W. M. Itano

We have measured motional heating rates of trapped atomic ions, a factor that can influence multi-ion quantum logic gate fidelities. Two simplified techniques were developed for this purpose: one relies on Raman sideband detection implemented with a single laser source, while the second is even simpler and is based on time-resolved fluorescence detection during Doppler recooling. We applied these methods to determine heating rates in a microfrabricated surface-electrode trap made of gold on fused quartz, which traps ions 40 microns above its surface. Heating rates obtained from the two techniques were found to be in reasonable agreement. In addition, the trap gives rise to a heating rate of 300 plus or minus 30 per second for a motional frequency of 5.25 MHz, substantially below the trend observed in other traps.

We investigate the temporal dynamics of Doppler cooling of an initially hot single trapped atom in the weak binding regime using a semiclassical approach. We develop an analytical model for the simplest case of a single vibrational mode for a harmonic trap, and show how this model allows us to estimate the initial energy of the trapped particle by observing the fluorescence rate during the cooling process. The experimental implementation of this temperature measurement provides a way to measure atom heating rates by observing the temperature rise in the absence of cooling. This method is technically relatively simple compared to conventional sideband detection methods, and the two methods are in reasonable agreement. We also discuss the effects of RF micromotion, relevant for a trapped atomic ion, and the effect of coupling between the vibrational modes on the cooling dynamics.

We report for the first time, laser spectroscopy of the 1S0 - 3P0 clock transition in 27Al+. A single aluminum ion and a single beryllium ion are simultaneously confined in a linear Paul trap, coupled by their mutual Coulomb repulsion. This coupling allows the beryllium ion to sympathetically cool the aluminum ion, and also enables transfer of the aluminum's electronic state to the beryllium's hyperfine state, which can be measured with high fidelity. These techniques are applied to a measurement of the clock transition frequency, ν= 1 121 015 393 207 851(8) Hz. They are also used to measure the lifetime of the metastable clock state, τ= 20.6 +/- 1.4 s, the ground state 1S0 g-factor, g_S = -0.00079248(14), and the excited state 3P0 g-factor, g_P = -0.00197686(21), in units of the Bohr magneton.

We analyze the error in trapped-ion, hyperfine qubit, quantum gates due to spontaneous scattering of photons from the gate laser beams. We investigate single-qubit rotations that are based on stimulated Raman transitions and two-qubit entangling phase-gates that are based on spin-dependent optical dipole forces. This error is compared between different ion species currently being investigated as possible quantum information carriers. For both gate types we show that with realistic laser powers the scattering error can be reduced to below current estimates of the fault-tolerance error threshold.

We briefly discuss recent experiments on quantum information processing using trapped ions at NIST. A central theme of this work has been to increase our capabilities in terms of quantum computing protocols, but we have also applied the same concepts to improved metrology, particularly in the area of frequency standards and atomic clocks. Such work may eventually shed light on more fundamental issues, such as the quantum measurement problem.

The coherence of a hyperfine-state superposition of a trapped $^{9}$Be$^+$ ion in the presence of off-resonant light is experimentally studied. It is shown that Rayleigh elastic scattering of photons that does not change state populations also does not affect coherence. Coherence times exceeding the average scattering time of 19 photons are observed. This result implies that, with sufficient control over its parameters, laser light can be used to manipulate hyperfine-state superpositions with very little decoherence.

We demonstrate the cooling of a two species ion crystal consisting of one $^9Be^+$ and one $^{24}Mg^+$ ion. Since the respective cooling transitions of these two species are separated by more than 30 nm, laser manipulation of one ion has negligible effect on the other even when the ions are not individually addressed. As such this is a useful system for re-initializing the motional state in an ion trap quantum computer without affecting the qubit information. Additionally, we have found that the mass difference between ions enables a novel method for detecting and subsequently eliminating the effects of radio frequency (RF) micro-motion.

Experiments directed towards the development of a quantum computer based on trapped atomic ions are described briefly. We discuss the implementation of single qubit operations and gates between qubits. A geometric phase gate between two ion qubits is described. Limitations of the trapped-ion method such as those caused by Stark shifts and spontaneous emission are addressed. Finally, we describe a strategy to realize a large-scale device.

We show how an experimentally realized set of operations on a single trapped ion is sufficient to simulate a wide class of Hamiltonians of a spin-1/2 particle in an external potential. This system is also able to simulate other physical dynamics. As a demonstration, we simulate the action of an $n$-th order nonlinear optical beamsplitter. Two of these beamsplitters can be used to construct an interferometer sensitive to phase shifts in one of the interferometer beam paths. The sensitivity in determining these phase shifts increases linearly with $n$, and the simulation demonstrates that the use of nonlinear beamsplitters ($n$=2,3) enhances this sensitivity compared to the standard quantum limit imposed by a linear beamsplitter ($n$=1).

Using a single, harmonically trapped $^9$Be$^+$ ion, we experimentally demonstrate a technique for generation of arbitrary states of a two-level particle confined by a harmonic potential. Rather than engineering a single Hamiltonian that evolves the system to a desired final sate, we implement a technique that applies a sequence of simple operations to synthesize the state.

We have investigated ion dynamics associated with a dual linear ion trap where ions can be stored in and moved between two distinct locations. Such a trap is a building block for a system to engineer arbitrary quantum states of ion ensembles. Specifically, this trap is the unit cell in a strategy for scalable quantum computing using a series of interconnected ion traps. We have transferred an ion between trap locations 1.2 mm apart in 50 $μ$s with near unit efficiency ($> 10^{6}$ consecutive transfers) and negligible motional heating, while maintaining internal-state coherence. In addition, we have separated two ions held in a common trap into two distinct traps.

We review recent experiments on entanglement, Bell's inequality, and decoherence-free subspaces in a quantum register of trapped \be ions. We have demonstrated entanglement of up to four ions using the technique of Mølmer and Sørensen. This method produces the state |down down> + |up up> for two ions and the state |down down down down> + |up up up up> for four ions. We generate the entanglement deterministically in each shot of the experiment. Measurements on the two-ion entangled state violates Bell's inequality at the $8σ$ level. Because of the high detector efficiency of our apparatus, this experiment closes the detector loophole for Bell's inequality measurements for the first time. This measurement is also the first violation of Bell's inequality by massive particles that does not implicitly assume results from quantum mechanics. Finally, we have demonstrated reversible encoding of an arbitrary qubit, originally contained in one ion, into a decoherence-free subspace (DFS) of two ions. The DFS-encoded qubit resists applied collective dephasing noise and retains coherence under ambient conditions 3.6 times longer than does an unencoded qubit. The encoding method, which uses single-ion gates and the two-ion entangling gate, demonstrates all the elements required for two-qubit universal quantum logic.

Frequency shifts of the ^199Hg^+ 5d^10 6s ^2S_1/2 (F=0, M_F=0) to 5d^9 6s^2 ^2D_5/2 (F=2, M_F=0) electric-quadrupole transition at 282 nm due to external fields are calculated, based on a combination of measured atomic parameters and ab initio calculations. This transition is under investigation as an optical frequency standard. The perturbations calculated are the quadratic Zeeman shift, the scalar and tensor quadratic Stark shifts, and the interaction between an external electric field gradient and the atomic quadrupole moment. The quadrupole shift is likely to be the most difficult to evaluate in a frequency standard and may have a magnitude of about 1 Hz for a single ion in a Paul trap.

Using a laser that is frequency-locked to a Fabry-Perot etalon of high finesse and stability, we probe the 5d10 6s 2S_1/2 (F=0) - 5d9 6s 2D_5/2 (F=2) Delta-m_F = 0 electric-quadrupole transition of a single laser-cooled 199Hg+ ion stored in a cryogenic radio-frequency ion trap. We observe Fourier-transform limited linewidths as narrow as 6.7 Hz at 282 nm (1.06 X 10^15 Hz), yielding a line Q = 1.6 X 10^14. We perform a preliminary measurement of the 5d9 6s2 2D_5/2 electric-quadrupole shift due to interaction with the static fields of the trap, and discuss the implications for future trapped-ion optical frequency standards.

We have investigated motional heating of laser-cooled 9Be+ ions held in radio-frequency (Paul) traps. We have measured heating rates in a variety of traps with different geometries, electrode materials, and characteristic sizes. The results show that heating is due to electric-field noise from the trap electrodes which exerts a stochastic fluctuating force on the ion. The scaling of the heating rate with trap size is much stronger than that expected from a spatially uniform noise source on the electrodes (such as Johnson noise from external circuits), indicating that a microscopic uncorrelated noise source on the electrodes (such as fluctuating patch-potential fields) is a more likely candidate for the source of heating.

One limit to the fidelity of quantum logic operations on trapped ions arises from heating of the ions' collective modes of motion. Sympathetic cooling of the ions during the logic operations may eliminate this source of errors. We discuss benefits and drawbacks of this proposal, and describe possible experimental implementations. We also present an overview of trapped-ion dynamics in this scheme.

We summarize efforts at NIST to implement quantum computation using trapped ions, based on a scheme proposed by J.I. Cirac and P. Zoller (Innsbruck University). The use of quantum logic to create entangled states, which can maximize the quantum-limited signal-to-noise ratio in spectroscopy, is discussed.

We have prepared the internal states of two trapped ions in both the Bell-like singlet and triplet entangled states. In contrast to all other experiments with entangled states of either massive particles or photons, we do this in a deterministic fashion, producing entangled states on demand without selection. The deterministic production of entangled states is a crucial prerequisite for large-scale quantum computation.

We report preparation in the ground state of collective modes of motion of two trapped 9Be+ ions. This is a crucial step towards realizing quantum logic gates which can entangle the ions' internal electronic states. We find that heating of the modes of relative ion motion is substantially suppressed relative to that of the center-of-mass modes, suggesting the importance of these modes in future experiments.

Methods for, and limitations to, the generation of entangled states of trapped atomic ions are examined. As much as possible, state manipulations are described in terms of quantum logic operations since the conditional dynamics implicit in quantum logic is central to the creation of entanglement. Keeping with current interest, some experimental issues in the proposal for trapped-ion quantum computation by I. Cirac and P. Zoller (University of Innsbruck) are discussed. Several possible decoherence mechanisms are examined and what may be the more important of these are identified. Some potential applications for entangled states of trapped-ions which lie outside the immediate realm of quantum computation are also discussed.

A single laser-cooled and trapped 9Be+ ion is used to investigate methods of coherent quantum-state synthesis and quantum logic. We create and characterize nonclassical states of motion including "Schroedinger-cat" states. A fundamental quantum logic gate is realized which uses two states of the quantized ion motion and two ion internal states as qubits. We explore some of the applications for, and problems in realizing, quantum computation based on multiple trapped ions.

Experiments are described in which a single, harmonically bound, beryllium ion in a Paul trap is put into Fock, thermal, coherent, squeezed, and Schroedinger cat states. Experimental determinations of the density matrix and the Wigner function are described. A simple calculation of the decoherence of a superposition of coherent states due to an external electric field is given.

We describe a simplified scheme for quantum logic with a collection of laser-cooled trapped atomic ions. Building on the scheme of Cirac and Zoller, we show how the fundamental controlled-NOT gate between a collective mode of ion motion and the internal states of a single ion can be reduced to a single laser pulse, and the need for a third auxiliary internal electronic state can be eliminated.