Markus Hennrich

Microwave dressing of Rydberg ions creates tunable eigenstates with controllable polarizability and interaction strength, but coherent navigation between these states has remained elusive. Here, we report on the first demonstration of coherent population transfer between different Rydberg states of a trapped ion. We investigate both microwave-mediated Rabi oscillations between Rydberg S and P states and adiabatic transfer between microwave-dressed Rydberg states. Between Rydberg S and P states we achieve a population transfer efficiency of 91.5(5)% in a single microwave $π$-pulse. Microwave dressing hybridizes the S and P Rydberg states into new eigenstates with tunable polarizability, enabling both noise-resilient zero-polarizability states and maximally interacting states. We demonstrate adiabatic transfer between these zero-polarizability and maximally dressed states, enabling experiments that combine noise-resilient excitation with strong dipole-dipole interactions and Förster resonance control within a single measurement sequence.

Quantum simulation of interacting many-body spin systems is routinely performed with cold trapped ions, and systems with hundreds of spins have been studied in one and two dimensions. In the most common realizations of these platforms, spin degrees of freedom are encoded in low-lying electronic levels, and interactions among the spins are mediated through crystal vibrations. Here we propose a new approach which enables the quantum simulation of two-dimensional spin systems with interaction strengths that are increased by orders of magnitude. This, together with the unprecedented longevity of trapped ions, opens an avenue for the exploration of phenomena that take place on long timescales, e.g., slow and collective relaxation in frustrated and kinetically constrained systems. Our platform makes use of the strong dipolar interactions among electronic Rydberg states and planar confinement provided by a Penning trap. We investigate how the strong electric and magnetic fields that form this trap affect the properties of the Rydberg states and show that spin-spin interaction strengths on the order of MHz are achievable under experimentally realistic conditions. As a brief illustration of the capabilities of this quantum simulator, we study the entanglement in a frustrated spin system realized by three ions.

State-dependent conformational changes play a central role in molecular dynamics, yet they are often difficult to observe or simulate due to their complexity and ultrafast nature. One alternative approach is to emulate such phenomena using quantum simulations with cold, trapped ions. In their electronic ground state, these ions form long-lived Wigner crystals. When excited to high-lying electronic Rydberg states, the ions experience a modified trapping potential, resulting in a strong coupling between their electronic and vibrational degrees of freedom. In an ion crystal, this vibronic coupling creates electronic state-dependent potential energy surfaces that can support distinct crystal structures -- closely resembling the conformational changes of molecules driven by electronic excitations. Here, we present the first experimental observation of this effect, by laser-coupling a single ion at the centre of a three-ion crystal to a Rydberg state. By tuning the system close to a structural phase transition, the excitation induces a state-dependent conformational change, transforming the Wigner crystal from a linear to a zigzag configuration. This structural change leads to a strong hybridisation between vibrational and electronic states, producing a clear spectroscopic signature in the Rydberg excitation. Our findings mark the first experimental step towards using Rydberg ions to create and study artificial molecular systems. change leads to a strong hybridisation between vibrational and electronic states, producing a clear spectroscopic signature in the Rydberg excitation. Our findings mark the first experimental step towards using Rydberg ions to create and study artificial molecular systems.

Trapped ions are among the most advanced platforms for quantum simulation and computation. Their capabilities can be further augmented by making use of electronically highly excited Rydberg states, which enable the realization of long-ranged electric dipolar interactions. Most experimental and theoretical studies so far focus on the excitation of ionic Rydberg states in linear Paul traps, which generate confinement by a combination of static and oscillating electric fields. These two fields need to be carefully aligned to minimize so-called micromotion, caused by the time-dependent electric field. The purpose of this work is to systematically understand the qualitative impact of micromotion on the Rydberg excitation spectrum, when the symmetry axes of the two electric fields do not coincide. Considering this scenario is not only important in the case of possible field misalignment, but becomes inevitable for Rydberg excitations in 2D and 3D ion crystals. We develop a minimal model describing a single trapped Rydberg ion, which we solve numerically via Floquet theory and analytically using a perturbative approach. We calculate the excitation spectra and analyze in which parameter regimes addressable and energetically isolated Rydberg lines persist, which are an important requirement for conducting coherent manipulations.

Interference underpins some of the most practical and impactful properties of both the classical and quantum worlds. In this work we experimentally investigate a new formalism to describe interference effects, based on collective states which have enhanced or suppressed coupling to a two-level system. We employ a single trapped ion, whose electronic state is coupled to two of the ion's motional modes in order to simulate a multi-mode light-matter interaction. We observe the emergence of phononic bright and dark states for both a single phonon and a superposition of coherent states and demonstrate that a view of interference which is based solely on their decomposition in the collective basis is able to intuitively describe their coupling to a single atom. This work also marks the first time that multi-mode bright and dark states have been formed with the bounded motion of a single trapped ion and we highlight the potential of the methods discussed here for use in quantum information processing.

In this work, we present a method for measuring the motional state of a two-level system coupled to a harmonic oscillator. Our technique uses ultra-narrowband composite pulses on the blue sideband transition to scan through the populations of the different motional states. Our approach does not assume any previous knowledge of the motional state distribution and is easily implemented. It is applicable both inside and outside of the Lamb-Dicke regime. For higher phonon numbers especially, the composite pulse sequence can be used as a filter for measuring phonon number ranges. We demonstrate this measurement technique using a single trapped ion and show good detection results with the numerically evaluated pulse sequence.

We present a single-shot method to measure motional states in the number basis. The technique can be applied to systems with at least three non-degenerate energy levels which can be coupled to a linear quantum harmonic oscillator, such as in trapped ion experiments. The method relies on probing an Autler-Townes splitting that arises when two levels are strongly coupled via a phonon-number changing transition. We demonstrate the method using a single trapped ion and show that it may be used in a non-demolition fashion to prepare phonon number states. We also show how the Autler-Townes splitting can be used to measure phonon number distributions.

We minimize the stray electric field in a linear Paul trap quickly and accurately, by applying interferometry pulse sequences to a trapped ion optical qubit. The interferometry sequences are sensitive to the change of ion equilibrium position when the trap stiffness is changed, and we use this to determine the stray electric field. The simplest pulse sequence is a two-pulse Ramsey sequence, and longer sequences with multiple pulses offer a higher precision. The methods allow the stray field strength to be minimized beyond state-of-the-art levels, with only modest experimental requirements. Using a sequence of nine pulses we reduce the 2D stray field strength to $(10.5\pm0.8)\,\mathrm{mV\,m^{-1}}$ in $11\,\mathrm{s}$ measurement time. The pulse sequences are easy to implement and automate, and they are robust against laser detuning and pulse area errors. We use interferometry sequences with different lengths and precisions to measure the stray field with an uncertainty below the standard quantum limit. This marks a real-world case in which quantum metrology offers a significant enhancement. Also, we minimize micromotion in 2D using a single probe laser, by using an interferometry method together with the resolved sideband method; this is useful for experiments with restricted optical access. Furthermore, a technique presented in this work is related to quantum protocols for synchronising clocks; we demonstrate these protocols here.

Conical intersections between electronic potential energy surfaces are paradigmatic for the study of non-adiabatic processes in the excited states of large molecules. However, since the corresponding dynamics occurs on a femtosecond timescale, their investigation remains challenging and requires ultrafast spectroscopy techniques. We demonstrate that trapped Rydberg ions are a platform to engineer conical intersections and to simulate their ensuing dynamics on larger length and time scales of the order of nanometers and microseconds, respectively; all this in a highly controllable system. Here, the shape of the potential energy surfaces and the position of the conical intersection can be tuned thanks to the interplay between the high polarizability and the strong dipolar exchange interactions of Rydberg ions. We study how the presence of a conical intersection affects both the nuclear and electronic dynamics demonstrating, in particular, how it results in the inhibition of the nuclear motion. These effects can be monitored in real-time via a direct spectroscopic measurement of the electronic populations in a state-of-the-art experimental setup.

Highly excited Rydberg states are usually extremely polarizable and exceedingly sensitive to electric fields. Because of this Rydberg ions confined in electric fields have state-dependent trapping potentials. We engineer a Rydberg state that is insensitive to electric fields by coupling two Rydberg states with static polarizabilities of opposite sign, in this way we achieve state-independent magic trapping. We show that the magically-trapped ion can be coherently excited to the Rydberg state without the need for control of the ion's motion.

Trapped Rydberg ions represent a flexible platform for quantum simulation and information processing which combines a high degree of control over electronic and vibrational degrees of freedom. The possibility to individually excite ions to high-lying Rydberg levels provides a system where strong and long-range interactions between pairs of excited ions can be engineered and tuned via external laser fields. We show that the coupling between Rydberg pair interactions and collective motional modes gives rise to effective long-range multi-body interactions, consisting of two, three, and four-body terms. Their shape, strength, and range can be controlled via the ion trap parameters and strongly depends on both the equilibrium configuration and vibrational modes of the ion crystal. By focusing on an experimentally feasible quasi one-dimensional setup of $ {}^{88}\mathrm{Sr}^+ $ Rydberg ions, we demonstrate that multi-body interactions are enhanced by the emergence of a soft mode associated, e.g., with a structural phase transition. This has a striking impact on many-body electronic states and results, for example, in a three-body anti-blockade effect. Our study shows that trapped Rydberg ions offer new opportunities to study exotic many-body quantum dynamics driven by enhanced multi-body interactions.

The response of matter to fields underlies the physical sciences, from particle physics to astrophysics, and from chemistry to biophysics. We observe an atom's response to an electric quadrupole field to second- and higher orders; this arises from the atom's electric quadrupole polarizability and hyperpolarizabilities. We probe a single atomic ion which is excited to Rydberg states and confined in the electric fields of a Paul trap. The quadrupolar trapping fields cause atomic energy level shifts and give rise to spectral sidebands. The observed effects are described well by theory calculations.

In this chapter, we present an overview of experiments with trapped Rydberg ions and outline the advantages and challenges of developing applications of this new platform for quantum computing, sensing and simulation. Trapped Rydberg ions feature several important properties, unique in their combination: they are tightly bound in a harmonic potential of a Paul trap, in which their internal and external degrees of freedom can be controlled in a precise fashion. High fidelity state preparation of both internal and motional states of the ions has been demonstrated, and the internal states have been employed to store and manipulate qubit information. Furthermore, strong dipolar interactions can be realised between ions in Rydberg states and be explored for investigating correlated many-body systems. By laser coupling to Rydberg states, the polarisability of the ions can be both enhanced and tuned. This can be used to control the interactions with the trapping fields in a Paul trap as well as dipolar interactions between the ions. Thus, trapped Rydberg ions present an attractive alternative for fast entangling operations as compared to those mediated by normal modes of trapped ions, which are advantageous for a future quantum computer or a quantum simulator.

Generating quantum entanglement in large systems on time scales much shorter than the coherence time is key to powerful quantum simulation and computation. Trapped ions are among the most accurately controlled and best isolated quantum systems with low-error entanglement gates operated via the vibrational motion of a few-ion crystal within tens of microseconds. To exceed the level of complexity tractable by classical computers the main challenge is to realise fast entanglement operations in large ion crystals. The strong dipole-dipole interactions in polar molecule and Rydberg atom systems allow much faster entangling gates, yet stable state-independent confinement comparable with trapped ions needs to be demonstrated in these systems. Here, we combine the benefits of these approaches: we report a $700\,\mathrm{ns}$ two-ion entangling gate which utilises the strong dipolar interaction between trapped Rydberg ions and produce a Bell state with $78\%$ fidelity. The sources of gate error are identified and a total error below $0.2\%$ is predicted for experimentally-achievable parameters. Furthermore, we predict that residual coupling to motional modes contributes $\sim 10^{-4}$ gate error in a large ion crystal of 100 ions. This provides a new avenue to significantly speed up and scale up trapped ion quantum computers and simulators.

Usually the influence of the quadratic Stark effect on an ion's trapping potential is minuscule and only needs to be considered in atomic clock experiments. In this work we excite a trapped ion to a Rydberg state with polarizability $\sim$~eight orders of magnitude higher than a low-lying electronic state; we find that the highly-polarizable ion experiences a vastly different trapping potential owing to the Stark effect. We observe changes in trap stiffness, equilibrium position and minimum potential, which can be tuned using the trapping electric fields. These effects lie at the heart of proposals to shape motional mode spectra, simulate quantum magnetism and coherently drive structural phase transitions; in addition we propose using these effects to simulate cosmological particle creation, study quantum fluctuations of work and minimize ion micromotion. Mitigation of Stark effects is important for coherent control of Rydberg ions; we illustrate this by carrying out the first Rabi oscillations between a low-lying electronic state and a Rydberg state of an ion.

The existence of ideal quantum measurements is one of the fundamental predictions of quantum mechanics. In theory the measurement projects onto the eigenbasis of the measurement observable while preserving all coherences of degenerate eigenstates. The question arises whether there are dynamical processes in nature that correspond to such ideal quantum measurements. Here we address this question and present experimental results monitoring the dynamics of a naturally occurring measurement process: the coupling of a trapped ion qutrit to the photon environment. By taking tomographic snapshots during the detection process, we show with an average fidelity of $94\%$ that the process develops in agreement with the model of an ideal quantum measurement.

Trapped Rydberg ions are a promising novel approach to quantum computing and simulations. They are envisaged to combine the exquisite control of trapped ion qubits with the fast two-qubit Rydberg gates already demonstrated in neutral atom experiments. Coherent Rydberg excitation is a key requirement for these gates. Here, we carry out the first coherent Rydberg excitation of an ion and perform a single-qubit Rydberg gate, thus demonstrating basic elements of a trapped Rydberg ion quantum computer.

Trapped Rydberg ions are a promising new system for quantum information processing. They have the potential to join the precise quantum operations of trapped ions and the strong, long-range interactions between Rydberg atoms. Technically, the ion trap will need to stay active while exciting the ions into the Rydberg state, else the strong Coulomb repulsion will quickly push the ions apart. Thus, a thorough understanding of the trap effects on Rydberg ions is essential for future applications. Here we report the observation of two fundamental trap effects. First, we investigate the interaction of the Rydberg electron with the quadrupolar electric trapping field. This effect leads to Floquet sidebands in the spectroscopy of Rydberg D-states whereas Rydberg S-states are unaffected due to their symmetry. Second, we report on the modified trapping potential in the Rydberg state compared to the ground state which results from the strong polarizability of the Rydberg ion. We observe the resultant energy shifts as a line broadening which can be suppressed by cooling the ion to the motional ground state in the directions orthogonal to the excitation laser.

Single atoms or atom-like emitters are the purest source of on-demand single photons, they are intrinsically incapable of multi-photon emission. To demonstrate this degree of purity we have realized a tunable, on-demand source of single photons using a single ion trapped at the common focus of high numerical aperture lenses. Our trapped-ion source produces single-photon pulses at a rate of 200 kHz with g$^2(0) = (1.9 \pm 0.2) \times 10^{-3}$, without any background subtraction. The corresponding residual background is accounted for exclusively by detector dark counts. We further characterize the performance of our source by measuring the violation of a non-Gaussian state witness and show that its output corresponds to ideal attenuated single photons. Combined with current efforts to enhance collection efficiency from single emitters, our results suggest that single trapped ions are not only ideal stationary qubits for quantum information processing, but promising sources of light for scalable optical quantum networks.

Trapped ion crystals have proved to be one of the most viable physical implementations of quantum registers and a promising candidate for a scalable realization of quantum networks. The latter will require the development of an efficient interface between trapped ions and photons. We describe two research directions that are currently investigated to realize such photonic quantum interfaces in free space using high numerical aperture optics. The first approach investigates how strong focusing of light onto a single ion can increase the interaction strength to achieve efficient interaction between a photon and the ion. The second approach uses a probabilistic measurement on scattered photons to generate entanglement between two ions that could be used to distribute information in a quantum network. For both approaches a higher numerical aperture would increase the efficiency of the interface.

The construction of a quantum computer remains a fundamental scientific and technological challenge, in particular due to unavoidable noise. Quantum states and operations can be protected from errors using protocols for fault-tolerant quantum computing (FTQC). Here we present a step towards this by implementing a quantum error correcting code, encoding one qubit in entangled states distributed over 7 trapped-ion qubits. We demonstrate the capability of the code to detect one bit flip, phase flip or a combined error of both, regardless on which of the qubits they occur. Furthermore, we apply combinations of the entire set of logical single-qubit Clifford gates on the encoded qubit to explore its computational capabilities. The implemented 7-qubit code is the first realization of a complete Calderbank-Shor-Steane (CSS) code and constitutes a central building block for FTQC schemes based on concatenated elementary quantum codes. It also represents the smallest fully functional instance of the color code, opening a route towards topological FTQC.

Quantum computers hold the promise to solve certain problems exponentially faster than their classical counterparts. Trapped atomic ions are among the physical systems in which building such a computing device seems viable. In this work we present a small-scale quantum information processor based on a string of $^{40}$Ca${^+}$ ions confined in a macroscopic linear Paul trap. We review our set of operations which includes non-coherent operations allowing us to realize arbitrary Markovian processes. In order to build a larger quantum information processor it is mandatory to reduce the error rate of the available operations which is only possible if the physics of the noise processes is well understood. We identify the dominant noise sources in our system and discuss their effects on different algorithms. Finally we demonstrate how our entire set of operations can be used to facilitate the implementation of algorithms by examples of the quantum Fourier transform and the quantum order finding algorithm.

A century on from the development of quantum theory, the interpretation of a quantum state is still discussed. If a physicist claims to have produced a system with a particular wave function, does this represent directly a physical wave of some kind, or is the wave function merely a summary of knowledge, or information, about the system? A recent no-go theorem shows that models in which the wave function is not physical, but corresponds only to an experimenter's information about a hypothetical real state of the system, must make different predictions from quantum theory when a certain test is carried out. Here we report on an experimental implementation using trapped ions. Within experimental error, the results confirm quantum theory. We analyse which kinds of theories are ruled out.

We report on the implementation of a quantum process tomography (QPT) technique known as direct characterization of quantum dynamics (DCQD) applied on coherent and incoherent single- qubit processes in a system of trapped calcium 40 ions. Using quantum correlations with an ancilla qubit, DCQD reduces exponentially the number of experimental configurations required for standard QPT. With this technique, the system's relaxation times T1 and T2 were measured with a single experimental configuration. We further show the first complete characterization of single-qubit processes using a single generalized measurement realized through multi-body correlations with three ancilla qubits.

The control of quantum systems is of fundamental scientific interest and promises powerful applications and technologies. Impressive progress has been achieved in isolating the systems from the environment and coherently controlling their dynamics, as demonstrated by the creation and manipulation of entanglement in various physical systems. However, for open quantum systems, engineering the dynamics of many particles by a controlled coupling to an environment remains largely unexplored. Here we report the first realization of a toolbox for simulating an open quantum system with up to five qubits. Using a quantum computing architecture with trapped ions, we combine multi-qubit gates with optical pumping to implement coherent operations and dissipative processes. We illustrate this engineering by the dissipative preparation of entangled states, the simulation of coherent many-body spin interactions and the quantum non-demolition measurement of multi-qubit observables. By adding controlled dissipation to coherent operations, this work offers novel prospects for open-system quantum simulation and computation.