D. Leibfried

We study the impact of an unshielded dielectric $\unicode{x2013}$ here, a bare optical fiber $\unicode{x2013}$ on a $^{40}$Ca${^+}$ ion held several hundred $μ$m away in a cryogenic surface electrode trap. We observe distance-dependent stray electric fields of up to a few kV/m due to the dielectric, which drift on average less than 10% per month and can be fully compensated with reasonable voltages on the trap electrodes. We observe ion motional heating rates attributable to the dielectric of $\approx$30 quanta per second at an ion-fiber distance of 215(4) $μ$m and $\approx$1.5 MHz motional frequency. These results demonstrate the viability of using unshielded, trap-integrated dielectric objects such as miniature optical cavities or other optical elements in cryogenic surface electrode ion traps.

Cooling of atomic motion is a crucial tool for many branches of atomic physics, ranging from fundamental physics explorations to quantum information and sensing. For trapped ions, electromagnetically-induced-transparency (EIT) cooling has received attention for the relative speed, low laser power requirements, and broad cooling bandwidth of the technique. However, in applications where the ion used for cooling has hyperfine structure to enable long coherence times, it is difficult to find a closed three-level system in which to perform standard EIT cooling. Here, we demonstrate successful EIT cooling on 25Mg+ by the addition of an extra laser frequency; this method can be applied to any ion with non-zero nuclear spin. Furthermore, we demonstrate simultaneous EIT cooling of all axial modes in mixed-species crystals 9Be+ - 25Mg+ and 9Be+ - 25Mg+ - 9Be+ through the 25Mg+ ion.

We show experimentally that a broad class of interactions involving quantum harmonic oscillators can be made stronger (amplified) using a unitary squeezing protocol. While our demonstration uses the motional and spin states of a single trapped $^{25}$Mg$^{+}$ ion, the scheme applies generally to Hamiltonians involving just a single harmonic oscillator as well as Hamiltonians coupling the oscillator to another quantum degree of freedom such as a qubit, covering a large range of systems of interest in quantum information and metrology applications. Importantly, the protocol does not require knowledge of the parameters of the Hamiltonian to be amplified, nor does it require a well-defined phase relationship between the squeezing interaction and the rest of the system dynamics, making it potentially useful in instances where certain aspects of a signal or interaction may be unknown or uncontrolled.

Transport, separation, and merging of trapped ion crystals are essential operations for most large-scale quantum computing architectures. In this work, we develop a theoretical framework that describes the dynamics of ions in time-varying potentials with a motional squeeze operator, followed by a motional displacement operator. Using this framework, we develop a new, general protocol for trapped ion transport, separation, and merging. We show that motional squeezing can prepare an ion wave packet to enable transfer from the ground state of one trapping potential to another. The framework and protocol are applicable if the potential is harmonic over the extent of the ion wave packets at all times. As illustrations, we discuss two specific operations: changing the strength of the confining potential for a single ion, and separating same-species ions with their mutual Coulomb force. Both of these operations are, ideally, free of residual motional excitation.

Universal control of multiple qubits -- the ability to entangle qubits and to perform arbitrary individual qubit operations -- is a fundamental resource for quantum computation, simulation, and networking. Here, we implement a new laser-free scheme for universal control of trapped ion qubits based on microwave magnetic fields and radiofrequency magnetic field gradients. We demonstrate high-fidelity entanglement and individual control by creating symmetric and antisymmetric two-qubit maximally entangled states with fidelities in the intervals [0.9983, 1] and [0.9964, 0.9988], respectively, at 68% confidence, corrected for state initialization error. This technique is robust against multiple sources of decoherence, usable with essentially any trapped ion species, and has the potential to perform simultaneous entangling operations on many pairs of ions without increasing control signal power or complexity.

Strong and precisely-controlled interactions between quantum objects are essential for quantum information processing, simulation, and sensing, and for the formation of exotic quantum matter. A well-established paradigm for coupling otherwise weakly-interacting quantum objects is to use auxiliary bosonic quantum excitations to mediate the interactions. Important examples include photon-mediated interactions between atoms, superconducting qubits, and color centers in diamond, and phonon-mediated interactions between trapped ions and between optical and microwave photons. Boson-mediated interactions can in principle be amplified through parametric driving of the boson channel; the drive need not couple directly to the interacting quantum objects. This technique has been proposed for a variety of quantum platforms, but has not to date been realized in the laboratory. Here we experimentally demonstrate the amplification of a boson-mediated interaction between two trapped-ion qubits by parametric modulation of the trapping potential. The amplification provides up to a 3.25-fold increase in the interaction strength, validated by measuring the speedup of two-qubit entangling gates. This amplification technique can be used in any quantum platform where parametric modulation of the boson channel is possible, enabling exploration of new parameter regimes and enhanced quantum information processing.

We report high-fidelity state readout of a trapped ion qubit using a trap-integrated photon detector. We determine the hyperfine qubit state of a single $^9$Be$^+$ ion held in a surface-electrode rf ion trap by counting state-dependent ion fluorescence photons with a superconducting nanowire single-photon detector (SNSPD) fabricated into the trap structure. The average readout fidelity is 0.9991(1), with a mean readout duration of 46 $μ$s, and is limited by the polarization impurity of the readout laser beam and by off-resonant optical pumping. Because there are no intervening optical elements between the ion and the detector, we can use the ion fluorescence as a self-calibrated photon source to determine the detector quantum efficiency and its dependence on photon incidence angle and polarization.

Two vertical-external-cavity surface-emitting laser (VECSEL) systems producing ultraviolet (UV) radiation at 235 nm and 313 nm are demonstrated. The systems are suitable for quantum information processing applications with trapped beryllium ions. Each system consists of a compact, single-frequency, continuous-wave VECSEL producing high-power near-infrared light, tunable over tens of nanometers. One system generates 2.4 W at 940 nm, using a gain mirror based on GaInAs/GaAs quantum wells, which is converted to 54 mW of 235 nm light for photoionization of neutral beryllium atoms. The other system uses a novel gain mirror based on GaInNAs/GaAs quantum-wells, enabling wavelength extension with manageable strain in the GaAs lattice. This system generates 1.6 W at 1252 nm, which is converted to 41 mW of 313 nm light that is used to laser cool trapped $^{9}$Be$^{+}$ ions and to implement quantum state preparation and detection. The 313 nm system is also suitable for implementing high-fidelity quantum gates, and more broadly, our results extend the capabilities of VECSEL systems for applications in atomic, molecular, and optical physics.

Scaling quantum information processors is a challenging task, requiring manipulation of a large number of qubits with high fidelity and a high degree of connectivity. For trapped ions, this could be realized in a two-dimensional array of interconnected traps in which ions are separated, transported and recombined to carry out quantum operations on small subsets of ions. Here, we use a junction connecting orthogonal linear segments in a two-dimensional (2D) trap array to reorder a two-ion crystal. The secular motion of the ions experiences low energy gain and the internal qubit levels maintain coherence during the reordering process, therefore demonstrating a promising method for providing all-to-all connectivity in a large-scale, two- or three-dimensional trapped-ion quantum information processor.

The dominant error sources for state-of-the-art laser-free trapped-ion entangling gates are decoherence of the qubit state and the ion motion. The effect of these decoherence mechanisms can be suppressed with additional control fields, or with techniques that have the disadvantage of reducing gate speed. Here, we propose using a near-motional-frequency magnetic field gradient to implement a laser-free gate that is simultaneously resilient to both types of decoherence, does not require additional control fields, and has a relatively small cost in gate speed.

A mixed-species geometric phase gate has been proposed for implementing quantum logic spectroscopy on trapped ions that combines probe and information transfer from the spectroscopy to the logic ion in a single pulse. We experimentally realize this method, show how it can be applied as a technique for identifying transitions in currently intractable atoms or molecules, demonstrate its reduced temperature sensitivity, and observe quantum-enhanced frequency sensitivity when it is applied to multi-ion chains. Potential applications include improved readout of trapped-ion clocks and simplified error syndrome measurements for quantum error correction.

Detection of the weakest forces in nature and the search for new physics are aided by increasingly sensitive measurements of the motion of mechanical oscillators. However, the attainable knowledge of an oscillator's motion is limited by quantum fluctuations that exist even if the oscillator is in its lowest possible energy state. Here we demonstrate a widely applicable technique for amplifying coherent displacements of a mechanical oscillator with initial magnitudes well below these zero-point fluctuations. When applying two orthogonal "squeezing" interactions before and after a small displacement, the displacement is amplified, ideally with no added quantum noise. We implement this protocol with a trapped-ion mechanical oscillator and measure an increase of up to 17.5(3) decibels in sensitivity to small displacements.

We present a new method of spin-motion coupling for trapped ions using microwaves and a magnetic field gradient oscillating close to the ions' motional frequency. We demonstrate and characterize this coupling experimentally using a single ion in a surface-electrode trap that incorporates current-carrying electrodes to generate the microwave field and the oscillating magnetic field gradient. Using this method, we perform resolved-sideband cooling of a single motional mode to its ground state.

We present a general theory for laser-free entangling gates with trapped-ion hyperfine qubits, using either static or oscillating magnetic-field gradients combined with a pair of uniform microwave fields symmetrically detuned about the qubit frequency. By transforming into a `bichromatic' interaction picture, we show that either ${\hatσ_φ\otimes\hatσ_φ}$ or ${\hatσ_{z}\otimes\hatσ_{z}}$ geometric phase gates can be performed. The gate basis is determined by selecting the microwave detuning. The driving parameters can be tuned to provide intrinsic dynamical decoupling from qubit frequency fluctuations. The ${\hatσ_{z}\otimes\hatσ_{z}}$ gates can be implemented in a novel manner which eases experimental constraints. We present numerical simulations of gate fidelities assuming realistic parameters.

Studying a single atomic ion confined in a time-dependent periodic anharmonic potential, we find large amplitude trajectories stable for millions of oscillation periods in the presence of stochastic laser cooling. The competition between energy gain from the time-dependent drive and damping leads to the stabilization of such stochastic limit cycles. Instead of converging to the global minimum of the averaged potential, the steady-state phase-space distribution develops multiple peaks in the regions of phase space where the frequency of the motion is close to a multiple of the periodic drive. Such distinct nonequilibrium behaviour can be observed in realistic radio-frequency traps with laser-cooled ions, suggesting that Paul traps offer a well-controlled test-bed for studying transport and dynamics of microscopically driven systems.

We study the stochastic dynamics of a particle in a periodically driven potential. For atomic ions trapped in radio-frequency Paul traps, noise heating and laser cooling typically act slowly in comparison with the unperturbed motion. These stochastic processes can be accounted for in terms of a probability distribution defined over the action variables, which would otherwise be conserved within the regular regions of the Hamiltonian phase space. We present a semiclassical theory of low-saturation laser cooling applicable from the limit of low-amplitude motion to large-amplitude motion, accounting fully for the time-dependent and anharmonic trap. We employ our approach to a detailed study of the stochastic dynamics of a single ion, drawing general conclusions regarding the nonequilibrium dynamics of laser-cooled trapped ions. We predict a regime of anharmonic motion in which laser cooling becomes diffusive (i.e., it is equally likely to cool the ion as it is to heat it), and can also turn into effective heating. This implies that a high-energy ion could be easily lost from the trap despite being laser cooled; however, we find that this loss can be counteracted using a laser detuning much larger than Doppler detuning.

We present a comprehensive phase-space treatment of the motion of charged particles in electrodynamic traps. Focusing on five-wire surface-electrode Paul traps, we study the details of integrable and chaotic motion of a single ion. We introduce appropriate phase-space measures and give a universal characterization of the trap effectiveness as a function of the parameters. We rigorously derive the commonly used (time-independent) pseudopotential approximation, quantify its regime of validity and analyze the mechanism of its breakdown within the time-dependent potential. The phase space approach that we develop gives a general framework for describing ion dynamics in a broad variety of surface Paul traps. To probe this framework experimentally, we propose and analyze, using numerical simulations, an experiment that can be realized with an existing four-wire trap. We predict a robust experimental signature of the existence of trapping pockets within a mixed regular and chaotic phase-space structure. Intricately rich escape dynamics suggest that surface traps give access to exploring microscopic Hamiltonian transport phenomena in phase space.

Effective spin-spin interactions between N+1 qubits enable the determination of the eigenvalue of an arbitrary Pauli product of dimension N with a constant, small number of multi-qubit gates that is independent of N and encodes the eigenvalue in the measurement basis states of an extra ancilla qubit. Such interactions are available whenever qubits can be coupled to a shared harmonic oscillator, a situation that can be realized in several physical qubit implementations. For example, suitable interactions have already been realized for up to 14 qubits in ion traps. It should be possible to implement stabilizer codes for quantum error correction with a constant number of multi-qubit gates, in contrast to typical constructions using a number of two-qubit gates that increases as a function of N. The special case of finding the parity of N qubits only requires a small number of operations that is independent of N. This compares favorably to algorithms for computing the parity on conventional machines, which implies a genuine quantum advantage.

Electric-field noise from the surfaces of ion-trap electrodes couples to the ion's charge causing heating of the ion's motional modes. This heating limits the fidelity of quantum gates implemented in quantum information processing experiments. The exact mechanism that gives rise to electric-field noise from surfaces is not well-understood and remains an active area of research. In this work, we detail experiments intended to measure ion motional heating rates with exchangeable surfaces positioned in close proximity to the ion, as a sensor to electric-field noise. We have prepared samples with various surface conditions, characterized in situ with scanned probe microscopy and electron spectroscopy, ranging in degrees of cleanliness and structural order. The heating-rate data, however, show no significant differences between the disparate surfaces that were probed. These results suggest that the driving mechanism for electric-field noise from surfaces is due to more than just thermal excitations alone.

We demonstrate superconducting nanowire single photon detectors with 76 +/- 4 % system detection efficiency at a wavelength of 315 nm and an operating temperature of 3.2 K, with a background count rate below 1 count per second at saturated detection efficiency. We propose integrating these detectors into planar surface electrode radio-frequency Paul traps for use in trapped ion quantum information processing. We operate detectors integrated into test ion trap structures at 3.8 K both with and without typical radio-frequency trapping electric fields. The trapping fields reduce system detection efficiency by 9 %, but do not increase background count rates.

We implement faster-than-adiabatic two-qubit phase gates using smooth state-dependent forces. The forces are designed to leave no final motional excitation, independently of the initial motional state in the harmonic, small-oscillations limit. They are simple, explicit functions of time and the desired logical phase of the gate, and are based on quadratic invariants of motion and Lewis-Riesenfeld phases of the normal modes.

Entangled states are a crucial resource for quantum-based technologies such as quantum computers and quantum communication systems (1,2). Exploring new methods for entanglement generation is important for diversifying and eventually improving current approaches. Here, we create entanglement in atomic ions by applying laser fields to constrain the evolution to a restricted number of states, in an approach that has become known as "quantum Zeno dynamics" (3-5). With two trapped $^9\rm{Be}^+$ ions, we obtain Bell state fidelities up to $0.990^{+2}_{-5}$, with three ions, a W-state (6) fidelity of $0.910^{+4}_{-7}$ is obtained. Compared to other methods of producing entanglement in trapped ions, this procedure is relatively insensitive to certain imperfections such as fluctuations in laser intensity, laser frequency, and ion-motion frequencies.

Precision control over hybrid physical systems at the quantum level is important for the realization of many quantum-based technologies. In the field of quantum information processing (QIP) and quantum networking, various proposals discuss the possibility of hybrid architectures where specific tasks are delegated to the most suitable subsystem. For example, in quantum networks, it may be advantageous to transfer information from a subsystem that has good memory properties to another subsystem that is more efficient at transporting information between nodes in the network. For trapped-ions, a hybrid system formed of different species introduces extra degrees of freedom that can be exploited to expand and refine the control of the system. Ions of different elements have previously been used in QIP experiments for sympathetic cooling, creation of entanglement through dissipation, and quantum non-demolition (QND) measurement of one species with another. Here, we demonstrate an entangling quantum gate between ions of different elements which can serve as an important building block of QIP, quantum networking, precision spectroscopy, metrology, and quantum simulation. A geometric phase gate between a $^9$Be$^+$ ion and a $^{25}$Mg$^+$ ion is realized through an effective spin-spin interaction generated by state-dependent forces induced with laser beams. Combined with single-qubit gates and same-species entangling gates, this mixed-element entangling gate provides a complete set of gates over such a hybrid system for universal QIP. Using a sequence of such gates, we demonstrate a Controlled-NOT (CNOT) gate and a SWAP gate. We further demonstrate the robustness of these gates against thermal excitation and show improved detection in quantum logic spectroscopy (QLS). We also observe a strong violation of a CHSH-type Bell inequality on entangled states composed of different ion species.

We investigate the dynamics of mixed-species ion crystals during transport between spatially distinct locations in a linear Paul trap in the diabatic regime. In a general mixed-species crystal, all degrees of freedom along the direction of transport are excited by an accelerating well, so unlike the case of same-species ions, where only the center-of-mass-mode is excited, several degrees of freedom have to be simultaneously controlled by the transport protocol. We design protocols that lead to low final excitations in the diabatic regime using invariant-based inverse-engineering for two different-species ions and also show how to extend this approach to longer mixed-species ion strings. Fast transport of mixed-species ion strings can significantly reduce the time overhead in certain architectures for scalable quantum information processing with trapped ions.

We describe an ex-situ surface-cleaning procedure that is shown to reduce motional heating from ion-trap electrodes. This precleaning treatment, to be implemented immediately before the final assembly and vacuum processing of ion traps, removes surface contaminants remaining after the electrode-fabrication process. We incorporate a multi-angle ion-bombardment treatment intended to clean the electrode surfaces and interelectrode gaps of microfabricated traps. This procedure helps to minimize redeposition in the gaps between electrodes that can cause electrical shorts. We report heating rates in a stylus-type ion trap prepared in this way that are lower by one order of magnitude compared to a similar untreated stylus-type trap using the same experimental setup.

We show how to create quantum gates of arbitrary speed between trapped ions, using a laser walking wave, with complete insensitivity to drift of the optical phase, and requiring cooling only to the Lamb-Dicke regime. We present pulse sequences that satisfy the requirements and are easy to produce in the laboratory.

Entangled states are a key resource in fundamental quantum physics, quantum cryp-tography, and quantum computation [1].To date, controlled unitary interactions applied to a quantum system, so-called "quantum gates", have been the most widely used method to deterministically create entanglement [2]. These processes require high-fidelity state preparation as well as minimizing the decoherence that inevitably arises from coupling between the system and the environment and imperfect control of the system parameters. Here, on the contrary, we combine unitary processes with engineered dissipation to deterministically produce and stabilize an approximate Bell state of two trapped-ion qubits independent of their initial state. While previous works along this line involved the application of sequences of multiple time-dependent gates [3] or generated entanglement of atomic ensembles dissipatively but relied on a measurement record for steady-state entanglement [4], we implement the process in a continuous time-independent fashion, analogous to optical pumping of atomic states. By continuously driving the system towards steady-state, the entanglement is stabilized even in the presence of experimental noise and decoherence. Our demonstration of an entangled steady state of two qubits represents a step towards dissipative state engineering, dissipative quantum computation, and dissipative phase transitions [5-7]. Following this approach, engineered coupling to the environment may be applied to a broad range of experimental systems to achieve desired quantum dynamics or steady states. Indeed, concurrently with this work, an entangled steady state of two superconducting qubits was demonstrated using dissipation [8].

We demonstrate a trapped-ion entangling-gate scheme proposed by Bermudez et al. [Phys. Rev. A 85, 040302 (2012)]. Simultaneous excitation of a strong carrier and a single-sideband transition enables deterministic creation of entangled states. The method works for magnetic field-insensitive states, is robust against thermal excitations, includes dynamical decoupling from qubit dephasing errors, and provides simplifications in experimental implementation compared to some other entangling gates with trapped ions. We achieve a Bell state fidelity of 0.974(4) and identify the main sources of error.

Microwave near-field quantum control of spin and motional degrees of freedom of 25Mg+ ions can be used to generate two-ion entanglement, as recently demonstrated in Ospelkaus et al. [Nature 476, 181 (2011)]. Here, we describe additional details of the setup and calibration procedures for these experiments. We discuss the design and characteristics of the surface-electrode trap and the microwave system, and compare experimental measurements of the microwave near-fields with numerical simulations. Additionally, we present a method that utilizes oscillating magnetic-field gradients to detect micromotion induced by the ponderomotive radio-frequency potential in linear traps. Finally, we discuss the present limitations of microwave-driven two-ion entangling gates in our system.

Individual-qubit addressing is a prerequisite for many instances of quantum information processing. We demonstrate this capability on trapped-ion qubits with microwave near-fields delivered by electrode structures integrated into a microfabricated surface-electrode trap. We describe four approaches that may be used in quantum information experiments with hyperfine levels as qubits. We implement individual control on two 25Mg+ ions separated by 4.3 micrometer and find spin-flip crosstalk errors on the order of 10^(-3).

We investigate the motional dynamics of single and multiple ions during transport between and separation into spatially distinct locations in a multi-zone linear Paul trap. A single 9Be+ ion in a 2 MHz harmonic well located in one zone was laser-cooled to near its ground state of motion and transported 370 micrometers by moving the well to another zone. This was accomplished in 8 microseconds, corresponding to 16 periods of oscillation. Starting from a state with n=0.1 quanta, during transport the ion was excited to a displaced coherent state with n=1.6 quanta but on completion was returned close to its motional ground state with n=0.2. Similar results were achieved for the transport of two ions. We also separated chains of up to 9 ions from one potential well to two distinct potential wells. With two ions this was accomplished in 55 microseconds, with final excitations of about 2 quanta for each ion. Fast coherent transport and separation can significantly reduce the time overhead in certain architectures for scalable quantum information processing with trapped ions.

As experimental platforms for quantum information processing continue to mature, characterization of the quality of unitary gates that can be applied to their quantum bits (qubits) becomes essential. Eventually, the quality must be sufficiently high to support arbitrarily long quantum computations. Randomized benchmarking already provides a platform-independent method for assessing the quality of one-qubit rotations. Here we describe an extension of this method to multi-qubit gates. We provide a platform-independent protocol for evaluating the performance of experimental Clifford unitaries, which form the basis of fault-tolerant quantum computing. We implemented the benchmarking protocol with trapped-ion two-qubit phase gates and one-qubit gates and found an error per random two-qubit Clifford unitary of $0.162 \pm 0.008$, thus setting the first benchmark for such unitaries. By implementing a second set of sequences with an extra two-qubit phase gate at each step, we extracted an error per phase gate of $0.069 \pm 0.017$. We conducted these experiments with movable, sympathetically cooled ions in a multi-zone Paul trap - a system that can in principle be scaled to larger numbers of ions.

Anomalous heating of trapped atomic ions is a major obstacle to their use as quantum bits in a scalable quantum computer. The physical origin of this heating is not fully understood, but experimental evidence suggests that it is caused by electric-field noise emanating from the surface of the trap electrodes. In this study, we have investigated the role that adsorbates on the electrodes play by identifying contaminant overlayers, developing an in situ argon-ion beam cleaning procedure, and measuring ion heating rates before and after cleaning the trap electrodes' surfaces. We find a reduction of two orders of magnitude in heating rate after cleaning.

Preparing molecules at rest and in a highly pure quantum state is a long standing dream in chemistry and physics, so far achieved only for a select set of molecules in dedicated experimental setups. Here, a quantum-limited combination of mass spectrometry and Raman spectroscopy is proposed that should be applicable to a wide range of molecular ions. Excitation of electrons in the molecule followed by uncontrolled decay and branching into several lower energy states is avoided. Instead, the molecule is always connected to rotational states within the electronic and vibrational ground-state manifold, while a co-trapped atomic ion provides efficient entropy removal and allows for extraction of information on the molecule. The outlined techniques might enable preparation, manipulation and measurement of a large multitude of molecular ion species with the same instrument, with applications including, but not limited to, precise determination of molecular properties and fundamental tests of physics.

We have demonstrated transport of Be+ ions through a 2D Paul-trap array that incorporates an X-junction, while maintaining the ions near the motional ground-state of the confining potential well. We expand on the first report of the experiment [1], including a detailed discussion of how the transport potentials were calculated. Two main mechanisms that caused motional excitation during transport are explained, along with the methods used to mitigate such excitation. We reduced the motional excitation below the results in Ref. [1] by a factor of approximately 50. The effect of a mu-metal shield on qubit coherence is also reported. Finally, we examined a method for exchanging energy between multiple motional modes on the few-quanta level, which could be useful for cooling motional modes without directly accessing the modes with lasers. These results establish how trapped ions can be transported in a large-scale quantum processor with high fidelity.

We theoretically and experimentally examine the effects of anharmonic terms in the trapping potential for linear chains of trapped ions. We concentrate on two different effects that become significant at different levels of anharmonicity. The first is a modification of the oscillation frequencies and amplitudes of the ions' normal modes of vibration for multi-ion crystals, resulting from each ion experiencing a different curvature in the potential. In the second effect, which occurs with increased anharmonicity or higher excitation amplitude, amplitude-dependent shifts of the normal-mode frequencies become important. We evaluate normal-mode frequency and amplitude shifts, and comment on the implications for quantum information processing and quantum state engineering. Since the ratio of the anharmonic to harmonic terms typically increases as the ion--electrode distance decreases, anharmonic effects will become more significant as ion trap sizes are reduced. To avoid unwanted problems, anharmonicities should therefore be taken into account at the design stage of trap development.

Control over physical systems at the quantum level is a goal shared by scientists in fields as diverse as metrology, information processing, simulation and chemistry. For trapped atomic ions, the quantized motional and internal degrees of freedom can be coherently manipulated with laser light. Similar control is difficult to achieve with radio frequency or microwave radiation because the essential coupling between internal degrees of freedom and motion requires significant field changes over the extent of the atoms' motion. The field gradients are negligible at these frequencies for freely propagating fields; however, stronger gradients can be generated in the near-field of microwave currents in structures smaller than the free-space wavelength. In the experiments reported here, we coherently manipulate the internal quantum states of the ions on time scales of 20 ns. We also generate entanglement between the internal degrees of freedom of two atoms with a gate operation suitable for general quantum computation. We implement both operations through the magnetic fields from microwave currents in electrodes that are integrated into the micro-fabricated trap structure and create an entangled state with fidelity 76(3) %. This approach, where the quantum control mechanism is integrated into the trapping device in a scalable manner, can potentially benefit quantum information processing, simulation and spectroscopy.

With a 9Be+ trapped-ion hyperfine-states qubit, we demonstrate an error probability per randomized single-qubit gate of 2.0(2) x 10^-5, below the threshold estimate of 10^-4 commonly considered sufficient for fault-tolerant quantum computing. The 9Be+ ion is trapped above a microfabricated surface-electrode ion trap and is manipulated with microwaves applied to a trap electrode. The achievement of low single-qubit-gate errors is an essential step toward the construction of a scalable quantum computer.

The harmonic oscillator is one of the simplest physical systems but also one of the most fundamental. It is ubiquitous in nature, often serving as an approximation for a more complicated system or as a building block in larger models. Realizations of harmonic oscillators in the quantum regime include electromagnetic fields in a cavity [1-3] and the mechanical modes of a trapped atom [4] or macroscopic solid [5]. Quantized interaction between two motional modes of an individual trapped ion has been achieved by coupling through optical fields [6], and entangled motion of two ions in separate locations has been accomplished indirectly through their internal states [7]. However, direct controllable coupling between quantized mechanical oscillators held in separate locations has not been realized previously. Here we implement such coupling through the mutual Coulomb interaction of two ions held in trapping potentials separated by 40 um (similar work is reported in a related paper [8]). By tuning the confining wells into resonance, energy is exchanged between the ions at the quantum level, establishing that direct coherent motional coupling is possible for separately trapped ions. The system demonstrates a building block for quantum information processing and quantum simulation. More broadly, this work is a natural precursor to experiments in hybrid quantum systems, such as coupling a trapped ion to a quantized macroscopic mechanical or electrical oscillator [9-13].

Integration of fiber optics may play a critical role in the development of quantum information processors based on trapped ions and atoms by enabling scalable collection and delivery of light and coupling trapped ions to optical microcavities. We trap 24Mg+ ions in a surface-electrode Paul trap that includes an integrated optical fiber for detecting 280-nm fluorescence photons. The collection numerical aperture is 0.37 and total collection efficiency is 2.1 %. The ion can be positioned between 80 \mum and 100 \mum from the tip of the fiber by use of an adjustable rf-pseudopotential.

We report on the design, fabrication, and preliminary testing of a 150 zone array built in a `surface-electrode' geometry microfabricated on a single substrate. We demonstrate transport of atomic ions between legs of a `Y'-type junction and measure the in-situ heating rates for the ions. The trap design demonstrates use of a basic component design library that can be quickly assembled to form structures optimized for a particular experiment.

The universal quantum computer is a device capable of simulating any physical system and represents a major goal for the field of quantum information science. Algorithms performed on such a device are predicted to offer significant gains for some important computational tasks. In the context of quantum information, "universal" refers to the ability to perform arbitrary unitary transformations in the system's computational space. The combination of arbitrary single-quantum-bit (qubit) gates with an entangling two-qubit gate is a gate set capable of achieving universal control of any number of qubits, provided that these gates can be performed repeatedly and between arbitrary pairs of qubits. Although gate sets have been demonstrated in several technologies, they have as yet been tailored toward specific tasks, forming a small subset of all unitary operators. Here we demonstrate a programmable quantum processor that realises arbitrary unitary transformations on two qubits, which are stored in trapped atomic ions. Using quantum state and process tomography, we characterise the fidelity of our implementation for 160 randomly chosen operations. This universal control is equivalent to simulating any pairwise interaction between spin-1/2 systems. A programmable multi-qubit register could form a core component of a large-scale quantum processor, and the methods used here are suitable for such a device.

We report techniques for the fabrication of multi-zone linear RF Paul traps that exploit the machinability and electrical conductivity of degenerate silicon. The approach was tested by trapping and laser cooling 24Mg+ ions in two trap geometries: a single-zone two-layer trap and a multi-zone surface-electrode trap. From the measured ion motional heating rate we determine an electric field spectral density at the ion's position of approximately 1E-10 (V/m)^2/Hz at a frequency of 1.125 MHz when the ion lies 40 micron above the trap surface. One application of these devices is controlled manipulation of atomic ion qubits, the basis of one form of quantum information processing.

Large-scale quantum information processors must be able to transport and maintain quantum information, and repeatedly perform logical operations. Here we demonstrate a combination of all the fundamental elements required to perform scalable quantum computing using qubits stored in the internal states of trapped atomic ions. We quantify the repeatability of a multi-qubit operation, observing no loss of performance despite qubit transport over macroscopic distances. Key to these results is the use of different pairs of beryllium ion hyperfine states for robust qubit storage, readout and gates, and simultaneous trapping of magnesium re-cooling ions along with the qubit ions.

A scalable, multiplexed ion trap for quantum information processing is fabricated and tested. The trap design and fabrication process are optimized for scalability to small trap size and large numbers of interconnected traps, and for integration of control electronics and optics. Multiple traps with similar designs are tested with Cd+, Mg+, and Sr+ ions at room temperature and with Sr+ at 6 K, with respective ion lifetimes of 90 s, 300 +/- 30 s, 56 +/- 6 s, and 4.5 +/- 1.1 hours. The motional heating rate for Mg+ at room temperature and a trap frequency of 1.6 MHz is measured to be 7 +/- 3 quanta per millisecond. For Sr+ at 6 K and 540 kHz the heating rate is measured to be 220 +/- 30 quanta per second.

We report reliable transport of 9Be+ ions through a 2-D trap array that includes a separate loading/reservoir zone and an "X-junction". During transport the ion's kinetic energy in its local well increases by only a few motional quanta and internal-state coherences are preserved. We also examine two sources of energy gain during transport: a particular radio-frequency (RF) noise heating mechanism and digital sampling noise. Such studies are important to achieve scaling in a trapped-ion quantum information processor.

This submission is an introduction to microfabricated ion traps. We cover the basics of Paul traps, various geometries for realizing the traps, a number of design considerations, and, finally, a review of existing microfabricated traps.

Oscillating magnetic fields and field gradients can be used to implement single-qubit rotations and entangling multi-qubit quantum gates for trapped-ion quantum information processing (QIP). With fields generated by currents in microfabricated surface-electrode traps, it should be possible to achieve gate speeds that are comparable to those of optically induced gates for realistic distances between the ion crystal and the electrode surface. Magnetic-field-mediated gates have the potential to significantly reduce the overhead in laser beam control and motional state initialization compared to current QIP experiments with trapped ions and will eliminate spontaneous scattering, a fundamental source of decoherence in laser-mediated gates.

Many efforts are currently underway to build a device capable of large scale quantum information processing (QIP). Whereas QIP has been demonstrated for a few qubits in several systems, many technical difficulties must be overcome in order to construct a large-scale device. In one proposal for large-scale QIP, trapped ions are manipulated by precisely controlled light pulses and moved through and stored in multizone trap arrays. The technical overhead necessary to precisely control both the ion geometrical configurations and the laser interactions is demanding. Here we propose methods that significantly reduce the overhead on laser beam control for performing single and multiple qubit operations on trapped ions. We show how a universal set of operations can be implemented by controlled transport of ions through stationary laser beams. At the same time, each laser beam can be used to perform many operations in parallel, potentially reducing the total laser power necessary to carry out QIP tasks. The overall setup necessary for implementing transport gates is simpler than for gates executed on stationary ions. We also suggest a transport-based two-qubit gate scheme utilizing microfabricated permanent magnets that can be executed without laser light.

We have measured motional heating rates of trapped atomic ions, a factor that can influence multi-ion quantum logic gate fidelities. Two simplified techniques were developed for this purpose: one relies on Raman sideband detection implemented with a single laser source, while the second is even simpler and is based on time-resolved fluorescence detection during Doppler recooling. We applied these methods to determine heating rates in a microfrabricated surface-electrode trap made of gold on fused quartz, which traps ions 40 microns above its surface. Heating rates obtained from the two techniques were found to be in reasonable agreement. In addition, the trap gives rise to a heating rate of 300 plus or minus 30 per second for a motional frequency of 5.25 MHz, substantially below the trend observed in other traps.

We investigate the temporal dynamics of Doppler cooling of an initially hot single trapped atom in the weak binding regime using a semiclassical approach. We develop an analytical model for the simplest case of a single vibrational mode for a harmonic trap, and show how this model allows us to estimate the initial energy of the trapped particle by observing the fluorescence rate during the cooling process. The experimental implementation of this temperature measurement provides a way to measure atom heating rates by observing the temperature rise in the absence of cooling. This method is technically relatively simple compared to conventional sideband detection methods, and the two methods are in reasonable agreement. We also discuss the effects of RF micromotion, relevant for a trapped atomic ion, and the effect of coupling between the vibrational modes on the cooling dynamics.

A key requirement for scalable quantum computing is that elementary quantum gates can be implemented with sufficiently low error. One method for determining the error behavior of a gate implementation is to perform process tomography. However, standard process tomography is limited by errors in state preparation, measurement and one-qubit gates. It suffers from inefficient scaling with number of qubits and does not detect adverse error-compounding when gates are composed in long sequences. An additional problem is due to the fact that desirable error probabilities for scalable quantum computing are of the order of 0.0001 or lower. Experimentally proving such low errors is challenging. We describe a randomized benchmarking method that yields estimates of the computationally relevant errors without relying on accurate state preparation and measurement. Since it involves long sequences of randomly chosen gates, it also verifies that error behavior is stable when used in long computations. We implemented randomized benchmarking on trapped atomic ion qubits, establishing a one-qubit error probability per randomized pi/2 pulse of 0.00482(17) in a particular experiment. We expect this error probability to be readily improved with straightforward technical modifications.

We analyze the error in trapped-ion, hyperfine qubit, quantum gates due to spontaneous scattering of photons from the gate laser beams. We investigate single-qubit rotations that are based on stimulated Raman transitions and two-qubit entangling phase-gates that are based on spin-dependent optical dipole forces. This error is compared between different ion species currently being investigated as possible quantum information carriers. For both gate types we show that with realistic laser powers the scattering error can be reduced to below current estimates of the fault-tolerance error threshold.

It was recently proposed to use small groups of trapped ions as qubit carriers in miniaturized electrode arrays that comprise a large number of individual trapping zones, between which ions could be moved. This approach might be scalable for quantum information processing with a large numbers of qubits. Processing of quantum information is achieved by transporting ions to and from separate memory and qubit manipulation zones in between quantum logic operations. The transport of ion groups in this scheme plays a major role and requires precise experimental control and fast transport. In this paper we introduce a theoretical framework to study ion transport in external potentials that might be created by typical miniaturized Paul trap electrode arrays. In particular we discuss the relationship between classical and quantum descriptions of the transport and study the energy transfer to the oscillatory motion during near-adiabatic transport. Based on our findings we suggest a numerical method to find electrode potentials as a function of time to optimize the local potential an ion experiences during transport. We demonstrate this method for one specific electrode geometry that should closely represent the situation encountered in realistic trap arrays.

The prospect of building a quantum information processor underlies many recent advances ion trap fabrication techniques. Potentially, a quantum computer could be constructed from a large array of interconnected ion traps. We report on a micrometer-scale ion trap, fabricated from bulk silicon using micro-electromechanical systems (MEMS) techniques. The trap geometry is relatively simple in that the electrodes lie in a single plane beneath the ions. In such a trap we confine laser-cooled 24Mg+ ions approximately 40 microns above the surface. The fabrication technique and planar electrode geometry together make this approach amenable to scaling up to large trap arrays. In addition we observe that little laser cooling light is scattered by the electrodes.

We demonstrate confinement of individual atomic ions in a radio-frequency Paul trap with a novel geometry where the electrodes are located in a single plane and the ions confined above this plane. This device is realized with a relatively simple fabrication procedure and has important implications for quantum state manipulation and quantum information processing using large numbers of ions. We confine laser-cooled Mg-24 ions approximately 40 micrometer above planar gold electrodes. We measure the ions' motional frequencies and compare them to simulations. From measurements of the escape time of ions from the trap, we also determine a heating rate of approximately five motional quanta per millisecond for a trap frequency of 5.3 MHz.

We briefly discuss recent experiments on quantum information processing using trapped ions at NIST. A central theme of this work has been to increase our capabilities in terms of quantum computing protocols, but we have also applied the same concepts to improved metrology, particularly in the area of frequency standards and atomic clocks. Such work may eventually shed light on more fundamental issues, such as the quantum measurement problem.

The coherence of a hyperfine-state superposition of a trapped $^{9}$Be$^+$ ion in the presence of off-resonant light is experimentally studied. It is shown that Rayleigh elastic scattering of photons that does not change state populations also does not affect coherence. Coherence times exceeding the average scattering time of 19 photons are observed. This result implies that, with sufficient control over its parameters, laser light can be used to manipulate hyperfine-state superpositions with very little decoherence.

We investigate a surface-mounted electrode geometry for miniature linear radio frequency Paul ion traps. The electrodes reside in a single plane on a substrate, and the pseudopotential minimum of the trap is located above the substrate at a distance on order of the electrodes' lateral extent or separation. This architecture provides the possibility to apply standard microfabrication principles to the construction of multiplexed ion traps, which may be of particular importance in light of recent proposals for large-scale quantum computation based on individual trapped ions.

We demonstrate the cooling of a two species ion crystal consisting of one $^9Be^+$ and one $^{24}Mg^+$ ion. Since the respective cooling transitions of these two species are separated by more than 30 nm, laser manipulation of one ion has negligible effect on the other even when the ions are not individually addressed. As such this is a useful system for re-initializing the motional state in an ion trap quantum computer without affecting the qubit information. Additionally, we have found that the mass difference between ions enables a novel method for detecting and subsequently eliminating the effects of radio frequency (RF) micro-motion.

Experiments directed towards the development of a quantum computer based on trapped atomic ions are described briefly. We discuss the implementation of single qubit operations and gates between qubits. A geometric phase gate between two ion qubits is described. Limitations of the trapped-ion method such as those caused by Stark shifts and spontaneous emission are addressed. Finally, we describe a strategy to realize a large-scale device.

We show how an experimentally realized set of operations on a single trapped ion is sufficient to simulate a wide class of Hamiltonians of a spin-1/2 particle in an external potential. This system is also able to simulate other physical dynamics. As a demonstration, we simulate the action of an $n$-th order nonlinear optical beamsplitter. Two of these beamsplitters can be used to construct an interferometer sensitive to phase shifts in one of the interferometer beam paths. The sensitivity in determining these phase shifts increases linearly with $n$, and the simulation demonstrates that the use of nonlinear beamsplitters ($n$=2,3) enhances this sensitivity compared to the standard quantum limit imposed by a linear beamsplitter ($n$=1).

Using a single, harmonically trapped $^9$Be$^+$ ion, we experimentally demonstrate a technique for generation of arbitrary states of a two-level particle confined by a harmonic potential. Rather than engineering a single Hamiltonian that evolves the system to a desired final sate, we implement a technique that applies a sequence of simple operations to synthesize the state.

We have investigated ion dynamics associated with a dual linear ion trap where ions can be stored in and moved between two distinct locations. Such a trap is a building block for a system to engineer arbitrary quantum states of ion ensembles. Specifically, this trap is the unit cell in a strategy for scalable quantum computing using a series of interconnected ion traps. We have transferred an ion between trap locations 1.2 mm apart in 50 $μ$s with near unit efficiency ($> 10^{6}$ consecutive transfers) and negligible motional heating, while maintaining internal-state coherence. In addition, we have separated two ions held in a common trap into two distinct traps.

The quadrupole S$_{1/2}$ -- D$_{5/2}$ optical transition of a single trapped Ca$^+$ ion, well suited for encoding a quantum bit of information, is coherently coupled to the standing wave field of a high finesse cavity. The coupling is verified by observing the ion's response to both spatial and temporal variations of the intracavity field. We also achieve deterministic coupling of the cavity mode to the ion's vibrational state by selectively exciting vibrational state-changing transitions and by controlling the position of the ion in the standing wave field with nanometer-precision.

A novel method of ground state laser cooling of trapped atoms utilizes the absorption profile of a three (or multi-) level system which is tailored by a quantum interference. With cooling rates comparable to conventional sideband cooling, lower final temperatures may be achieved. The method was experimentally implemented to cool a single Ca$^+$ ion to its vibrational ground state. Since a broad band of vibrational frequencies can be cooled simultaneously, the technique will be particularly useful for the cooling of larger ion strings, thereby being of great practical importance for initializing a quantum register based on trapped ions. We also discuss its application to different level schemes and for ground state cooling of neutral atoms trapped by a far detuned standing wave laser field.

Ground state cooling and coherent manipulation of ions in an rf-(Paul) trap is the prerequisite for quantum information experiments with trapped ions. With resolved sideband cooling on the optical S1/2 - D5/2 quadrupole transition we have cooled one and two 40Ca+ ions to the ground state of vibration with up to 99.9% probability. With a novel cooling scheme utilizing electromagnetically induced transparency on the S1/2 - P1/2 manifold we have achieved simultaneous ground state cooling of two motional sidebands 1.7 MHz apart. Starting from the motional ground state we have demonstrated coherent quantum state manipulation on the S1/2 - D5/2 quadrupole transition at 729 nm. Up to 30 Rabi oscillations within 1.4 ms have been observed in the motional ground state and in the n=1 Fock state. In the linear quadrupole rf-trap with 700 kHz trap frequency along the symmetry axis (2 MHz in radial direction) the minimum ion spacing is more than 5 micron for up to 4 ions. We are able to cool two ions to the ground state in the trap and individually address the ions with laser pulses through a special optical addressing channel.

Ground state laser cooling of a single trapped ion is achieved using a technique which tailors the absorption profile for the cooling laser by exploiting electromagnetically induced transparency in the Zeeman structure of a dipole transition. This new method is robust, easy to implement and proves particularly useful for cooling several motional degrees of freedom simultaneously, which is of great practical importance for the implementation of quantum logic schemes with trapped ions.

We have cooled a two-ion-crystal to the ground state of its collective modes of motion. Laser cooling, more specific resolved sideband cooling is performed sympathetically by illuminating only one of the two $^{40}$Ca$^+$ ions in the crystal. The heating rates of the motional modes of the crystal in our linear trap have been measured, and we found them considerably smaller than those previously reported by Q. Turchette {\em et. al.} Phys. Rev. A 61, 063418 (2000) in the case of trapped $^9$Be$^+$ ions. After the ground state is prepared, coherent quantum state manipulation of the atomic population can be performed. Within the coherence time, up to 12 Rabi oscillations are observed, showing that many coherent manipulations can be achieved. Coherent excitation of each ion individually and ground state cooling are important tools for the realization of quantum information processing in ion traps.

We investigate single ions of $^{40}Ca^+$ in Paul traps for quantum information processing. Superpositions of the S$_{1/2}$ electronic ground state and the metastable D$_{5/2}$ state are used to implement a qubit. Laser light on the S$_{1/2} \leftrightarrow$ D$_{5/2}$ transition is used for the manipulation of the ion's quantum state. We apply sideband cooling to the ion and reach the ground state of vibration with up to 99.9% probability. Starting from this Fock state $|n=0>$, we demonstrate coherent quantum state manipulation. A large number of Rabi oscillations and a ms-coherence time is observed. Motional heating is measured to be as low as one vibrational quantum in 190 ms. We also report on ground state cooling of two ions.

We investigate theoretically the speed limit of quantum gate operations for ion trap quantum information processors. The proposed methods use laser pulses for quantum gates which entangle the electronic and vibrational degrees of freedom of the trapped ions. Two of these methods are studied in detail and for both of them the speed is limited by a combination of the recoil frequency of the relevant electronic transition, and the vibrational frequency in the trap. We have experimentally studied the gate operations below and above this speed limit. In the latter case, the fidelity is reduced, in agreement with our theoretical findings. // Changes: a) error in equ. 24 and table III repaired b) reference Jonathan et al, quant-ph/ 0002092, added (proposes fast quantum gates using the AC-Stark effect)

We have investigated motional heating of laser-cooled 9Be+ ions held in radio-frequency (Paul) traps. We have measured heating rates in a variety of traps with different geometries, electrode materials, and characteristic sizes. The results show that heating is due to electric-field noise from the trap electrodes which exerts a stochastic fluctuating force on the ion. The scaling of the heating rate with trap size is much stronger than that expected from a spatially uniform noise source on the electrodes (such as Johnson noise from external circuits), indicating that a microscopic uncorrelated noise source on the electrodes (such as fluctuating patch-potential fields) is a more likely candidate for the source of heating.

A single Ca+ ion in a Paul trap has been cooled to the ground state of vibration with up to 99.9% probability. Starting from this Fock state |n=0> we have demonstrated coherent quantum state manipulation on an optical transition. Up to 30 Rabi oscillations within 1.4 ms have been observed. We find a similar number of Rabi oscillations after preparation of the ion in the |n=1> Fock state. The coherence of optical state manipulation is only limited by laser and ambient magnetic field fluctuations. Motional heating has been measured to be as low as one vibrational quantum in 190 ms.

A new scheme for the individual addressing of ions in a trap is described that does not rely on light beams tightly focused onto only one ion. The scheme utilizes ion micromotion that may be induced in a linear trap by dc offset potentials. Thus coupling an individual ion to the globally applied light fields corresponds to a mere switching of voltages on a suitable set of compensation electrodes. The proposed scheme is especially suitable for miniaturized rf (Paul) traps with typical dimensions of about 20-40 microns.

We have prepared the internal states of two trapped ions in both the Bell-like singlet and triplet entangled states. In contrast to all other experiments with entangled states of either massive particles or photons, we do this in a deterministic fashion, producing entangled states on demand without selection. The deterministic production of entangled states is a crucial prerequisite for large-scale quantum computation.

We report preparation in the ground state of collective modes of motion of two trapped 9Be+ ions. This is a crucial step towards realizing quantum logic gates which can entangle the ions' internal electronic states. We find that heating of the modes of relative ion motion is substantially suppressed relative to that of the center-of-mass modes, suggesting the importance of these modes in future experiments.

Methods for, and limitations to, the generation of entangled states of trapped atomic ions are examined. As much as possible, state manipulations are described in terms of quantum logic operations since the conditional dynamics implicit in quantum logic is central to the creation of entanglement. Keeping with current interest, some experimental issues in the proposal for trapped-ion quantum computation by I. Cirac and P. Zoller (University of Innsbruck) are discussed. Several possible decoherence mechanisms are examined and what may be the more important of these are identified. Some potential applications for entangled states of trapped-ions which lie outside the immediate realm of quantum computation are also discussed.

A single laser-cooled and trapped 9Be+ ion is used to investigate methods of coherent quantum-state synthesis and quantum logic. We create and characterize nonclassical states of motion including "Schroedinger-cat" states. A fundamental quantum logic gate is realized which uses two states of the quantized ion motion and two ion internal states as qubits. We explore some of the applications for, and problems in realizing, quantum computation based on multiple trapped ions.

Experiments are described in which a single, harmonically bound, beryllium ion in a Paul trap is put into Fock, thermal, coherent, squeezed, and Schroedinger cat states. Experimental determinations of the density matrix and the Wigner function are described. A simple calculation of the decoherence of a superposition of coherent states due to an external electric field is given.

We describe a simplified scheme for quantum logic with a collection of laser-cooled trapped atomic ions. Building on the scheme of Cirac and Zoller, we show how the fundamental controlled-NOT gate between a collective mode of ion motion and the internal states of a single ion can be reduced to a single laser pulse, and the need for a third auxiliary internal electronic state can be eliminated.