C. F. Roos

Well isolated quantum systems are exquisite sensors of electromagnetic fields. In this work, we use a single trapped ion for characterizing chirped ultraviolet (UV) picosecond laser pulses. The frequency swept pulses resonantly drive a strong dipole transition via rapid adiabatic passage, resulting in near deterministic population exchange caused by absorption or stimulated emission of photons. When subjecting an ion to counterpropagating pulse pairs, we observe the loss and revival of atomic coherence as a function of the pulse pair spatial overlap enabling quantification of the temporal pulse broadening caused by a frequency chirp in shaped UV pulses with a very low peak power. We find good agreement between measured and applied chirp. The ultrafast population exchange imparts an impulsive force where the estimated change in the mean phonon numbers of 0.5 is measured for two pairs of pulses. The resonant ultrafast kicks could be applied to matter wave interferometry experiments and present a step towards ultrafast entanglement operations in trapped ions.

The conventional approach to perform two-qubit gate operations in trapped ions relies on exciting the ions on motional sidebands with laser light, which is an inherently slow process. One way to implement a fast entangling gate protocol requires a suitable pulsed laser to increase the gate speed by orders of magnitude. However, the realization of such a fast entangling gate operation presents a big technical challenge, as such the required laser source is not available off-the-shelf. For this, we have engineered an ultrafast entangling gate source based on a frequency comb. The source generates bursts of several hundred mode-locked pulses with pulse energy $\sim$800 pJ at 5 GHz repetition rate at 393.3 nm and complies with all requirements for implementing a fast two-qubit gate operation. Using a single, chirped ultraviolet pulse, we demonstrate a rapid adiabatic passage in a Ca$^+$ ion. To verify the applicability and projected performance of the laser system for inducing entangling gates we run simulations based on our source parameters. The gate time can be faster than a trap period with an error approaching $10^{-4}$.

We present experiments on polarization gradient cooling of Ca$^+$ multi-ion Coulomb crystals in a linear Paul trap. Polarization gradient cooling of the collective modes of motion whose eigenvectors have overlap with the symmetry axis of the trap is achieved by two counter-propagating laser beams with mutually orthogonal linear polarizations that are blue-detuned from the S$_{1/2}$ to P$_{1/2}$ transition. We demonstrate cooling of linear chains of up to 51 ions and 2D-crystals in zig-zag configuration with 22 ions. The cooling results are compared with numerical simulations and the predictions of a simple model of cooling in a moving polarization gradient.

Trapped ions are a well-studied and promising system for the realization of a scalable quantum computer. Faster quantum gates would greatly improve the applicability of such a system and allow for greater flexibility in the number of calculation steps. In this paper we present a pulsed laser system, delivering picosecond pulses at a repetition rate of 5 GHz and resonant to the S$_{1/2}$ to P$_{3/2}$ transition in Ca$^+$ for coherent population transfer to implement fast phase gate operations. The optical pulse train is derived from a mode-locked, stabilized optical frequency comb and inherits its frequency stability. Using a single trapped ion, we implement three different techniques for measuring the ion-laser coupling strength and characterizing the pulse train emitted by the laser, and show how all requirements can be met for an implementation of a fast phase gate operation.

Quantum statistics have a profound impact on the properties of systems composed of identical particles. In this Letter, we demonstrate that the quantum statistics of a pair of identical massive particles can be probed by a direct measurement of the exchange symmetry of their wave function even in conditions where the particles always remain spatially well separated and thus the exchange contribution to their interaction energy is negligible. We present two protocols revealing the bosonic or fermionic nature of a pair of particles and discuss possible implementations with a pair of trapped atoms or ions.

Quantum state tomography (QST) is the gold standard technique for obtaining an estimate for the state of small quantum systems in the laboratory. Its application to systems with more than a few constituents (e.g. particles) soon becomes impractical as the effort required grows exponentially in the number of constituents. Developing more efficient techniques is particularly pressing as precisely-controllable quantum systems that are well beyond the reach of QST are emerging in laboratories. Motivated by this, there is a considerable ongoing effort to develop new characterisation tools for quantum many-body systems. Here we demonstrate Matrix Product State (MPS) tomography, which is theoretically proven to allow the states of a broad class of quantum systems to be accurately estimated with an effort that increases efficiently with constituent number. We first prove that this broad class includes the out-of-equilbrium states produced by 1D systems with finite-range interactions, up to any fixed point in time. We then use the technique to reconstruct the dynamical state of a trapped-ion quantum simulator comprising up to 14 entangled spins (qubits): a size far beyond the reach of QST. Our results reveal the dynamical growth of entanglement and description complexity as correlations spread out during a quench: a necessary condition for future beyond-classical performance. MPS tomography should find widespread use to study large quantum many-body systems and to benchmark and verify quantum simulators and computers.

Electromagnetically-induced-transparency (EIT) cooling is a ground-state cooling technique for trapped particles. EIT offers a broader cooling range in frequency space compared to more established methods. In this work, we experimentally investigate EIT cooling in strings of trapped atomic ions. In strings of up to 18 ions, we demonstrate simultaneous ground state cooling of all radial modes in under 1 ms. This is a particularly important capability in view of emerging quantum simulation experiments with large numbers of trapped ions. Our analysis of the EIT cooling dynamics is based on a novel technique enabling single-shot measurements of phonon numbers, by rapid adiabatic passage on a vibrational sideband of a narrow transition.

We investigate the dynamics of an ion sympathetically cooled by another laser-cooled ion or small ion crystal. To this end, we develop simple models of the cooling dynamics in the limit of weak Coulomb interactions. Experimentally, we create a two-ion crystal of Ca$^+$ and Al$^+$ by photo-ionization of neutral atoms produced by laser ablation. We characterize the velocity distribution of the laser-ablated atoms crossing the trap by time-resolved fluorescence spectroscopy. We observe neutral atom velocities much higher than the ones of thermally heated samples and find as a consequence long sympathethic cooling times before crystallization occurs. Our key result is a new technique for detecting the loading of an initially hot ion with energy in the eV range by monitoring the motional state of a Doppler-cooled ion already present in the trap. This technique not only detects the ion but also provides information about dynamics of the sympathetic cooling process.

We demonstrate a new method for the direct measurement of atomic dipole transition matrix elements based on techniques developed for quantum information purposes. The scheme consists of measuring dispersive and absorptive off-resonant light-ion interactions and is applicable to many atomic species. We determine the dipole matrix element pertaining to the Ca II H line, i.e. the 4$^2$S$_{1/2} \leftrightarrow $ 4$^2$P$_{1/2}$ transition of $^{40}$Ca$^+$, for which we find the value 2.8928(43) ea$_0$. Moreover, the method allows us to deduce the lifetime of the 4$^2$P$_{1/2}$ state to be 6.904(26) ns, which is in agreement with predictions from recent theoretical calculations and resolves a longstanding discrepancy between calculated values and experimental results.

The static and dynamic properties of many-body quantum systems are often well described by collective excitations, known as quasiparticles. Engineered quantum systems offer the opportunity to study such emergent phenomena in a precisely controlled and otherwise inaccessible way. We present a spectroscopic technique to study artificial quantum matter and use it for characterizing quasiparticles in a many-body system of trapped atomic ions. Our approach is to excite combinations of the system's fundamental quasiparticle eigenmodes, given by delocalised spin waves. By observing the dynamical response to superpositions of such eigenmodes, we extract the system dispersion relation, magnetic order, and even detect signatures of quasiparticle interactions. Our technique is not limited to trapped ions, and it is suitable for verifying quantum simulators by tuning them into regimes where the collective excitations have a simple form.

The key to explaining a wide range of quantum phenomena is understanding how entanglement propagates around many-body systems. Furthermore, the controlled distribution of entanglement is of fundamental importance for quantum communication and computation. In many situations, quasiparticles are the carriers of information around a quantum system and are expected to distribute entanglement in a fashion determined by the system interactions. Here we report on the observation of magnon quasiparticle dynamics in a one-dimensional many-body quantum system of trapped ions representing an Ising spin model. Using the ability to tune the effective interaction range, and to prepare and measure the quantum state at the individual particle level, we observe new quasiparticle phenomena. For the first time, we reveal the entanglement distributed by quasiparticles around a many-body system. Second, for long-range interactions we observe the divergence of quasiparticle velocity and breakdown of the light-cone picture that is valid for short-range interactions. Our results will allow experimental studies of a wide range of phenomena, such as quantum transport, thermalisation, localisation and entanglement growth, and represent a first step towards a new quantum-optical regime with on-demand quasiparticles with tunable non-linear interactions.

We report on the experimental violation of multipartite Bell inequalities by entangled states of trapped ions. First we consider resource states for measurement-based quantum computation of between 3 and 7 ions and show that all strongly violate a Bell-type inequality for graph states, where the criterion for violation is a sufficiently high fidelity. Second we analyze GHZ states of up to 14 ions generated in a previous experiment using stronger Mermin-Klyshko inequalities, and show that in this case the violation of local realism increases exponentially with system size. These experiments represent a violation of multipartite Bell-type inequalities of deterministically prepared entangled states. In addition, the detection loophole is closed.

Measurement-based quantum computation (MBQC) represents a powerful and flexible framework for quantum information processing, based on the notion of entangled quantum states as computational resources. The most prominent application is the one-way quantum computer, with the cluster state as its universal resource. Here we demonstrate the principles of MBQC using deterministically generated graph states of up to 7 qubits, in a system of trapped atomic ions. Firstly we implement a universal set of operations for quantum computing. Secondly we demonstrate a family of measurement-based quantum error correction codes, and show their improved performance as the code length is increased. We show that all our graph states violate a multipartite Bell inequality and are therefore capable of information processing tasks that cannot be described by a local hidden variable model. The methods presented can directly be scaled up to generate graph states of several tens of qubits.

Studying entanglement growth in quantum dynamics provides both insight into the underlying microscopic processes and information about the complexity of the quantum states, which is related to the efficiency of simulations on classical computers. Recently, experiments with trapped ions, polar molecules, and Rydberg excitations have provided new opportunities to observe dynamics with long-range interactions. We explore nonequilibrium coherent dynamics after a quantum quench in such systems, identifying qualitatively different behavior as the exponent of algebraically decaying spin-spin interactions in a transverse Ising chain is varied. Computing the build-up of bipartite entanglement as well as mutual information between distant spins, we identify linear growth of entanglement entropy corresponding to propagation of quasiparticles for shorter range interactions, with the maximum rate of growth occurring when the Hamiltonian parameters match those for the quantum phase transition. Counter-intuitively, the growth of bipartite entanglement for long-range interactions is only logarithmic for most regimes, i.e., substantially slower than for shorter range interactions. Experiments with trapped ions allow for the realization of this system with a tunable interaction range, and we show that the different phenomena are robust for finite system sizes and in the presence of noise. These results can act as a direct guide for the generation of large-scale entanglement in such experiments, towards a regime where the entanglement growth can render existing classical simulations inefficient.

Quantum systems in mixed states can be unentangled and yet still correlated in a way that is not possible for classical systems. These correlations can be quantified by the quantum discord and might provide a resource for certain mixed-state quantum information processing tasks. Here we report on the generation of discordant states of two trapped atomic ions via Markovian decoherence processes. While entanglement is strictly non-increasing under such operations, discord can be generated in various forms. Firstly we show that, starting from two classically correlated qubits, it is possible to generate discord by applying decoherence to just one of them. Secondly, even when starting with completely uncorrelated systems, we show that discord can be generated via classically correlated decoherence processes. Finally, the Werner states are created. The generated states can be used as a resource state for quantum information transmission and could be readily extended to more ions.

The ability to detect the interaction of light and matter at the single-particle level is becoming increasingly important for many areas of science and technology. The absorption or emission of a photon on a narrow transition of a trapped ion can be detected with near unit probability, thereby enabling the realization of ultra-precise ion clocks and quantum information processing applications. Extending this sensitivity to broad transitions is challenging due to the difficulty of detecting the rapid photon scattering events in this case. Here, we demonstrate a technique to detect the scattering of a single photon on a broad optical transition with high sensitivity. Our approach is to use an entangled state to amplify the tiny momentum kick an ion receives upon scattering a photon. The method should find applications in spectroscopy of atomic and molecular ions and quantum information processing.

A digital quantum simulator is an envisioned quantum device that can be pro- grammed to efficiently simulate any other local system. We demonstrate and investigate the digital approach to quantum simulation in a system of trapped ions. Using sequences of up to 100 gates and 6 qubits, the full time dynamics of a range of spin systems are digitally simulated. Interactions beyond those naturally present in our simulator are accurately reproduced and quantitative bounds are provided for the overall simulation quality. Our results demon- strate the key principles of digital quantum simulation and provide evidence that the level of control required for a full-scale device is within reach.

We propose the quantum simulation of a fermion and an antifermion field modes interacting via a bosonic field mode, and present a possible implementation with two trapped ions. This quantum platform allows for the scalable add-up of bosonic and fermionic modes, and represents an avenue towards quantum simulations of quantum field theories in perturbative and nonperturbative regimes.

We consider the quantum simulation of relativistic quantum mechanics, as described by the Dirac equation and classical potentials, in trapped-ion systems. We concentrate on three problems of growing complexity. First, we study the bidimensional relativistic scattering of single Dirac particles by a linear potential. Furthermore, we explore the case of a Dirac particle in a magnetic field and its topological properties. Finally, we analyze the problem of two Dirac particles that are coupled by a controllable and confining potential. The latter interaction may be useful to study important phenomena as the confinement and asymptotic freedom of quarks.

In a recent experiment, Barreiro et al. demonstrated the fundamental building blocks of an open-system quantum simulator with trapped ions [Nature 470, 486 (2011)]. Using up to five ions, single- and multi-qubit entangling gate operations were combined with optical pumping in stroboscopic sequences. This enabled the implementation of both coherent many-body dynamics as well as dissipative processes by controlling the coupling of the system to an artificial, suitably tailored environment. This engineering was illustrated by the dissipative preparation of entangled two- and four-qubit states, the simulation of coherent four-body spin interactions and the quantum non-demolition measurement of a multi-qubit stabilizer operator. In the present paper, we present the theoretical framework of this gate-based ("digital") simulation approach for open-system dynamics with trapped ions. In addition, we discuss how within this simulation approach minimal instances of spin models of interest in the context of topological quantum computing and condensed matter physics can be realized in state-of-the-art linear ion-trap quantum computing architectures. We outline concrete simulation schemes for Kitaev's toric code Hamiltonian and a recently suggested color code model. The presented simulation protocols can be adapted to scalable and two-dimensional ion-trap architectures, which are currently under development.

A quantum simulator is a device engineered to reproduce the properties of an ideal quantum model. It allows the study of quantum systems that cannot be efficiently simulated on classical computers. While a universal quantum computer is also a quantum simulator, only particular systems have been simulated up to now. Still, there is a wealth of successful cases, such as spin models, quantum chemistry, relativistic quantum physics and quantum phase transitions. Here, we show how to design a quantum simulator for the Majorana equation, a non-Hamiltonian relativistic wave equation that might describe neutrinos and other exotic particles beyond the standard model. The simulation demands the implementation of charge conjugation, an unphysical operation that opens a new front in quantum simulations, including the discrete symmetries associated with complex conjugation and time reversal. Finally, we show how to implement this general method in trapped ions.

We report on quantum simulations of relativistic scattering dynamics using trapped ions. The simulated state of a scattering particle is encoded in both the electronic and vibrational state of an ion, representing the discrete and continuous components of relativistic wave functions. Multiple laser fields and an auxiliary ion simulate the dynamics generated by the Dirac equation in the presence of a scattering potential. Measurement and reconstruction of the particle wave packet enables a frame-by-frame visualization of the scattering processes. By precisely engineering a range of external potentials we are able to simulate text book relativistic scattering experiments and study Klein tunneling in an analogue quantum simulator. We describe extensions to solve problems that are beyond current classical computing capabilities.

Multiparticle entanglement leads to richer correlations than two-particle entanglement and gives rise to striking contradictions with local realism, inequivalent classes of entanglement, and applications such as one-way or topological quantum computing. When exposed to decohering or dissipative environments, multiparticle entanglement yields subtle dynamical features and access to new classes of states and applications. Here, using a string of trapped ions, we experimentally characterize the dynamics of entanglement of a multiparticle state under the influence of decoherence. By embedding an entangled state of four qubits in a decohering environment (via spontaneous decay), we observe a rich dynamics crossing distinctive domains: Bell-inequality violation, entanglement superactivation, bound entanglement, and full separability. We also develop new theoretical tools for characterizing entanglement in quantum states. Our techniques to control the environment can be used to enable novel quantum-computation, state-engineering, and simulation paradigms based on dissipation and decoherence.

We propose the quantum simulation of the Dirac equation with potentials, allowing the study of relativistic scaterring and the Klein tunneling. This quantum relativistic effect permits a positive-energy Dirac particle to propagate through a repulsive potential via the population transfer to negative-energy components. We show how to engineer scalar, pseudoscalar, and other potentials in the 1+1 Dirac equation by manipulating two trapped ions. The Dirac spinor is represented by the internal states of one ion, while its position and momentum are described by those of a collective motional mode. The second ion is used to build the desired potentials with high spatial resolution.

A basic assumption behind the inequalities used for testing noncontextual hidden variable models is that the observables measured on the same individual system are perfectly compatible. However, compatibility is not perfect in actual experiments using sequential measurements. We discuss the resulting "compatibility loophole" and present several methods to rule out certain hidden variable models which obey a kind of extended noncontextuality. Finally, we present a detailed analysis of experimental imperfections in a recent trapped ion experiment and apply our analysis to that case.

We experimentally demonstrate a quantum walk on a line in phase space using one and two trapped ion. A walk with up to 23 steps is realized by subjecting an ion to state-dependent displacement operations interleaved with quantum coin tossing operations. To analyze the ion's motional state after each step we apply a technique that directly maps the probability density distribution onto the ion's internal state. The measured probability distributions and the position's second moment clearly show the non-classical character of the quantum walk. To further highlight the difference between the classical (random) and the quantum walk, we demonstrate the reversibility of the latter. Finally, we extend the quantum walk by using two ions, giving the walker the additional possibility to stay instead of taking a step.

Any residual coupling of a quantum computer to the environment results in computational errors. Encoding quantum information in a so-called decoherence-free subspace provides means to avoid these errors. Despite tremendous progress in employing this technique to extend memory storage times by orders of magnitude, computation within such subspaces has been scarce. Here, we demonstrate the realization of a universal set of quantum gates acting on decoherence-free ion qubits. We combine these gates to realize the first controlled-NOT gate within a decoherence-free, scalable quantum computer.

The Dirac equation is a cornerstone in the history of physics, merging successfully quantum mechanics with special relativity, providing a natural description of the electron spin and predicting the existence of anti-matter. Furthermore, it is able to reproduce accurately the spectrum of the hydrogen atom and its realm, relativistic quantum mechanics, is considered as the natural transition to quantum field theory. However, the Dirac equation also predicts some peculiar effects such as Klein's paradox and Zitterbewegung, an unexpected quivering motion of a free relativistic quantum particle first examined by Schrödinger. These and other predictions would be difficult to observe in real particles, while constituting key fundamental examples to understand relativistic quantum effects. Recent years have seen an increased interest in simulations of relativistic quantum effects in different physical setups, where parameter tunability allows accessibility to different physical regimes. Here, we perform a proof-of-principle quantum simulation of the one-dimensional Dirac equation using a single trapped ion, which is set to behave as a free relativistic quantum particle. We measure as a function of time the particle position and study Zitterbewegung for different initial superpositions of positive and negative energy spinor states, as well as the cross-over from relativistic to nonrelativistic dynamics. The high level of control of trapped-ion experimental parameters makes it possible to simulate elegant textbook examples of relativistic quantum physics.

The question of whether quantum phenomena can be explained by classical models with hidden variables is the subject of a long lasting debate. In 1964, Bell showed that certain types of classical models cannot explain the quantum mechanical predictions for specific states of distant particles. Along this line, some types of hidden variable models have been experimentally ruled out. An intuitive feature for classical models is non-contextuality: the property that any measurement has a value which is independent of other compatible measurements being carried out at the same time. However, the results of Kochen, Specker, and Bell show that non-contextuality is in conflict with quantum mechanics. The conflict resides in the structure of the theory and is independent of the properties of special states. It has been debated whether the Kochen-Specker theorem could be experimentally tested at all. Only recently, first tests of quantum contextuality have been proposed and undertaken with photons and neutrons. Yet these tests required the generation of special quantum states and left various loopholes open. Here, using trapped ions, we experimentally demonstrate a state-independent conflict with non-contextuality. The experiment is not subject to the detection loophole and we show that, despite imperfections and possible measurement disturbances, our results cannot be explained in non-contextual terms.

Quantum computers hold the promise to solve certain computational task much more efficiently than classical computers. We review the recent experimental advancements towards a quantum computer with trapped ions. In particular, various implementations of qubits, quantum gates and some key experiments are discussed. Furthermore, we review some implementations of quantum algorithms such as a deterministic teleportation of quantum information and an error correction scheme.

Optimal control techniques are applied for the decomposition of unitary quantum operations into a sequence of single-qubit gates and entangling operations. To this end, we modify a gradient-ascent algorithm developed for systems of coupled nuclear spins in molecules to make it suitable for trapped ion quantum computing. We decompose unitary operations into entangling gates that are based on a nonlinear collective spin operator and complemented by global spinflip and local light shift gates. Among others, we provide explicit decompositions of controlled-NOT and Toffoli gates, and a simple quantum error correction protocol.

We perform precision measurements of the branching ratios of the 4P3/2 level decay of a single 40Ca+ ion suspended in a linear Paul trap. High precision is achieved by a novel technique based on monitoring the population transfer when repeatedly pumping the ion between different internal states. The branching fractions into the 4S1/2, 3D5/2 and 3D3/2 levels are found to be 0.9347(3), 0.0587(2) and 0.00661(4), respectively. For the branching ratio A(P3/2-S1/2)/\sum_J A(P3/2-D_J)=14.31(5), we find a forty-fold improvement in accuracy as compared to the best previous measurement.

We report on the first absolute transition frequency measurement at the 10^{-15} level with a single, laser-cooled 40Ca+ ion in a linear Paul trap. For this measurement, a frequency comb is referenced to the transportable Cs atomic fountain clock of LNE-SYRTE and is used to measure the S1/2-D5/2 electric-quadrupole transition frequency. After the correction of systematic shifts, the clock transition frequency f_Ca+ = 411 042 129 776 393.2 (1.0) Hz is obtained, which corresponds to a fractional uncertainty within a factor of three of the Cs standard. Future improvements are expected to lead to an uncertainty surpassing the best Cs fountain clocks. In addition, we determine the Lande g-factor of the D5/2 level to be gD5/2=1.2003340(3).

For quantum information processing (QIP) with trapped ions, the isotope 43Ca+ offers the combined advantages of a quantum memory with long coherence time, a high fidelity read out and the possibility of performing two qubit gates on a quadrupole transition with a narrow-band laser. Compared to other ions used for quantum computing, 43Ca+ has a relatively complicated level structure. In this paper we discuss how to meet the basic requirements for QIP and demonstrate ground state cooling, robust state initialization and efficient read out for the hyperfine qubit with a single 43Ca+ ion. A microwave field and a Raman light field are used to drive qubit transitions, and the coherence times for both fields are compared. Phase errors due to interferometric instabilities in the Raman field generation do not limit the experiments on a time scale of 100 ms. We find a quantum information storage time of many seconds for the hyperfine qubit.

Today ion traps are among the most promising physical systems for constructing a quantum device harnessing the computing power inherent in the laws of quantum physics. The standard circuit model of quantum computing requires a universal set of quantum logic gates for the implementation of arbitrary quantum operations. As in classical models of computation, quantum error correction techniques enable rectification of small imperfections in gate operations, thus allowing for perfect computation in the presence of noise. For fault-tolerant computation, it is commonly believed that error thresholds ranging between 10^-4 and 10^-2 will be required depending on the noise model and the computational overhead for realizing the quantum gates. Up to now, all experimental implementations have fallen short of these requirements. Here, we report on a Molmer-Sorensen type gate operation entangling ions with a fidelity of 99.3(1)% which together with single-qubit operations forms a universal set of quantum gates. The gate operation is performed on a pair of qubits encoded in two trapped calcium ions using a single amplitude-modulated laser beam interacting with both ions at the same time. A robust gate operation, mapping separable states onto maximally entangled states is achieved by adiabatically switching the laser-ion coupling on and off. We analyse the performance of a single gate and concatenations of up to 21 gate operations. The gate mechanism holds great promise not only for two-qubit but also for multi-qubit operations.

We propose a geometric phase gate of two ion qubits that are encoded in two levels linked by an optical dipole-forbidden transition. Compared to hyperfine geometric phase gates mediated by electric dipole transitions, the gate has many interesting properties, such as very low spontaneous emission rates, applicability to magnetic field insensitive states, and use of a co-propagating laser beam geometry. We estimate that current technology allows for infidelities of around 10$^{-4}$.

We propose the implementation of a geometric-phase gate on magnetic-field-insensitive qubits with $\hatσ^z$-dependent forces for trapped ion quantum computing. The force is exerted by two laser beams in a Raman configuration. Qubit-state dependency is achieved by a small frequency detuning from the virtually-excited state. Ion species with excited states of long radiative lifetimes are used to reduce the chance of a spontaneous photon emission to less than 10$^{-8}$ per gate-run. This eliminates the main source of gate infidelity of previous implementations. With this scheme it seems possible to reach the fault tolerant threshold.

We discuss techniques that allow for long coherence times in laser spectroscopy experiments with two trapped ions. We show that for this purpose not only entangled ions prepared in decoherence-free subspaces can be used but also a pair of ions that are not entangled but subject to the same kind of phase noise. We apply this technique to a measurement of the electric quadrupole moment of the 3d D5/2 state of 40Ca+ and to a measurement of the linewidth of an ultrastable laser exciting a pair of 40Ca+ ions.

We experimentally investigate nonlinear couplings between vibrational modes of strings of cold ions stored in linear ion traps. The nonlinearity is caused by the ions' Coulomb interaction and gives rise to a Kerr-type interaction Hamiltonian H = n_r*n_s, where n_r,n_s are phonon number operators of two interacting vibrational modes. We precisely measure the resulting oscillation frequency shift and observe a collapse and revival of the contrast in a Ramsey experiment. Implications for ion trap experiments aiming at high-fidelity quantum gate operations are discussed.

The performance of a quantum teleportation algorithm implemented on an ion trap quantum computer is investigated. First the algorithm is analyzed in terms of the teleportation fidelity of six input states evenly distributed over the Bloch sphere. Furthermore, a quantum process tomography of the teleportation algorithm is carried out which provides almost complete knowledge about the algorithm.

Entanglement is recognized as a key resource for quantum computation and quantum cryptography. For quantum metrology, the use of entangled states has been discussed and demonstrated as a means of improving the signal-to-noise ratio. In addition, entangled states have been used in experiments for efficient quantum state detection and for the measurement of scattering lengths. In quantum information processing, manipulation of individual quantum bits allows for the tailored design of specific states that are insensitive to the detrimental influences of an environment. Such 'decoherence-free subspaces' protect quantum information and yield significantly enhanced coherence times. Here we use a decoherence-free subspace with specifically designed entangled states to demonstrate precision spectroscopy of a pair of trapped Ca+ ions; we obtain the electric quadrupole moment, which is of use for frequency standard applications. We find that entangled states are not only useful for enhancing the signal-to-noise ratio in frequency measurements - a suitably designed pair of atoms also allows clock measurements in the presence of strong technical noise. Our technique makes explicit use of non-locality as an entanglement property and provides an approach for 'designed' quantum metrology.

The hyperfine structure of the S1/2-D5/2 quadrupole transition at 729 nm in 43Ca+ has been investigated by laser spectroscopy using a single trapped 43Ca+ ion. We determine the hyperfine structure constants of the metastable level as A=-3.8931(2) MHz and B=-4.241(4) MHz. The isotope shift of the transition with respect to 40Ca+ was measured to be 4134.713(5) MHz. We demonstrate the existence of transitions that become independent of the first-order Zeeman shift at non-zero low magnetic fields. These transitions might be better suited for building a frequency standard than the well-known 'clock transitions' between m=0 levels at zero magnetic field.

A crucial building block for quantum information processing with trapped ions is a controlled-NOT quantum gate. In this paper, two different sequences of laser pulses implementing such a gate operation are analyzed using quantum process tomography. Fidelities of up to 92.6(6)% are achieved for single gate operations and up to 83.4(8)% for two concatenated gate operations. By process tomography we assess the performance of the gates for different experimental realizations and demonstrate the advantage of amplitude--shaped laser pulses over simple square pulses. We also investigate whether the performance of concatenated gates can be inferred from the analysis of the single gates.

Among the various kinds of entangled states, the 'W state' plays an important role as its entanglement is maximally persistent and robust even under particle loss. Such states are central as a resource in quantum information processing and multiparty quantum communication. Here we report the scalable and deterministic generation of four-, five-, six-, seven- and eight-particle entangled states of the W type with trapped ions. We obtain the maximum possible information on these states by performing full characterization via state tomography, using individual control and detection of the ions. A detailed analysis proves that the entanglement is genuine. The availability of such multiparticle entangled states, together with full information in the form of their density matrices, creates a test-bed for theoretical studies of multiparticle entanglement. Independently, -Greenberger-Horne-Zeilinger- entangled states with up to six ions have been created and analysed in Boulder.

We demonstrate how quantum entanglement can be used for precision frequency measurements with trapped ions. In particular, we show how to suppress linear Zeeman shifts in optical frequency measurements by using maximally entangled states of two ions even if the individual ions do not have any field-independent transition. In addition, this technique allows for an accurate measurement of small external field frequency shifts such as the electric quadrupole shift which are important for ion clock experiments.

It is common belief among physicists that entangled states of quantum systems loose their coherence rather quickly. The reason is that any interaction with the environment which distinguishes between the entangled sub-systems collapses the quantum state. Here we investigate entangled states of two trapped Ca$^+$ ions and observe robust entanglement lasting for more than 20 seconds.

We report the realization of an elementary quantum processor based on a linear crystal of trapped ions. Each ion serves as a quantum bit (qubit) to store the quantum information in long lived electronic states. We present the realization of single-qubit and of universal two-qubit logic gates. The qwo-qubit operation relies on the coupling of the ions through their collective quantized motion. A detailed description of the setup and the methods is included.

We report on tomographic means to study the stability of a qubit register based on a string of trapped ions. In our experiment, two ions are held in a linear Paul trap and are entangled deterministically by laser pulses that couple their electronic and motional states. We reconstruct the density matrix using single qubit rotations and subsequent measurements with near-unity detection efficiency. This way, we characterize the created Bell states, the states into which they subsequently decay, and we derive their entanglement, applying different entanglement measures.

A novel method of ground state laser cooling of trapped atoms utilizes the absorption profile of a three (or multi-) level system which is tailored by a quantum interference. With cooling rates comparable to conventional sideband cooling, lower final temperatures may be achieved. The method was experimentally implemented to cool a single Ca$^+$ ion to its vibrational ground state. Since a broad band of vibrational frequencies can be cooled simultaneously, the technique will be particularly useful for the cooling of larger ion strings, thereby being of great practical importance for initializing a quantum register based on trapped ions. We also discuss its application to different level schemes and for ground state cooling of neutral atoms trapped by a far detuned standing wave laser field.

Ground state laser cooling of a single trapped ion is achieved using a technique which tailors the absorption profile for the cooling laser by exploiting electromagnetically induced transparency in the Zeeman structure of a dipole transition. This new method is robust, easy to implement and proves particularly useful for cooling several motional degrees of freedom simultaneously, which is of great practical importance for the implementation of quantum logic schemes with trapped ions.

We have cooled a two-ion-crystal to the ground state of its collective modes of motion. Laser cooling, more specific resolved sideband cooling is performed sympathetically by illuminating only one of the two $^{40}$Ca$^+$ ions in the crystal. The heating rates of the motional modes of the crystal in our linear trap have been measured, and we found them considerably smaller than those previously reported by Q. Turchette {\em et. al.} Phys. Rev. A 61, 063418 (2000) in the case of trapped $^9$Be$^+$ ions. After the ground state is prepared, coherent quantum state manipulation of the atomic population can be performed. Within the coherence time, up to 12 Rabi oscillations are observed, showing that many coherent manipulations can be achieved. Coherent excitation of each ion individually and ground state cooling are important tools for the realization of quantum information processing in ion traps.

We investigate theoretically the speed limit of quantum gate operations for ion trap quantum information processors. The proposed methods use laser pulses for quantum gates which entangle the electronic and vibrational degrees of freedom of the trapped ions. Two of these methods are studied in detail and for both of them the speed is limited by a combination of the recoil frequency of the relevant electronic transition, and the vibrational frequency in the trap. We have experimentally studied the gate operations below and above this speed limit. In the latter case, the fidelity is reduced, in agreement with our theoretical findings. // Changes: a) error in equ. 24 and table III repaired b) reference Jonathan et al, quant-ph/ 0002092, added (proposes fast quantum gates using the AC-Stark effect)