K. Kim

Laser-cooled and trapped atomic ions form an ideal standard for the simulation of interacting quantum spin models. Effective spins are represented by appropriate internal energy levels within each ion, and the spins can be measured with near-perfect efficiency using state-dependent fluorescence techniques. By applying optical fields that exert optical dipole forces on the ions, their Coulomb interaction can be modulated to produce long-range and tunable spin-spin interactions that can be reconfigured by shaping the spectrum and pattern of the laser fields, in a prototypical example of a quantum simulator. Here we review the theoretical mapping of atomic ions to interacting spin systems, the preparation of complex equilibrium states, the study of dynamical processes in these many-body interacting quantum systems, and the use of this platform for optimization and other tasks. The use of such quantum simulators for studying spin models may inform our understanding of exotic quantum materials and shed light on the behavior of interacting quantum systems that cannot be modeled with conventional computers.

We study the precision limits of detecting a linear magnetic-field gradient by using W-states in the presence of different types of noises. We consider to use an atomic spin chain for probing the magnetic-field gradient, where a W-state is prepared. We compare this method with the measurement of using two uncorrelated atoms. For pure states, W-states can provide an improvement over uncorrelated states in determining the magnetic-field gradient up to four particles. We examine the effects of local dephasing and dissipations on the performances of detections. In presence of dephasing, the uncorrelated atoms can give a higher precision than using W-states. But W-states provide a better performance in the presence of dissipation for a few particles. We briefly discuss the implementation of the detection methods with cold atoms and trapped ions.

A quantum simulator is a well controlled quantum system that can simulate the behavior of another quantum system which may require exponentially large classical computing resources to understand otherwise. In the 1980s, Feynman proposed the use of quantum logic gates on a standard controllable quantum system to efficiently simulate the behavior of a model Hamiltonian. Recent experiments using trapped ions and neutral atoms have realized quantum simulation of Ising model in presence of external magnetic fields, and showed almost arbitrary control in generating non-trivial Ising coupling patterns. Here we use laser-cooled trapped 171-Yb+ ions to simulate the emergence of magnetism in a system of interacting spins by implementing a fully-connected non-uniform ferromagnetic Ising model in a transverse magnetic field. To link this quantum simulation to condensed matter physics, we measure scalable correlation functions and order parameters appropriate for the description of larger systems, such as various moments of the magnetization. By increasing the Ising coupling strengths compared with the external field, the crossover from paramagnetism to ferromagnetic order sharpens as the system is scaled up from N = 2 to 9 trapped ion spins. This points toward the onset of a quantum phase transition that should become infinitely sharp as the system approaches the macroscopic scale. We compare the measured ground state order to theory, which may become intractable for non-uniform Ising couplings as the number of spins grows beyond 20- 30 and even NP complete for a fully-connected frustrated Ising model, making this experiment an important benchmark for large-scale quantum simulation.

We perform a quantum simulation of the Ising model with a transverse field using a collection of three trapped atomic ion spins. By adiabatically manipulating the Hamiltonian, we directly probe the ground state for a wide range of fields and form of the Ising couplings, leading to a phase diagram of magnetic order in this microscopic system. The technique is scalable to much larger numbers of trapped ion spins, where phase transitions approaching the thermodynamic limit can be studied in cases where theory becomes intractable.

Any residual coupling of a quantum computer to the environment results in computational errors. Encoding quantum information in a so-called decoherence-free subspace provides means to avoid these errors. Despite tremendous progress in employing this technique to extend memory storage times by orders of magnitude, computation within such subspaces has been scarce. Here, we demonstrate the realization of a universal set of quantum gates acting on decoherence-free ion qubits. We combine these gates to realize the first controlled-NOT gate within a decoherence-free, scalable quantum computer.

We demonstrate tunable spin-spin couplings between trapped atomic ions, mediated by laser forces on multiple transverse collective modes of motion. A $σ_x σ_x$-type Ising interaction is realized between quantum bits stored in the ground hyperfine clock states of Yb ions. We demonstrate entangling gates and tailor the spin-spin couplings with two and three trapped ions. The use of closely-spaced transverse modes provides a new class of interactions relevant to quantum computing and simulation with large collections of ions in a single crystal.

We propose a large-scale quantum computer architecture by stabilizing a single large linear ion chain in a very simple trap geometry. By confining ions in an anharmonic linear trap with nearly uniform spacing between ions, we show that high-fidelity quantum gates can be realized in large linear ion crystals under the Doppler temperature based on coupling to a near-continuum of transverse motional modes with simple shaped laser pulses.

We report on the first absolute transition frequency measurement at the 10^{-15} level with a single, laser-cooled 40Ca+ ion in a linear Paul trap. For this measurement, a frequency comb is referenced to the transportable Cs atomic fountain clock of LNE-SYRTE and is used to measure the S1/2-D5/2 electric-quadrupole transition frequency. After the correction of systematic shifts, the clock transition frequency f_Ca+ = 411 042 129 776 393.2 (1.0) Hz is obtained, which corresponds to a fractional uncertainty within a factor of three of the Cs standard. Future improvements are expected to lead to an uncertainty surpassing the best Cs fountain clocks. In addition, we determine the Lande g-factor of the D5/2 level to be gD5/2=1.2003340(3).

Algorithms for quantum information processing are usually decomposed into sequences of quantum gate operations, most often realized with single- and two- qubit gates[1]. While such operations constitute a universal set for quantum computation, gates acting on more than two qubits can simplify the implementation of complex quantum algorithms[2]. Thus, a single three-qubit operation can replace a complex sequence of two-qubit gates, which in turn promises faster execution with potentially higher Fidelity. One important three-qubit operation is the quantum Toffoli gate which performs a NOT operation on a target qubit depending on the state of two control qubits. Here we present the first experimental realization of the quantum Toffoli gate in an ion trap quantum computer. Our implementation is particular effcient as we directly encode the relevant logic information in the motion of the ion string. [1] DiVincenzo, D. P. Two-bit gates are universal for quantum computation. cond-mat/9407022, Phys.Rev. A 51, 1015-1022 (1995). [2] Chiaverini, J. et al. Realization of quantum error correction. Nature 432, 602-605 (2004).

We propose a geometric phase gate of two ion qubits that are encoded in two levels linked by an optical dipole-forbidden transition. Compared to hyperfine geometric phase gates mediated by electric dipole transitions, the gate has many interesting properties, such as very low spontaneous emission rates, applicability to magnetic field insensitive states, and use of a co-propagating laser beam geometry. We estimate that current technology allows for infidelities of around 10$^{-4}$.

We propose the implementation of a geometric-phase gate on magnetic-field-insensitive qubits with $\hatσ^z$-dependent forces for trapped ion quantum computing. The force is exerted by two laser beams in a Raman configuration. Qubit-state dependency is achieved by a small frequency detuning from the virtually-excited state. Ion species with excited states of long radiative lifetimes are used to reduce the chance of a spontaneous photon emission to less than 10$^{-8}$ per gate-run. This eliminates the main source of gate infidelity of previous implementations. With this scheme it seems possible to reach the fault tolerant threshold.

We discuss techniques that allow for long coherence times in laser spectroscopy experiments with two trapped ions. We show that for this purpose not only entangled ions prepared in decoherence-free subspaces can be used but also a pair of ions that are not entangled but subject to the same kind of phase noise. We apply this technique to a measurement of the electric quadrupole moment of the 3d D5/2 state of 40Ca+ and to a measurement of the linewidth of an ultrastable laser exciting a pair of 40Ca+ ions.

We experimentally investigate nonlinear couplings between vibrational modes of strings of cold ions stored in linear ion traps. The nonlinearity is caused by the ions' Coulomb interaction and gives rise to a Kerr-type interaction Hamiltonian H = n_r*n_s, where n_r,n_s are phonon number operators of two interacting vibrational modes. We precisely measure the resulting oscillation frequency shift and observe a collapse and revival of the contrast in a Ramsey experiment. Implications for ion trap experiments aiming at high-fidelity quantum gate operations are discussed.

We report for the first time, laser spectroscopy of the 1S0 - 3P0 clock transition in 27Al+. A single aluminum ion and a single beryllium ion are simultaneously confined in a linear Paul trap, coupled by their mutual Coulomb repulsion. This coupling allows the beryllium ion to sympathetically cool the aluminum ion, and also enables transfer of the aluminum's electronic state to the beryllium's hyperfine state, which can be measured with high fidelity. These techniques are applied to a measurement of the clock transition frequency, ν= 1 121 015 393 207 851(8) Hz. They are also used to measure the lifetime of the metastable clock state, τ= 20.6 +/- 1.4 s, the ground state 1S0 g-factor, g_S = -0.00079248(14), and the excited state 3P0 g-factor, g_P = -0.00197686(21), in units of the Bohr magneton.

Entanglement is recognized as a key resource for quantum computation and quantum cryptography. For quantum metrology, the use of entangled states has been discussed and demonstrated as a means of improving the signal-to-noise ratio. In addition, entangled states have been used in experiments for efficient quantum state detection and for the measurement of scattering lengths. In quantum information processing, manipulation of individual quantum bits allows for the tailored design of specific states that are insensitive to the detrimental influences of an environment. Such 'decoherence-free subspaces' protect quantum information and yield significantly enhanced coherence times. Here we use a decoherence-free subspace with specifically designed entangled states to demonstrate precision spectroscopy of a pair of trapped Ca+ ions; we obtain the electric quadrupole moment, which is of use for frequency standard applications. We find that entangled states are not only useful for enhancing the signal-to-noise ratio in frequency measurements - a suitably designed pair of atoms also allows clock measurements in the presence of strong technical noise. Our technique makes explicit use of non-locality as an entanglement property and provides an approach for 'designed' quantum metrology.

A crucial building block for quantum information processing with trapped ions is a controlled-NOT quantum gate. In this paper, two different sequences of laser pulses implementing such a gate operation are analyzed using quantum process tomography. Fidelities of up to 92.6(6)% are achieved for single gate operations and up to 83.4(8)% for two concatenated gate operations. By process tomography we assess the performance of the gates for different experimental realizations and demonstrate the advantage of amplitude--shaped laser pulses over simple square pulses. We also investigate whether the performance of concatenated gates can be inferred from the analysis of the single gates.