Jie Zhang

The quantum Mpemba effect (ME) in Markovian systems is conventionally explained by a smaller overlap between the initial state and the slowest decay mode (SDM). Such state, initially farther away from equilibrium or steady state, relaxes faster than closer ones, resulting to a crossing of their trajectories. This picture, by neglecting the transient dynamics, holds in the long-time limit. Here we experimentally observe multiple trajectory crossings (multi-ME) in the relaxation dynamics of a trapped ion. Such novel dynamics takes place in a unusual scenario where the initial state instead has a larger overlap with the SDM. We develop a theoretical framework based on relaxation speed to understand the multi-ME. We show that the initial relaxation speed is governed by the fastest decay mode, which together with the SDM overlap gives a phase diagram that reveals both the occurrence and the types of quantum ME observed in our experiment. Our study goes beyond the simple picture based on the long-time limit, tracks continuously the quantum ME dynamics, and establishes a comprehensive framework to describe the transient quantum relaxation.

In trapped ion system, accurate thermometry of ion is crucial for evaluating the system state and precisely performing quantum operations. However, when the motional state of a single ion is far away from the ground state, the spatial dimension of the phonon state sharply increases, making it difficult to realize accurate and mode-resolved thermometry with existing methods. In this work, we apply deep learning for the first time to the thermometry of trapped ion, providing an efficient and mode-resolved method for accurately estimating large mean phonon numbers. Our trained neural network model can be directly applied to other experimental setups without retraining or post-processing, as long as the related parameters are covered by the model's effective range, and it can also be conveniently extended to other parameter ranges. We have conducted experimental verification based on our surface trap, of which the result has shown the accuracy and efficiency of the method for thermometry of single ion under large mean phonon number, and its mode resolution characteristic can make it better applied to the characterization of system parameters, such as evaluating cooling effectiveness, analyzing surface trap noise.

An ancient and counterintuitive phenomenon know as the Mpemba effect (water can cool faster when initially heated up) showcases the critical role of initial conditions in relaxation processes. How to realize and utilize this effect for speeding up relaxation is an important but challenging task in purely quantum system till now. Here, we report the first experiment, as far as we know,about the strong Mpemba effect in a single trapped ion system in which an exponentially expedited relaxation in time is observed by preparing an optimal initial state with no excitation of the slowest decaying mode. Also, we find that the condition of realizing such effect coincides with the Liouvillian exceptional point, featuring the coalescence of both the eigenvalues and the eigenmodes of the system. Our work provides an efficient strategy to exponentially accelerate relaxations of quantum system to their stationary state, and suggests a link unexplored yet between the Mpemba effect and the non-Hermitian physics. It could open up the door to engineer a wide range of dissipative quantum systems by utilizing the anomalous Mpemba effect, for applications in quantum simulation and quantum information processing.

We investigate speeding up of relaxation of Markovian open quantum systems with the Liouvillian exceptional point (LEP), where the slowest decay mode degenerate with a faster decay mode. The degeneracy significantly increases the gap of the Liouvillian operator, which determines the timescale of such systems in converging to stationarity, and hence accelerates the relaxation process. We explore an experimentally relevant three level atomic system, whose eigenmatrices and eigenspectra are obtained completely analytically. This allows us to gain insights in the LEP and examine respective dynamics with details. We illustrate that the gap can be further widened through Floquet engineering, which further accelerates the relaxation process. Finally, we extend this approach to analyze laser cooling of trapped ions, where vibrations (phonons) couple to the electronic states. An optimal cooling condition is obtained analytically, which agrees with both existing experiments and numerical simulations. Our study provides analytical insights in understanding LEP, as well as in controlling and optimizing dissipative dynamics of atoms and trapped ions.

Quantum correlations, both spatial and temporal, are the central pillars of quantum mechanics. Over the last two decades, a big breakthrough in quantum physics is its complex extension to the non-Hermitian realm, and dizzying varieties of novel phenomena and applications beyond the Hermitian framework have been uncovered. However, unique features of non-Hermitian quantum correlations, especially in the time domain, still remain to be explored. Here, for the first time, we experimentally achieve this goal by using a parity-time (PT)-symmetric trapped-ion system. The upper limit of temporal quantum correlations, known as the algebraic bound, which has so far not been achieved in the standard measurement scenario, is reached here by approaching the exceptional point (EP), thus showing the unexpected ability of EPs in tuning temporal quantum correlation effects. Our study, unveiling the fundamental interplay of non-Hermiticity, nonlinearity, and temporal quantum correlations, provides the first step towards exploring and utilizing various non-Hermitian temporal quantum effects by operating a wide range of EP devices, which are important for both fundamental studies and applications of quantum EP systems.

The accurate characterization of the spatial potential generated by a planar electrode in a surface-type Paul trap is of great interest. To achieve this, we employ a simple yet highly precise parametric expression to describe the spatial field of a rectangular-shaped electrode. Based on this, an optimization method is introduced to precisely characterize the axial electric field intensity created by the powered electrode and the stray field. In contrast to existing methods, various types of experimental data, such as the equilibrium position of ions in a linear string, equilibrium positions of single trapped ions and trap frequencies, are utilized for potential estimation in order to mitigate systematic errors. This approach offers significant flexibility in voltage settings for data collection, making it particularly well-suited for surface electrode traps where ion probe trapping height may vary with casual voltage settings. In our demonstration, we successfully minimized the discrepancy between experimental observations and model predictions to an impressive extent. The relative errors of secular frequencies were suppressed within $\pm$ 0.5$\%$, and the positional error of ions was limited to less than 1.2 $μ$m, all surpassing those achieved by existing methodologies.

An array of ions in a linear radio-frequency (RF) Paul trap is a good candidate for investigating structural phase transitions, such as the linear-to-zigzag (LZ) transition, due to the convenient control provided by modification of the trap confinement strength. In such studies, the trap secular frequencies are a key factor that limits the stability of the critical point (CP). In this paper, we implement secular-frequency stabilization, including active feedback stabilization of the RF voltage near the trap electrodes, and achieve a stability of better than 5~ppm over 200~s for both transverse and axial potentials. To evaluate the combined long-term stability of the trap potential in both directions, we measure the zigzag (ZZ) mode frequency near the CP, where the effect of instability in both trap directions is substantially amplified. The short-term noise within a limited spectral window is also suppressed by this scheme, as inferred from decoherence rates of the ZZ mode measured at different frequencies with Ramsey fringes. We also identify that the limitation of the secular frequency stability is mainly from the imperfect temperature insensitivity of voltage dividers and RF detectors, and as a result improvement of lab temperature stability is of great help for stabilizing the trap frequency.

Leggett-Garg inequality (LGI) studies the temporal correlation in the evolution of physical systems. Classical systems obey the LGI but quantum systems may violate it. The extent of the violation depends on the dimension of the quantum system and the state update rule. In this work, we experimentally test the LGI in a three-level trapped-ion system under the model of a large spin precessing in a magnetic field. The Von Neumann and Lüders state update rules are employed in our system for direct comparative analysis. The maximum observed value of Leggett-Garg correlator under the Von Neumann state update rule is $K_3 = 1.739 \pm 0.014$, which demonstrates a violation of the Lüders bound by 17 standard deviations and is by far the most significant violation in natural three-level systems.

We theoretically propose and experimentally demonstrate a parallel-electromagnetically-induced transparency (parallel-EIT) cooling technique for ion crystals in the Paul trap. It has less stringent requirements on the cooling resonance condition than the standard electromagnetically-induced transparency (EIT) cooling, thus allowing, in principle, to simultaneously cool the motional mode spectrum with an arbitrary range. A proof-of-principle validation for this cooling scheme is experimentally demonstrated with up to 4 trapped 40Ca+ ions. We observe simultaneous near-ground-state cooling for all motional modes with best average phonon number about 0.2. By tuning the trap frequency in a large range to imitate a broadband motional mode spectrum, we can still reach almost the same cooling limit for all the modes while standard EIT cooling shows limited cooling range. Our method has a simple experimental configuration, requiring only appropriate modulation of the probe beam of standard EIT cooling, and can be applied to various types of ions (e.g., 171Yb+, 40Ca+). This cooling scheme provides a powerful tool for the initialization of the trapped-ion quantum computers and simulators.

Cooling down a trapped ion into its motional ground state is a central step for trapped ions based quantum information processing. State of the art cooling schemes often work under a set of optimal cooling conditions derived analytically using a perturbative approach, in which the sideband coupling is assumed to be the weakest of all the relevant transitions. As a result the cooling rate is severely limited. Here we propose to use quantum control technique powered with automatic differentiation to speed up the classical cooling schemes. We demonstrate the efficacy of our approach by applying it to find the optimal cooling conditions for classical sideband cooling and electromagnetically induced transparency cooling schemes, which are in general beyond the weak sideband coupling regime. Based on those numerically found optimal cooling conditions, we show that faster cooling can be achieved while at the same time a low average phonon occupation can be retained.

Parity-time($\mathcal{PT}$)-symmetric systems, featuring real eigenvalues despite its non-Hermitian nature, have been widely utilized to achieve exotic functionalities in the classical realm, such as loss-induced transparency or lasing revival. By approaching the exceptional point (EP) or the coalescences of both eigenvalues and eigenstates, unconventional effects are also expected to emerge in pure quantum $\mathcal{PT}$ devices. Here, we report experimental evidences of spontaneous $\mathcal{PT}$ symmetry breaking in a single cold $^{40}\mathrm{Ca}^{+}$ ion, and more importantly, a counterintuitive effect of perfect quantum coherence occurring at the EP. Excellent agreement between experimental results and theoretical predictions is identified. In view of the versatile role of cold ions in building quantum memory or processor, our experiment provides a new platform to explore and utilize pure quantum EP effects, with diverse applications in quantum engineering of trapped ions.

Quantum measurement remains a puzzle through its stormy history from the birth of quantum mechanics to state-of-the-art quantum technologies. Two complementary measurement schemes have been widely investigated in a variety of quantum systems: von Neumann's projective 'strong' measurement and Aharonov's weak measurement. Here, we report the observation of a weak-to-strong measurement transition in a single trapped $40Ca^+$ ion system. The transition is realized by tuning the interaction strength between the ion's internal electronic state and its vibrational motion, which play the roles of the measured system and the measuring pointer, respectively. By pre- and post-selecting the internal state, a pointer state composed of two of the ion's motional wavepackets is obtained, and its central-position shift, which corresponds to the measurement outcome, demonstrates the transition from the weak-value asymptotes to the expected-value asymptotes. Quantitatively, the weak-to-strong measurement transition is characterized by a universal transition factor $e^{-Γ^2}$, where $Γ$ is a dimensionless parameter related to the system-apparatus coupling. This transition, which continuously connects weak measurements and strong measurements, may open new experimental possibilities to test quantum foundations and prompt us to re-examine and improve the measurement schemes of related quantum technologies.

In this paper, we explore the possibilities of realizing weak value amplification (WVA) using purely atomic degrees of freedom. Our scheme identifies the internal electronic states and external motional states of a single trapped $^{40}$Ca$^+$ ion as the system degree and pointer degree respectively, and their controllable weak coupling is provided by a bichromatic light field. In our experimental demonstration, by performing appropriate postselection on the internal states, a position displacement of 4 angstroms (in phase space) of the trapped ion is amplified to 10 nanometers. The sensitivity of the amplification effect to the relative phase of the quantum state is also demonstrated. The high operational flexibility of this procedure allows fully exploration of the peculiarities of WVA.