitted quanta is detected, reducing the achievable sensitivity. Here, we consider few-level systems in which coherent couplings and dissipative processes compete, producing metastable dynamics characterized by emission intermittency or by the emergence of a dark state. We show that both phenomena can be beneficial for sensing but their relative performance depends strongly on the achievable detection efficiencies. Intermittent emission, marked by long alternating bright and dark periods, allows to achieve robustness with respect to inefficient detection and dephasing, whereas dark states yield significantly higher sensitivity at unit detection efficiency. Yet the latter are highly susceptible to losses. We quantify the impact of inefficient detection through the classical Fisher information of the emission record and benchmark it against the ultimate sensitivity encoded in the joint system-environment state. Finally, we demonstrate that maximum-likelihood estimators based on the observed emission record can effectively approach this sensitivity. We focus here on trapped-ion systems, however, the results extend to other quantum platforms in which similar emission dynamics can be observed.

Trapped ions excited to high-lying electronic states combine strongly coupled collective vibrational and electronic degrees of freedom with long-ranged interparticle interactions. These ingredients enable the quantum simulation of biochemical processes, associated with the dynamics of excitons in non-perturbative parameter regimes. The key feature of such a quantum simulator are electronic-state-dependent molecular potential surfaces which can be strongly coupled. This allows to shed light on a variety of mechanisms underlying exciton transport. We illustrate this in a system of three trapped ions, which is amenable to an ab initio treatment. Given that ion traps can be routinely prepared with hundreds of ions, these quantum simulators can immediately realise scenarios which are inaccessible by current numerical methods.

Quantum simulation of interacting many-body spin systems is routinely performed with cold trapped ions, and systems with hundreds of spins have been studied in one and two dimensions. In the most common realizations of these platforms, spin degrees of freedom are encoded in low-lying electronic levels, and interactions among the spins are mediated through crystal vibrations. Here we propose a new approach which enables the quantum simulation of two-dimensional spin systems with interaction strengths that are increased by orders of magnitude. This, together with the unprecedented longevity of trapped ions, opens an avenue for the exploration of phenomena that take place on long timescales, e.g., slow and collective relaxation in frustrated and kinetically constrained systems. Our platform makes use of the strong dipolar interactions among electronic Rydberg states and planar confinement provided by a Penning trap. We investigate how the strong electric and magnetic fields that form this trap affect the properties of the Rydberg states and show that spin-spin interaction strengths on the order of MHz are achievable under experimentally realistic conditions. As a brief illustration of the capabilities of this quantum simulator, we study the entanglement in a frustrated spin system realized by three ions.

Trapped ions as one of the most promising quantum-information-processing platforms, yet conventional entangling gates mediated by collective motion remain slow and difficult to scale. Exciting trapped ions to high-lying electronic Rydberg states provides a promising route to overcome these limitations by enabling strong, long-range dipole-dipole interactions that support much faster multi-qubit operations. Here, we introduce the first scheme for implementing a native controlled-controlled-Z gate with microwave-dressed Rydberg ions by optimizing a single-pulse protocol that accounts for the finite Rydberg-state lifetime. The resulting gate outperforms standard decompositions into one- and two-qubit gates by achieving fidelities above 97% under realistic conditions, with execution times of about 2 microseconds at cryogenic temperatures. To explore the potential of trapped Rydberg ions for fault-tolerant quantum error correction, and to illustrate the utility of three-qubit Rydberg-ion gates in this context, we develop and analyze a proposal for fault-tolerant, measurement-free quantum error correction using the nine-qubit Bacon-Shor code. Our simulations confirm that quantum error correction can be performed in a fully fault-tolerant manner on a linear Rydberg-ion chain despite its limited qubit connectivity. These results establish native multiqubit Rydberg-ion gates as a valuable resource for fast, high-fidelity quantum computing and highlight their potential for fault-tolerant quantum error correction.

State-dependent conformational changes play a central role in molecular dynamics, yet they are often difficult to observe or simulate due to their complexity and ultrafast nature. One alternative approach is to emulate such phenomena using quantum simulations with cold, trapped ions. In their electronic ground state, these ions form long-lived Wigner crystals. When excited to high-lying electronic Rydberg states, the ions experience a modified trapping potential, resulting in a strong coupling between their electronic and vibrational degrees of freedom. In an ion crystal, this vibronic coupling creates electronic state-dependent potential energy surfaces that can support distinct crystal structures -- closely resembling the conformational changes of molecules driven by electronic excitations. Here, we present the first experimental observation of this effect, by laser-coupling a single ion at the centre of a three-ion crystal to a Rydberg state. By tuning the system close to a structural phase transition, the excitation induces a state-dependent conformational change, transforming the Wigner crystal from a linear to a zigzag configuration. This structural change leads to a strong hybridisation between vibrational and electronic states, producing a clear spectroscopic signature in the Rydberg excitation. Our findings mark the first experimental step towards using Rydberg ions to create and study artificial molecular systems. change leads to a strong hybridisation between vibrational and electronic states, producing a clear spectroscopic signature in the Rydberg excitation. Our findings mark the first experimental step towards using Rydberg ions to create and study artificial molecular systems.

Quantum systems in nonequilibrium conditions, where coherent many-body interactions compete with dissipative effects, can feature rich phase diagrams and emergent critical behavior. Associated collective effects, together with the continuous observation of quanta dissipated into the environment -- typically photons -- allow to achieve quantum enhanced parameter estimation. However, protocols for tapping this enhancement typically involve intricate measurements on the combined system-environment state. Here we show that many-body quantum enhancement can in fact be obtained through classical measurements, such as photon counting and homodyne detection. We illustrate this in detail for a class of open spin-boson models which can be realized in trapped-ion or cavity QED setups. Our findings highlight a route towards the design of systems that enable a practical implementation of quantum enhanced metrology through continuous classical measurements.

Ultracold trapped atomic ions excited into highly energetic Rydberg states constitute a promising platform for scalable quantum information processing. Elementary building blocks for such tasks are high-fidelity and sufficiently fast entangling two-qubit gates, which can be achieved via strong dipole-dipole interactions between microwave-dressed Rydberg ions, as recently demonstrated in a breakthrough experiment at https://www.nature.com/articles/s41586-020-2152-9 . We theoretically investigate the performance of three protocols leading to controlled-phase gate operations. Starting from a microscopic description of Rydberg ions in a linear Paul trap, we derive an effective Hamiltonian that faithfully captures the essential dynamics underlying the gate protocols. We then use an optimization scheme to fine-tune experimentally controllable parameters like laser detuning and Rabi frequency to yield maximal gate fidelity under each studied protocol. We show how non-adiabatic transitions resulting from fast laser driving relative to the characteristic time scales of the system detrimentally affect the fidelity. Despite this, we demonstrate that in the realistic scenario of Rydberg ions with finite radiative lifetimes, optimizing the best found gate protocol enables achievement of fidelities as high as $99.25\,\%$ for a gate time of $0.2\,μ\mathrm{s}$. This considerably undercuts entangling gate durations between ground-state ions, for which gate times are typically limited by the comparably slower time scales of vibrational modes. Overall, this places trapped Rydberg ions into the regime where fast high-accuracy quantum computing and eventually quantum error correction become possible.

Trapped ions are among the most advanced platforms for quantum simulation and computation. Their capabilities can be further augmented by making use of electronically highly excited Rydberg states, which enable the realization of long-ranged electric dipolar interactions. Most experimental and theoretical studies so far focus on the excitation of ionic Rydberg states in linear Paul traps, which generate confinement by a combination of static and oscillating electric fields. These two fields need to be carefully aligned to minimize so-called micromotion, caused by the time-dependent electric field. The purpose of this work is to systematically understand the qualitative impact of micromotion on the Rydberg excitation spectrum, when the symmetry axes of the two electric fields do not coincide. Considering this scenario is not only important in the case of possible field misalignment, but becomes inevitable for Rydberg excitations in 2D and 3D ion crystals. We develop a minimal model describing a single trapped Rydberg ion, which we solve numerically via Floquet theory and analytically using a perturbative approach. We calculate the excitation spectra and analyze in which parameter regimes addressable and energetically isolated Rydberg lines persist, which are an important requirement for conducting coherent manipulations.

Quantum spin models with a large number of interaction partners per spin are frequently used to describe modern many-body quantum optical systems like arrays of Rydberg atoms, atom-cavity systems or trapped ion crystals. For theoretical analysis the mean-field (MF) ansatz is routinely applied. However, besides special cases of all-to-all or strong long range interactions, the MF ansatz provides only approximate results. Here we present a systematic correction to MF theory based on diagrammatic perturbation theory for quantum spin correlators in thermal equilibrium. Our analytic results are universally applicable for any lattice geometry and spin-length S. We provide pre-computed and easy-to-use building blocks for Ising, Heisenberg and transverse field Ising models in the symmetry-unbroken regime. We showcase the quality and simplicity of the method by computing magnetic phase boundaries and excitations gaps. We also treat the Dicke-Ising model of ground-state superradiance where we show that corrections to the MF phase boundary vanish.

We investigate a tripartite quantum Rabi model (TQRM) wherein a bosonic mode concurrently couples to two spin-$1/2$ particles through a spin-spin interaction, resulting in a spin-spin-boson coupling -- a departure from conventional quantum Rabi models featuring bipartite spin-boson couplings. The symmetries of the TQRM depend on the detuning parameter, representing the energy difference between the spin states. At zero detuning a parity symmetry renders the TQRM reducible to a quantum Rabi model. A subradiant to superradiant transition in the groundstate is predicted as the tripartite coupling strength increases. For non-zero detuning the total spin emerges as the sole conserved quantity in the TQRM. It is found that superradiance prevails in the groundstate as long as the tripartite coupling remains non-zero. We derive the Braak $\mathcal{G}$-function of the TQRM analytically, with which the eigenspectra are obtained. The TQRM can be realized in a viable trapped Rydberg ion quantum simulator, where the required tripartite couplings and single body interactions in the TQRM are naturally present. Our study opens opportunities to explore and create novel correlations and entanglement in the spin and motional degrees of freedoms with the TQRM.

Atoms and ions confined with electric and optical fields form the basis of many current quantum simulation and computing platforms. When excited to high-lying Rydberg states, long-ranged dipole interactions emerge which strongly couple the electronic and vibrational degrees of freedom through state-dependent forces. This vibronic coupling and the ensuing hybridization of internal and external degrees of freedom manifest through clear signatures in the many-body spectrum. We illustrate this by considering the case of two trapped Rydberg ions, for which the interaction between the relative vibrations and Rydberg states realizes a quantum Rabi model. We proceed to demonstrate that the aforementioned hybridization can be probed by radio frequency spectroscopy and discuss observable spectral signatures at finite temperatures and for larger ion crystals.

Time-translation symmetry breaking is a mechanism for the emergence of non-stationary many-body phases, so-called time-crystals, in Markovian open quantum systems. Dynamical aspects of time-crystals have been extensively explored over the recent years. However, much less is known about their thermodynamic properties, also due to the intrinsic nonequilibrium nature of these phases. Here, we consider the paradigmatic boundary time-crystal system, in a finite-temperature environment, and demonstrate the persistence of the time-crystalline phase at any temperature. Furthermore, we analyze thermodynamic aspects of the model investigating, in particular, heat currents, power exchange and irreversible entropy production. Our work sheds light on the thermodynamic cost of sustaining nonequilibrium time-crystalline phases and provides a framework for characterizing time-crystals as possible resources for, e.g., quantum sensing. Our results may be verified in experiments, for example with trapped ions or superconducting circuits, since we connect thermodynamic quantities with mean value and covariance of collective (magnetization) operators.

Trapped ions provide a platform for quantum technologies that offers long coherence times and high degrees of scalability and controllability. Here, we use this platform to develop a realistic model of a thermal device consisting of two laser-driven, strongly coupled Rydberg ions in a harmonic trap. We show that the translational degrees of freedom of this system can be utilized as a flywheel storing the work output that is generated by a cyclic thermodynamic process applied to its electronic degrees of freedom. Mimicking such a process through periodic variations of external control parameters, we use a mean-field approach underpinned by numerical and analytical calculations to identify relevant physical processes and to determine the charging rate of the flywheel. Our work paves the way for the design of microscopic thermal machines based on Rydberg ions that can be equipped with both many-body working media and universal work storages.

We consider open quantum systems whose dynamics is governed by a time-independent Markovian Lindblad Master equation. Such systems approach their stationary state on a timescale that is determined by the spectral gap of the generator of the Master equation dynamics. In the recent paper [Carollo et al., Phys. Rev. Lett. 127, 060401 (2021)] it was shown that under certain circumstances it is possible to exponentially accelerate the approach to stationarity by performing a unitary transformation of the initial state. This phenomenon can be regarded as the quantum version of the so-called Mpemba effect. The transformation of the initial state removes its overlap with the dynamical mode of the open system dynamics that possesses the slowest decay rate and thus determines the spectral gap. While this transformation can be exactly constructed in some cases, it is in practice challenging to implement. Here we show that even far simpler transformations constructed by a global unitary spin rotation allow to exponentially speed up relaxation. We demonstrate this using simple dissipative quantum spin systems, which are relevant for current quantum simulation and computation platforms based on trapped atoms and ions.

Conical intersections between electronic potential energy surfaces are paradigmatic for the study of non-adiabatic processes in the excited states of large molecules. However, since the corresponding dynamics occurs on a femtosecond timescale, their investigation remains challenging and requires ultrafast spectroscopy techniques. We demonstrate that trapped Rydberg ions are a platform to engineer conical intersections and to simulate their ensuing dynamics on larger length and time scales of the order of nanometers and microseconds, respectively; all this in a highly controllable system. Here, the shape of the potential energy surfaces and the position of the conical intersection can be tuned thanks to the interplay between the high polarizability and the strong dipolar exchange interactions of Rydberg ions. We study how the presence of a conical intersection affects both the nuclear and electronic dynamics demonstrating, in particular, how it results in the inhibition of the nuclear motion. These effects can be monitored in real-time via a direct spectroscopic measurement of the electronic populations in a state-of-the-art experimental setup.

Trapped Rydberg ions represent a flexible platform for quantum simulation and information processing which combines a high degree of control over electronic and vibrational degrees of freedom. The possibility to individually excite ions to high-lying Rydberg levels provides a system where strong and long-range interactions between pairs of excited ions can be engineered and tuned via external laser fields. We show that the coupling between Rydberg pair interactions and collective motional modes gives rise to effective long-range multi-body interactions, consisting of two, three, and four-body terms. Their shape, strength, and range can be controlled via the ion trap parameters and strongly depends on both the equilibrium configuration and vibrational modes of the ion crystal. By focusing on an experimentally feasible quasi one-dimensional setup of $ {}^{88}\mathrm{Sr}^+ $ Rydberg ions, we demonstrate that multi-body interactions are enhanced by the emergence of a soft mode associated, e.g., with a structural phase transition. This has a striking impact on many-body electronic states and results, for example, in a three-body anti-blockade effect. Our study shows that trapped Rydberg ions offer new opportunities to study exotic many-body quantum dynamics driven by enhanced multi-body interactions.

Generating quantum entanglement in large systems on time scales much shorter than the coherence time is key to powerful quantum simulation and computation. Trapped ions are among the most accurately controlled and best isolated quantum systems with low-error entanglement gates operated via the vibrational motion of a few-ion crystal within tens of microseconds. To exceed the level of complexity tractable by classical computers the main challenge is to realise fast entanglement operations in large ion crystals. The strong dipole-dipole interactions in polar molecule and Rydberg atom systems allow much faster entangling gates, yet stable state-independent confinement comparable with trapped ions needs to be demonstrated in these systems. Here, we combine the benefits of these approaches: we report a $700\,\mathrm{ns}$ two-ion entangling gate which utilises the strong dipolar interaction between trapped Rydberg ions and produce a Bell state with $78\%$ fidelity. The sources of gate error are identified and a total error below $0.2\%$ is predicted for experimentally-achievable parameters. Furthermore, we predict that residual coupling to motional modes contributes $\sim 10^{-4}$ gate error in a large ion crystal of 100 ions. This provides a new avenue to significantly speed up and scale up trapped ion quantum computers and simulators.

Spin-boson Hamiltonians are an effective description for numerous quantum many-body systems such as atoms coupled to cavity modes, quantum electrodynamics in circuits and trapped ion systems. While reaching the limit of strong coupling is possible in current experiments, the understanding of the physics in this parameter regime remains a challenge, especially when disorder and dissipation are taken into account. Here we investigate a regime where the many-body spin dynamics can be related to a Ising energy function defined in terms of the spin-boson couplings. While in the coherent weak coupling regime it is known that an effective description in terms of spin Hamiltonian is possible, we show that a similar viewpoint can be adopted in the presence of dissipation and strong couplings. The resulting many-body dynamics features approximately thermal regimes, separated by out-of-equilibrium ones in which detailed balance is broken. Moreover, we show that under appropriately chosen conditions one can even achieve cooling of the spin degrees of freedom. This points towards the possibility of using strongly coupled dissipative spin-boson systems for engineering complex energy landscapes together with an appropriate cooling dynamics.

Trapped Rydberg ions are a promising new system for quantum information processing. They have the potential to join the precise quantum operations of trapped ions and the strong, long-range interactions between Rydberg atoms. Technically, the ion trap will need to stay active while exciting the ions into the Rydberg state, else the strong Coulomb repulsion will quickly push the ions apart. Thus, a thorough understanding of the trap effects on Rydberg ions is essential for future applications. Here we report the observation of two fundamental trap effects. First, we investigate the interaction of the Rydberg electron with the quadrupolar electric trapping field. This effect leads to Floquet sidebands in the spectroscopy of Rydberg D-states whereas Rydberg S-states are unaffected due to their symmetry. Second, we report on the modified trapping potential in the Rydberg state compared to the ground state which results from the strong polarizability of the Rydberg ion. We observe the resultant energy shifts as a line broadening which can be suppressed by cooling the ion to the motional ground state in the directions orthogonal to the excitation laser.

We investigate quantum synchronization theoretically in a system consisting of two cold ions in microtraps. The ions' motion is damped by a standing-wave laser whilst also being driven by a blue-detuned laser which results in self-oscillation. Working in a non-classical regime, where these oscillations contain only a few phonons and have a sub-Poissonian number variance, we explore how synchronization occurs when the two ions are weakly coupled using a probability distribution for the relative phase. We show that strong correlations arise between the spin and vibrational degrees of freedom within each ion and find that when two ions synchronize their spin degrees of freedom in turn become correlated. This allows one to indirectly infer the presence of synchronization by measuring the ions' internal state.

We explore trapped ions as a setting to investigate non-equilibrium phases in a generalised Dicke model of dissipative spins coupled to phonon modes. We find a rich dynamical phase diagram including superradiant-like regimes, dynamical phase-coexistence and phonon-lasing behaviour. A particular advantage of trapped ions is that these phases and transitions among them can be probed in situ through fluorescence. We demonstrate that the main physical insights are captured by a minimal model and consider an experimental realisation with Ca+ ions trapped in a linear Paul trap.

We present a theoretical analysis of the implementation of an entangling quantum gate between two trapped Ca$^+$ ions which is based on the dipolar interaction among ionic Rydberg states. In trapped ions the Rydberg excitation dynamics is usually strongly affected by mechanical forces due to the strong couplings between electronic and vibrational degrees of freedom in inhomogeneous electric fields. We demonstrate that this harmful effect can be overcome by using dressed states that emerge from the microwave coupling of nearby Rydberg states. At the same time these dressed states exhibit long range dipolar interactions which we use to implement a controlled adiabatic phase gate. Our study highlights a route towards a trapped ion quantum processor in which quantum gates are realized independently of the vibrational modes.

We employ the concept of a dynamical, activity order parameter to study the Ising model in a transverse magnetic field coupled to a Markovian bath. For a certain range of values of the spin-spin coupling, magnetic field and dissipation rate, we identify a first order dynamical phase transition between active and inactive {\em dynamical phases}. We demonstrate that dynamical phase-coexistence becomes manifest in an intermittent behavior of the bath quanta emission. Moreover, we establish the connection between the dynamical order parameter that quantifies the activity, and the longitudinal magnetization that serves as static order parameter. The system we consider can be implemented in current experiments with Rydberg atoms and trapped ions.