Ion Trap Quantum Computing

We present the design, fabrication, and characterization of a monolithic, segmented, three-dimensional linear Paul ion trap for quantum science applications. The trap is fabricated from a single fused-silica block using selective laser-induced etching (SLE) and is subsequently metallized, forming electrodes isolated by self-shadowing trench structures without the need for layer alignment or external shadow masks. The segmented electrodes allow for shaping of the axial potential, enabling the creation of anharmonic potential wells, such as those required for equidistant ion strings. In addition, they enable shuttling and splitting of ion chains. We discuss key design choices and SLE-imposed constraints on achievable feature sizes, and evaluate electron-beam evaporation and magnetron sputtering as metallization approaches. Across two independent experimental setups, we demonstrate stable trapping and control of linear chains of up to 33 $^{40}$Ca$^+$ ions, including approximately equally spaced configurations. The measured secular frequencies in both traps agree with boundary-element simulations at the percent level, with residual deviations attributed to stray electric fields in the presence of anharmonic axial potentials, rather than fabrication imperfections. We measure axial micromotion field strengths on the order of 100 V/m along the trap axis, in approximate agreement with simulations. For radial mode frequencies near 2 MHz and an ion-electrode distance of 300 um, we measure heating rates of the order of 10 quanta/s in all but one motional mode, which is elevated by a technical noise source. The presented trap design is thus suitable for a wide range of quantum science applications and demonstrates the viability of SLE for the fabrication of finely segmented, monolithic, three-dimensional ion traps.

We demonstrate a state-dependent Gaussian gate set on the motional modes of trapped $^{40}$Ca$^+$ ions, realized with an optical tweezer. Dynamic control of the tweezer intensity and position enables local displacement, squeezing, phase-space rotation, and beamsplitter operations, constituting a complete gate set. By varying the tweezer position relative to the ion, we show how the strength of each operation is set by the corresponding spatial derivative of the local optical potential. We further demonstrate the inherent dependence of each operation on the ion's internal state and use coherent spin-motion coupling provided by the tweezer to create a motional cat state. Our work establishes optical tweezers as a unified and local resource for continuous-variable quantum control in trapped ion systems.

We directly observe and spatially map an optical analog of the Magnus effect, where intrinsic spin-orbit-like coupling of light generates a spin-dependent transverse displacement of the atom-light interaction profile for a $^{40}$Ca$^+$ ion. Probed on a quadrupole transition using a tightly focused beam, we observe displacements of the maximum in the profile of the effective interaction by several 100 nm originating from intrinsic longitudinal electric field components beyond the paraxial approximation. The tight focus of the beam induces additional transverse polarization gradients, which we characterize through a phase-sensitive measurement and spatial maps for different beam configurations. The results establish the physical basis of polarization-gradient interactions relevant to optical tweezer-based quantum control.

We develop a framework for extracting non-polynomial analytic functions of density matrices in randomized measurement experiments by a method of analytical continuation. A central advantage of this approach, dubbed stabilized analytic continuation (SAC), is its robustness to statistical noise arising from finite repetitions of a quantum experiment, making it well-suited to realistic quantum hardware. As a demonstration, we use SAC to estimate the von Neumann entanglement entropy of a numerically simulated quenched Néel state from Rényi entropies estimated via the randomized measurement protocol. We then apply the method to experimental Rényi data from a trapped-ion quantum simulator, extracting subsystem von Neumann entropies at different evolution times. Finally, we briefly note that the SAC framework is readily generalizable to obtain other nonlinear diagnostics, such as the logarithmic negativity and Rényi relative entropies.

Accurate simulation of dynamical processes in molecules and reactions is among the most challenging problems in quantum chemistry. Quantum computers promise efficient chemical simulation, but the existing quantum algorithms require many logical qubits and gates, placing practical applications beyond existing technology. Here, we carry out the first quantum simulations of chemical dynamics by employing a more hardware-efficient encoding scheme that uses both qubits and bosonic degrees of freedom. Our trapped-ion device accurately simulates the dynamics of non-adiabatic chemical processes, which are among the most difficult problems in computational chemistry because they involve strong coupling between electronic and nuclear motions. We demonstrate the programmability and versatility of our approach by simulating the dynamics of three different molecules as well as open-system dynamics in the condensed phase, all with the same quantum resources. Our approach requires orders of magnitude fewer resources than equivalent qubit-only quantum simulations, demonstrating the potential of using hybrid encoding schemes to accelerate quantum simulations of complex chemical processes, which could have applications in fields ranging from energy conversion and storage to biology and drug design.

Conical intersections are ubiquitous in chemistry and physics, often governing processes such as light harvesting, vision, photocatalysis, and chemical reactivity. They act as funnels between electronic states of molecules, allowing rapid and efficient relaxation during chemical dynamics. In addition, when a reaction path encircles a conical intersection, the molecular wavefunction experiences a geometric phase, which can affect the outcome of the reaction through quantum-mechanical interference. Past experiments have measured indirect signatures of geometric phases in scattering patterns and spectroscopic observables, but there has been no direct observation of the underlying wavepacket interference. Here, we experimentally observe geometric-phase interference in the dynamics of a wavepacket travelling around an engineered conical intersection in a programmable trapped-ion quantum simulator. To achieve this, we develop a technique to reconstruct the two-dimensional wavepacket densities of a trapped ion. Experiments agree with the theoretical model, demonstrating the ability of analog quantum simulators -- such as those realised using trapped ions -- to accurately describe nuclear quantum effects.

Spectroscopy is one of the most accurate probes of the molecular world. However, predicting molecular spectra accurately is computationally difficult because of the presence of entanglement between electronic and nuclear degrees of freedom. Although quantum computers promise to reduce this computational cost, existing quantum approaches rely on combining signals from individual eigenstates, an approach that is difficult to scale because the number of eigenstates grows exponentially with molecule size. Here, we introduce a method for scalable analog quantum simulation of molecular spectroscopy, by performing simulations in the time domain. Our approach can treat more complicated molecular models than previous ones, requires fewer approximations, and can be extended to open quantum systems with minimal overhead. We present a direct mapping of the underlying problem of time-domain simulation of molecular spectra to the degrees of freedom and control fields available in a trapped-ion quantum simulator. We experimentally demonstrate our algorithm on a trapped-ion device, exploiting both intrinsic electronic and motional degrees of freedom, showing excellent quantitative agreement for a single-mode vibronic photoelectron spectrum of SO$_2$.

The atomic mass difference of 163Ho and 163Dy has been directly measured with the Penning trap mass spectrometer SHIPTRAP applying the novel phase imaging ion cyclotron resonance technique. Our measurement has solved the long standing problem of large discrepancies in the Q value of the electron capture in 163Ho determined by different techniques. Our measured mass difference shifts the current Q value of 2555(16) eV evaluated in the Atomic Mass Evaluation 2012 [G. Audi et al., Chin. Phys. C 36, 1157 (2012)] by more than 7 sigma to 2833(30stat)(15sys) eV/c2. With the new mass difference it will be possible, e.g., to reach in the first phase of the ECHo experiment a statistical sensitivity to the neutrino mass below 10 eV, which will reduce its present upper limit by more than an order of magnitude.

A new mechanism for acceleration and enrichment of 3He during impulsive solar flares is presented. Low-frequency electromagnetic plasma waves excited by the Electron Firehose Instability (EFI) can account for the acceleration of ions up to 1 MeV/amu energies as a single stage process. The EFI arises as a direct consequence of the free energy stored in a temperature anisotropy (T_parallel>T_perp) of the bulk energized electron population during the acceleration process. In contrast to other mechanisms which require special plasma properties, the EFI is an intrinsic feature of the acceleration process of the bulk electrons. Being present as a side effect in the flaring plasma, these waves can account for the acceleration of 3He and 4He while selectively enhancing 3He due to the spectral energy density built up from linear growth. Linearized kinetic theory, analytic models and test-particle simulations have been applied to investigate the ability of the waves to accelerate and fractionate. As waves grow in both directions parallel to the magnetic field, they can trap resonant ions and efficiently accelerate them to the highest energies. Plausible models have been found that can explain the observed energies, spectra and abundances of 3He and 4He.