Joseph W. P. Wilkinson

Trapped ions as one of the most promising quantum-information-processing platforms, yet conventional entangling gates mediated by collective motion remain slow and difficult to scale. Exciting trapped ions to high-lying electronic Rydberg states provides a promising route to overcome these limitations by enabling strong, long-range dipole-dipole interactions that support much faster multi-qubit operations. Here, we introduce the first scheme for implementing a native controlled-controlled-Z gate with microwave-dressed Rydberg ions by optimizing a single-pulse protocol that accounts for the finite Rydberg-state lifetime. The resulting gate outperforms standard decompositions into one- and two-qubit gates by achieving fidelities above 97% under realistic conditions, with execution times of about 2 microseconds at cryogenic temperatures. To explore the potential of trapped Rydberg ions for fault-tolerant quantum error correction, and to illustrate the utility of three-qubit Rydberg-ion gates in this context, we develop and analyze a proposal for fault-tolerant, measurement-free quantum error correction using the nine-qubit Bacon-Shor code. Our simulations confirm that quantum error correction can be performed in a fully fault-tolerant manner on a linear Rydberg-ion chain despite its limited qubit connectivity. These results establish native multiqubit Rydberg-ion gates as a valuable resource for fast, high-fidelity quantum computing and highlight their potential for fault-tolerant quantum error correction.

Ultracold trapped atomic ions excited into highly energetic Rydberg states constitute a promising platform for scalable quantum information processing. Elementary building blocks for such tasks are high-fidelity and sufficiently fast entangling two-qubit gates, which can be achieved via strong dipole-dipole interactions between microwave-dressed Rydberg ions, as recently demonstrated in a breakthrough experiment at https://www.nature.com/articles/s41586-020-2152-9 . We theoretically investigate the performance of three protocols leading to controlled-phase gate operations. Starting from a microscopic description of Rydberg ions in a linear Paul trap, we derive an effective Hamiltonian that faithfully captures the essential dynamics underlying the gate protocols. We then use an optimization scheme to fine-tune experimentally controllable parameters like laser detuning and Rabi frequency to yield maximal gate fidelity under each studied protocol. We show how non-adiabatic transitions resulting from fast laser driving relative to the characteristic time scales of the system detrimentally affect the fidelity. Despite this, we demonstrate that in the realistic scenario of Rydberg ions with finite radiative lifetimes, optimizing the best found gate protocol enables achievement of fidelities as high as $99.25\,\%$ for a gate time of $0.2\,μ\mathrm{s}$. This considerably undercuts entangling gate durations between ground-state ions, for which gate times are typically limited by the comparably slower time scales of vibrational modes. Overall, this places trapped Rydberg ions into the regime where fast high-accuracy quantum computing and eventually quantum error correction become possible.

Trapped ions are among the most advanced platforms for quantum simulation and computation. Their capabilities can be further augmented by making use of electronically highly excited Rydberg states, which enable the realization of long-ranged electric dipolar interactions. Most experimental and theoretical studies so far focus on the excitation of ionic Rydberg states in linear Paul traps, which generate confinement by a combination of static and oscillating electric fields. These two fields need to be carefully aligned to minimize so-called micromotion, caused by the time-dependent electric field. The purpose of this work is to systematically understand the qualitative impact of micromotion on the Rydberg excitation spectrum, when the symmetry axes of the two electric fields do not coincide. Considering this scenario is not only important in the case of possible field misalignment, but becomes inevitable for Rydberg excitations in 2D and 3D ion crystals. We develop a minimal model describing a single trapped Rydberg ion, which we solve numerically via Floquet theory and analytically using a perturbative approach. We calculate the excitation spectra and analyze in which parameter regimes addressable and energetically isolated Rydberg lines persist, which are an important requirement for conducting coherent manipulations.

Atoms and ions confined with electric and optical fields form the basis of many current quantum simulation and computing platforms. When excited to high-lying Rydberg states, long-ranged dipole interactions emerge which strongly couple the electronic and vibrational degrees of freedom through state-dependent forces. This vibronic coupling and the ensuing hybridization of internal and external degrees of freedom manifest through clear signatures in the many-body spectrum. We illustrate this by considering the case of two trapped Rydberg ions, for which the interaction between the relative vibrations and Rydberg states realizes a quantum Rabi model. We proceed to demonstrate that the aforementioned hybridization can be probed by radio frequency spectroscopy and discuss observable spectral signatures at finite temperatures and for larger ion crystals.