Ion Optical Frequency Standard

The phonon laser realized in a trapped ion, i.e., a self-sustained mechanical oscillator, has demonstrated the unique characteristics in practically detecting externally applied electric signals without the prerequisite of sideband cooling. Entering the quantum regime via sideband cooling is expected to further improve its sensing performance. Here we report the first experimental realization of a quantum-regime single-ion phonon laser ($\bar{n}<10$) using a trapped $^{40}\mathrm{Ca}^+$ ion and demonstrate electrometry based on its phase-space symmetry-breaking response to weak resonant electric fields. By tuning the phonon-laser parameters, we reveal that the sensing performance is fundamentally governed by the finite-time relaxation dynamics of the underlying open quantum system. We find that a slow Liouvillian relaxation, correlated with the finite experimental interaction window, effectively enhances the dynamic susceptibility while maintaining the structural robustness of the limit cycle. This regime, when applied to the detection of electric fields, produces a shot-noise-limited peak sensitivity of $14.15 \pm 0.77~μ\mathrm{V/m}/\sqrt{\mathrm{Hz}}$ and a minimum detectable field variation of $δE_{\mathrm{min}} \approx 1.83~μ\mathrm{V/m}$. Our results establish quantum phonon lasers as a practical platform for advanced sensing and highlight the central role of Liouvillian dynamics in non-equilibrium electrometry.

Stochastic resonance (SR) could amplify weak electric-field signals in nonlinear systems by means of the externally injected noises. Here we propose and experimentally demonstrate a modified SR method, termed squeezing-induced SR, implemented in the system involving a trapped ion behaving as a Duffing oscillator. We find that squeezing the phase noise of the oscillator results in amplified fluctuation of the corresponding amplitude, which helps achieve the SR. Since no auxiliary noise source is needed, the squeezing-induced SR may enhance the signal-to-noise ratio by 4.28 $\pm$ 0.39 dB compared to the conventional noise-induced SR under identical conditions of the electric-field detection. This technique offers a promising approach for developing atomic ion sensors for detecting weak electric-field signals.

The exceptional point has presented considerably interesting and counterintuitive phenomena associated with nonreciprocity, precision measurement, and topological dynamics. The Liouvillian exceptional point (LEP), involving the interplay of energy loss and decoherence inherently relevant to quantum jumps, has recently drawn much attention due to capability to fully capture quantum system dynamics and naturally facilitate non-Hermitian quantum investigations. It was also predicted that quantum jumps could give rise to third-order LEPs in two-level quantum systems for its high dimensional Liouvillian superoperator, which, however, has never been experimentally confirmed until now. Here we report the first observation of the third-order LEPs emerging from quantum jumps in an ultracold two-level trapped-ion system. Moreover, by combining decay with dephasing processes, we present the first experimental exploration of LEPs involving combinatorial effect of decay and dephasing. In particular, due to non-commutativity between the Lindblad superoperators governing LEPs for decay and dephasing, we witness the movement of LEPs driven by the competition between decay and dephasing occurring in an open quantum system. This unique feature of non-Hermitian quantum systems paves a new avenue for modifying nonreciprocity, enhancing precision measurement, and manipulating topological dynamics by tuning the LEPs.

Quantum signal processing (QSP), which enables systematic polynomial transformations on quantum data through sequences of qubit rotations, has emerged as a fundamental building block for quantum algorithms and data re-uploading quantum neural networks. While recent experiments have demonstrated the feasibility of shallow QSP circuits, the inherent limitations in scaling QSP to achieve complex transformations on quantum hardware remain an open and critical question. Here we report the first experimental realization of deep QSP circuits in a trapped-ion quantum simulator. By manipulating the qubit encoded in a trapped $^{43}\textrm{Ca}^{+}$ ion, we demonstrate high-precision simulation of some prominent functions used in quantum algorithms and machine learning, with circuit depths ranging from 15 to 360 layers and implementation time significantly longer than coherence time of the qubit. Our results reveal a crucial trade-off between the precision of function simulation and the concomitant accumulation of hardware noise, highlighting the importance of striking a balance between circuit depth and accuracy in practical QSP implementation. This work addresses a key gap in understanding the scalability and limitations of QSP-based algorithms on quantum hardware, providing valuable insights for developing quantum algorithms as well as practically realizing quantum singular value transformation and data re-uploading quantum machine learning models.

The approach of shortcuts to adiabaticity enables the effective execution of adiabatic dynamics in quantum information processing with enhanced speed. Owing to the inherent trade-off between dynamical speed and the cost associated with the transitionless driving field, executing arbitrarily fast operations becomes impractical. To understand the accurate interplay between speed and energetic cost in this process, we propose theoretically and verify experimentally a new trade-off, which is characterized by a tightly optimized bound within $s$-parameterized phase spaces. Our experiment is carried out in a single ultracold $^{40}$Ca$^{+}$ ion trapped in a harmonic potential. By exactly operating the quantum states of the ion, we execute the Landau-Zener model as an example, where the quantum speed limit as well as the cost are governed by the spectral gap. We witness that our proposed trade-off is indeed tight in scenarios involving both initially eigenstates and initially thermal equilibrium states. Our work helps understanding the fundamental constraints in shortcuts to adiabaticity and illuminates the potential of under-utilized phase spaces that have been traditionally overlooked.

Conventional theoretical studies on the ground-state laser cooling of a trapped ion have mostly focused on the weak sideband coupling (WSC) regime, where the cooling rate is inverse proportional to the linewidth of the excited state. In a recent work~[New J. Phys. 23, 023018 (2021)], we proposed a theoretical framework to study the ground state cooling of a trapped ion in the strong sideband coupling (SSC) regime, under the assumption of a vanishing carrier transition. Here we extend this analysis to more general situations with nonvanishing carrier transitions, where we show that by properly tuning the coupling lasers a cooling rate proportional to the linewidth can be achieved. Our theoretical predictions closely agree with the corresponding exact solutions in the SSC regime, which provide an important theoretical guidance for sideband cooling experiments.

Detecting extremely small forces helps exploring new physics quantitatively. Here we demonstrate that the phonon laser made of a single trapped $^{40}$Ca$^{+}$ ion behaves as an exquisite sensor for small force measurement. We report our successful detection of small electric forces regarding the DC trapping potential with sensitivity of 2.41$\pm$0.49 zN/$\sqrt{\rm Hz}$, with the ion only under Doppler cooling, based on the injection-locking of the oscillation phase of the phonon laser in addition to the classical squeezing applied to suppress the measurement uncertainty. We anticipate that such a single-ion sensor would reach a much better force detection sensitivity in the future once the trapping system is further improved and the fluorescence collection efficiency is further enhanced.

For the first time, we experimentally determine the infrared magic wavelength for the $^{40}$Ca$^{+}$ $4s\, ^{2}\!S_{1/2} \rightarrow 3d\,^{2}\!D_{5/2}$ electric quadrupole transition by observation of the light shift canceling in $^{40}$Ca$^{+}$ optical clock. A "magic" magnetic field direction is chosen to make the magic wavelength insensitive to both the linear polarization purity and the polarization direction of the laser. The determined magic wavelength for this transition is 1056.37(9)~nm, which is not only in good agreement with theoretical predictions but also more precise by a factor of about 300. Using this measured magic wavelength we also derive the differential static polarizability to be $-44.32(32)$~a.u., which will be an important input for the evaluation of the blackbody radiation shift at room temperatures. Our work paves a way for all-optical-trapping of $^{40}$Ca$^{+}$ optical clock.

Developing nano-mechanical oscillators for ultrasensitive force detection is of great importance in exploring science. We report our achievement of ultrasensitive detection of the external force regarding the radio-frequency electric field by a nano-sensor made of a single trapped $^{40}$Ca$^{+}$ ion under injection-locking, where squeezing is additionally applied to detection of the smallest force in the ion trap. The employed ion is confined stably in a surface electrode trap and works as a phonon laser that is very sensitive to the external disturbance. The injection-locking drove the ion's oscillation with phase synchronization, yielding the force detection with sensitivity of 347 $\pm$ 50 yN/$\sqrt{Hz}$. Further with 3 dB squeezing applied on the oscillation phase variance, we achieved a successful detection of the smallest force to be 86.5 $\pm$ 70.1 yN.

Quantum gates induced by geometric phases are intrinsically robust against noise due to their global properties of the evolution paths. Compared to conventional nonadiabatic geometric quantum computation (NGQC), the recently proposed nonadiabatic noncyclic geometric quantum computation (NNGQC) works in a faster fashion, while still remaining the robust feature of the geometric operations. Here, we experimentally implement the NNGQC in a single trapped ultracold $^{40}$Ca$^{+}$ ion for verifying the noise-resilient and fast feature. By performing unitary operations under imperfect conditions, we witness the advantages of the NNGQC with measured fidelities by quantum process tomography in comparison with other two quantum gates by conventional NGQC and by straightforwardly dynamical evolution. Our results provide the first evidence confirming the possibility of accelerated quantum information processing with limited systematic errors even in the imperfect situation.

We present a novel ultrastable superconducting radio-frequency (RF) ion trap realized as a combination of an RF cavity and a linear Paul trap. Its RF quadrupole mode at 34.52 MHz reaches a quality factor of $Q\approx2.3\times 10^5$ at a temperature of 4.1 K and is used to radially confine ions in an ultralow-noise pseudopotential. This concept is expected to strongly suppress motional heating rates and related frequency shifts which limit the ultimate accuracy achieved in advanced ion traps for frequency metrology. Running with its low-vibration cryogenic cooling system, electron beam ion trap and deceleration beamline supplying highly charged ions (HCI), the superconducting trap offers ideal conditions for optical frequency metrology with ionic species. We report its proof-of-principle operation as a quadrupole mass filter with HCI, and trapping of Doppler-cooled ${}^9\text{Be}^+$ Coulomb crystals.

Quantitative measure of disorder or randomness based on the entropy production characterizes thermodynamical irreversibility, which is relevant to the conventional second law of thermodynamics. Here we report, in a quantum mechanical fashion, the first theoretical prediction and experimental exploration of an information-theoretical bound on the entropy production. Our theoretical model consists of a simplest two-level dissipative system driven by a purely classical field, and under the Markovian dissipation, we find that such an information-theoretical bound, not fully validating quantum relaxation processes, strongly depends on the drive-to-decay ratio and the initial state. Furthermore, we carry out experimental verification of this information-theoretical bound by means of a single spin embedded in an ultracold trapped $^{40}$Ca$^{+}$ ion. Our finding, based on a two-level model, is fundamental to any quantum thermodynamical process and indicates much difference and complexity in quantum thermodynamics with respect to the conventionally classical counterpart.

A low-energy, compact and superconducting electron beam ion trap (the Shanghai-Wuhan EBIT or SW-EBIT) for extraction of highly charged ions is presented. The magnetic field in the central drift tube of the SW-EBIT is approximately 0.21 T produced by a pair of high-temperature superconducting coils. The electron-beam energy of the SW-EBIT is in the range of 30-4000 eV, and the maximum electron-beam current is up to 9 mA. Acting as a source of highly charged ions, the ion-beam optics for extraction is integrated, including an ion extractor and an einzel lens. A Wien filter is then used to measure the charge-state distribution of the extracted ions. In this work, the tungsten ions below the charge state of 15 have been produced, extracted, and analyzed. The charge-state distributions and spectra in the range of 530-580 nm of tungsten ions have been measured simultaneously with the electron-beam energy of 279 eV and 300 eV, which preliminarily indicates that the 549.9 nm line comes from $W^{14+}$.

We describe a framework for calculating the frequency shift and uncertainty of trapped-ion optical atomic clocks caused by background-gas collisions, and apply this framework to an $^{27}$Al$^+$ clock to enable a total fractional systematic uncertainty below $10^{-18}$. For this clock, with 38(19) nPa of room temperature H$_2$ background gas, we find that collisional heating generates a non-thermal distribution of motional states with a mean time-dilation shift of order $10^{-16}$ at the end of a 150 ms probe, which is not detected by sideband thermometry energy measurements. However, the contribution of collisional heating to the spectroscopy signal is highly suppressed and we calculate the BGC shift to be $-0.6(2.4)\times 10^{-19}$, where the shift is due to collisional heating time-dilation and the uncertainty is dominated by the worst case $\pm π/2$ bound used for collisional phase shift of the $^{27}$Al$^+$ superposition state. We experimentally validate the framework and determine the background-gas pressure in situ using measurements of the rate of collisions that cause reordering of mixed-species ion pairs.

Doppler cooling with lasers is essential to ions' trapping and also a preliminary step towards achievement of ultracold ions. Due to lack of effective tools, experimentally monitoring the ions' temperature and the laser-ion coupling is difficult in Doppler cooling. Here we analytically explore the Doppler cooling process of trapped ions, exemplified by $^{40}$Ca$^{+}$, by solving the friction coefficient in the Doppler cooling with respect to a thermal bath, particularly, to a bath with large heating rate. We show four regions for cooling and heating induced by the three-level electromagnetically induced transparency and propose a practical method for measuring the Rabi frequency by the Doppler cooling window. In addition, the final temperature of the laser-cooled ions can be obtained analytically in the case of a weak thermal bath, whereas for the strong thermal bath this requires numerical treatment due to involvement of the Doppler shift and large Lamb-Dicke parameter. Our analytic results would help for understanding many experimental observations, such as configuration phase transition, phonon laser and thermodynamics regarding hot trapped ions.

We demonstrate for the first time a linear-zigzag phase transition induced solely by temperature of the $^{40}$Ca$^{+}$ ion crystals in a surface-electrode trap. In contrast to the previously observed counterparts based on change of the mechanical equilibrium conditions of the ions, our presented structural phase transition occurs due to controllable influence of thermal fluctuation. The ions' temperature is well controlled by tuning the cooling laser and the experimental observation could be fully understood by classical Langevin equation in addition to the effects from thermal fluctuation. Our experimental investigation indicates the fantastic role of thermal fluctuation played in the thermodynamic process at atomic level, which might bridge the thermodynamics from the macroscopic domain to the quantum regime.

Quantum phase transitions are usually classified into discrete universality classes that typically only depend on symmetries and spatial dimensionalities. In this Letter, we demonstrate an opportunity to continuously vary the critical exponents or universalities by tuning experimental parameters in a given physical system. Particularly, we show that critical exponents in long-range spin systems simulated in ion traps can be easily tuned with laser detuning. We suggest that such experiments also effectively simulate some aspects of critical phenomena in conventional spin systems but in artificial non-integer spatial dimensions.

Most non-equilibrium processes in thermodynamics are quantified only by inequalities, however the Jarzynski relation presents a remarkably simple and general equality relating non-equilibrium quantities with the equilibrium free energy, and this equality holds in both classical and quantum regimes. We report a single-spin test and confirmation of the Jarzynski relation in quantum regime using a single ultracold $^{40}Ca^{+}$ ion trapped in a harmonic potential, based on a general information-theoretic equality for a temporal evolution of the system sandwiched between two projective measurements. By considering both initially pure and mixed states, respectively, we verify, in an exact and fundamental fashion, the non-equilibrium quantum thermodynamics relevant to the mutual information and Jarzynski equality.

One of the outstanding challenges to information processing is the eloquent suppression of energy consumption in execution of logic operations. Landauer principle sets an energy constraint in deletion of a classical bit of information. Although some attempts have been paid to experimentally approach the fundamental limit restricted by this principle, exploring Landauer principle in a purely quantum mechanical fashion is still an open question. Employing a trapped ultracold ion, we experimentally demonstrate a quantum version of Landauer principle, i.e., an equality associated with energy cost of information erasure in conjunction with entropy change of the associated quantized environment. Our experimental investigation substantiates an intimate link between information thermodynamics and quantum candidate systems for information processing.

The uncertainty relations, pioneered by Werner Heisenberg nearly 90 years ago, set a fundamental limitation on the joint measurability of complementary observables. This limitation has long been a subject of debate, which has been reignited recently due to new proposed forms of measurement uncertainty relations. The present work is associated with a new error trade-off relation for compatible observables approximating two incompatible observables, in keeping with the spirit of Heisenberg's original ideas of 1927. We report the first \textsl{direct} test and confirmation of the tight bounds prescribed by such an error trade-off relation, based on an experimental realisation of optimal joint measurements of complementary observables using a single ultracold $^{40}Ca^{+}$ ion trapped in a harmonic potential. Our work provides a prototypical determination of ultimate joint measurement error bounds with potential applications in quantum information science for high-precision measurement and information security.

In this paper, blackbody radiation (BBR) temperature rise seen by the $^{40}$Ca$^+$ ion confined in a miniature Paul trap and its uncertainty have been evaluated via finite-element method (FEM) modelling. The FEM model was validated by comparing with thermal camera measurements, which were calibrated by PT1000 resistance thermometer, at several points on a dummy trap. The input modelling parameters were analyzed carefully in detail, and their contributions to the uncertainty of environment temperature were evaluated on the validated FEM model. The result shows that the temperature rise seen by $^{40}$Ca$^+$ ion is 1.72 K with an uncertainty of 0.46 K. It results in a contribution of 2.2 mHz to the systematic uncertainty of $^{40}$Ca$^+$ ion optical clock, corresponding to a fractional uncertainty 5.4$\times$10$^{-18}$. This is much smaller than the uncertainty caused by the BBR shift coefficient, which is evaluated to be 4.8 mHz and at 10$^{-17}$ level in fractional frequency units.

A transportable optical clock refer to the $4s^2S_{1/2}-3d^2D_{5/2}$ electric quadrupole transition at 729 nm of single $^{40}Ca^+$ trapped in mini Paul trap has been developed. The physical system of $^{40}Ca^+$ optical clock is re-engineered from a bulky and complex setup to an integration of two subsystems: a compact single ion unit including ion trapping and detection modules, and a compact laser unit including laser sources, beam distributor and frequency reference modules. Apart from the electronics, the whole equipment has been constructed within a volume of 0.54 $m^3$. The systematic fractional uncertainty has been evaluated to be $7.7\times 10^{-17}$, and the Allan deviation fits to be $2.3\times {10}^{-14}/\sqrtτ$ by clock self-comparison with a probe pulse time 20 ms.

The $^{27}$Al$^+$ ion optical clock is one of the most attractive optical clocks due to its own advantages, such as low blackbody radiation shift at room temperature and insensitive to the magnetic drift. However, it cannot be laser-cooled directly in the absence of 167 nm laser to date. This problem can be solved by sympathetic cooling. In this work, a linear Paul trap is used to trap both $^{40}$Ca$^{+}$ and $^{27}$Al$^+$ ions simultaneously, and a single Doppler-cooled $^{40}$Ca$^+$ ion is employed to sympathetically cool a single $^{27}$Al$^+$ ion. Thus a "bright-dark" two-ion crystal has been successfully synthesized. The temperature of the crystal has been estimated to be about 7 mK by measuring the ratio of carrier and sideband spectral intensities. Finally, the dark ion is proved to be an $^{27}$Al$^+$ ion by precise measuring of the ion crystal`s secular motion frequency, which means that it is a great step for our $^{27}$Al$^+$ quantum logic clock.

We propose a new dark-state cooling method of trapped ion systems in the Lamb-Dicke limit. With application of microwave dressing the ion, we can obtain two electromagnetically induced transparency structures. The heating effects caused by the carrier and the blue sideband transition vanish due to the EIT effects and the final mean phonon numbers can be much less than the recoil limit. Our scheme is robust to fluctuations of microwave power and laser intensities which provides a broad cooling bandwidth to cool motional modes of a linear ion chain. Moreover, it is more suitable to cool four-level ions on a large-scale ion chip.

We demonstrate experimentally the existence of magic wavelengths and determine the ratio of the oscillator strengths for a single trapped ion. For the first time, two magic wavelengths for the 40Ca+ clock-transition are measured simultaneously with high precision, giving Lamda|mj|=1/2 = 395.7992(7) nm and Lamda|mj|=3/2 = 395.7990(7) nm. By tuning a laser to an intermediate wavelength between two transitions (4s1/2-4p1/2 and 4s1/2-4p3/2) of 40Ca+, the sensitivity of the clock transition Stark shift to the oscillator strengths for the resonance transition has been greatly enhanced. With the measured magic wavelengths, we determine the ratio of the oscillator strengths to sub-0.5% accuracy. Our experimental method may be applied to measure magic wavelengths for other ion clock-transitions, and, promisingly, the measurement of these magic wavelengths paves the way to building lattice ion clocks.

The static and dynamic electric multipolar polarizabilities and second hyperpolarizabilities of the H$_2^+$, D$_2^+$, and HD$^+$ molecular ions in the ground and first excited states are calculated nonrelativistically using explicitly correlated Hylleraas basis sets. The calculations are fully nonadiabatic; the Born-Oppenheimer approximation is not used. Comparisons are made with published theoretical and experimental results, where available. In our approach, no derivatives of energy functions nor derivatives of response functions are needed. In particular, we make contact with earlier calculations in the Born-Oppenheimer calculation where polarizabilities were decomposed into electronic, vibrational, and rotational contributions and where hyperpolarizabilities were determined from derivatives of energy functions. We find that the static hyperpolarizability for the ground state of HD$^+$ is seven orders of magnitude larger than the corresponding dipole polarizability. For the dipole polarizability of HD$^+$ in the first excited-state the high precision of the present method facilitates treatment of a near cancellation between two terms. For applications to laser spectroscopy of trapped ions we find tune-out and magic wavelengths for the HD$^+$ ion in a laser field. In addition, we also calculate the first few leading terms for long-range interactions of a hydrogen molecular ion interacting with a ground-state H, He, and Li atoms.

The oscillation coupling and different nonlinear effects are observed in a single trapped $^{40}Ca^{+}$ ion confined in our home-built surface-electrode trap (SET). The coupling and the nonlinearity are originated from the high-order multipole potentials due to different layouts and the fabrication asymmetry of the SET. We solve a complicated Duffing equation with coupled oscillation terms by the multiple scale method, which fits the experimental values very well. Our investigation in the SET helps for exploring nonlinearity using currently available techniques and for suppressing instability of qubits in quantum information processing with trapped ions.

In this brief report, we propose a possible way, theoretically and experimentally, to generate a NOON state of the two degenerate ferromagnetic ground states of the Transverse Ising Model. In our scheme we employ the macroscopic quantum tunneling (MQT) effect between the two degenerate ferromagnetic ground states to realize the NOON state. Our calculation about the MQT process is based on a higher-order degenerate perturbation method. After doing a transformation, the MQT process could also be treated as the hopping of individual virtual fermions in the spin chain, which will leads to an analytical description of tunneling process. The experimental feasibility for generating the NOON state is discussed in the setup of linear ion trap.

We show how to implement a Mach-Zehnder interferometry based upon a string of trapped ions with artificial nonlinear interactions. By adiabatically sweeping down/up the coupling strength between two involved internal states of the ions, we could achieve the beam splitting/recombination. Based on current techniques for manipulating trapped ions, we discuss the experimental feasibility of our scheme and analyze some undesired uncertainty under realistic experimental environment.

We report a frequency measurement of the clock transition of a single ^40Ca^+ ion trapped and laser cooled in a miniature ring Paul trap with 10^-15 level uncertainty. In the measurement, we used an optical frequency comb referenced to a Hydrogen maser, which was calibrated to the SI second through the Global Positioning System (GPS). Two rounds of measurements were taken in May and June 2011, respectively. The frequency was measured to be 411 042 129 776 393.0(1.6) Hz with a fractional uncertainty of 3.9{\times}10^-15 in a total averaging time of > 2{\times}10^6 s within 32 days.

We explore the possibility of implementing a Heisenberg-limited Mach-Zehnder interferometry via an array of trapped ions, which obey a quantum Ising model within a transverse field. Based upon adiabatic processes of increasing the Ising interaction and then decreasing the transverse field, we demonstrate a perfect transition from paramagnetism to ferromagnetic states, which can be used as the beam splitter for the multi-ion Mach-Zehnder interferometry. The achieved NOON state of the ions enables the Heisenberg-limited interferometry. Using currently available techniques for ultracold ions, we discuss the experimental feasibility of our scheme with global operations.

An efficient scheme is proposed to carry out gate operations on an array of trapped Yb$^+$ ions, based on a previous proposal using both electronic and nuclear degrees of freedom in a magnetic field gradient. For this purpose we consider the Paschen-Back regime (strong magnetic field) and employ a high-field approximation in this treatment. We show the possibility to suppress the unwanted coupling between the electron spins by appropriately swapping states between electronic and nuclear spins. The feasibility of generating the required high magnetic field is discussed.

Zitterbewegung (ZB), the trembling of free relativistic electrons in a vacuum could be simulated by a single trapped ion. We focus on the variations of ZB under different parity conditions and find no ZB in the case of odd or even parity. ZB occurs only for admixture of the odd and even parity states. We also show the similar role played by the parity operator for the trapped ion in Fock-state representation and the space inversion operator for a realistic relativistic electron. Although the ZB effect is invisible in a relativistic electron, preparation of the trapped ion in different parity states is a sophisticated job, which makes it possible to observe the parity relevant ZB effects with currently available techniques.

We propose how to explore the Franck-Condon (FC) physics via a single ion confined in a spin-dependent potential, formed by the combination of a Paul trap and a magnetic field gradient. The correlation between electronic and vibrational degrees of freedom, called as electron-vibron coupling, is induced by a nonzero gradient. For a sufficiently strong electron-vibron coupling, the FC blockade of low-lying vibronic transitions takes place. We analyze the feasibility of observing the FC physics in a single trapped ion, and demonstrate various potential applications of the ionic FC physics in quantum state engineering and quantum information processing.

We present an explanation of why the observed supersolid fractions of helium solids are rather far below unity. One might observe large supersolid fraction of neon systems immersing in liquid $^3$He. A system of bosonic ions in a ring trap could display a supersolid fraction close to unity.

Physical systems must fulfill a number of conditions to qualify as useful quantum bits (qubits) for quantum information processing, including ease of manipulation, long decoherence times, and high fidelity readout operations. Since these conditions are hard to satisfy with a single system, it may be necessary to combine different degrees of freedom. Here we discuss a possible system, based on electronic and nuclear spin degrees of freedom in trapped ions. The nuclear spin yields long decoherence times, while the electronic spin, in a magnetic field gradient, provides efficient manipulation, and the optical transitions of the ions assure a selective and efficient initialization and readout.

The main idea in the original Grover search (Phys. Rev. Lett. 79, 325 (1997)) is to single out a target state containing the solution to a search problem by amplifying the amplitude of the state, following the Oracle's job, i.e., a black box giving us information about the target state. We design quantum circuits to accomplish a complete Grover search involving both the Oracle's job and the amplification of the target state, which are employed to solve Satisfiability (SAT) problems. We explore how to carry out the quantum circuits by currently available ion-trap quantum computing technology.

We propose a potentially practical scheme for realization of an n-qubit (n>2) conditional phase flip (CPF) gate and implementation of Grover search algorithm in the ion-trap system. We demonstrate both analytically and numerically that, our scheme could be achieved efficiently to find a marked state with high fidelity and high success probability. We also show the merits of the proposal that the increase of the ion number can improve the fidelity and the success probability of the CPF gate. The required operations for Grover search are very close to the capabilities of current ion-trap techniques.

We consider a single ion confined in a trap under radiation of two traveling waves of lasers. In the strong-excitation regime and without the restriction of Lamb-Dicke limit, the Hamiltonian of the system is similar to a driving Jaynes-Cummings model without rotating wave approximation (RWA). The approach we developed enables us to present a complete eigensolutions, which makes it available to compare with the solutions under the RWA. We find that, the ground state in our non-RWA solution is energically lower than the counterpart under the RWA. If we have the ion in the ground state, it is equivalent to a spin dependent force on the trapped ion. Discussion is made for the difference between the solutions with and without the RWA, and for the relevant experimental test, as well as for the possible application in quantum information processing.

We propose a practical scheme for implementing two-dimension quantum dense coding (QDC) between three parties through manipulating three ions confined in microtraps addressed by microwaves and assisted by a magnetic field gradient. The ions in our scheme are not required to be strictly cooled to the vibrational ground state because single-qubit and multi-qubit operations are made via Ising terms, in which the vibrational modes of the ions remain unchanged throughout the scheme, rendering our scheme robust to the heating of the ions. We also present the detailed steps and parameters for implementing the three-party QDC experimentally and show that the proposed scheme is within the current techniques of ion-trap experiments.

The quantum behavior of a precooled cantilever can be probed highly efficiently by coupling to a trapped ultracold ion, in which a fast cooling of the cantilever down to the ground vibrational state is possible. We solve the dynamics of the coupling system by a squeezed-state expansion technique, and can in principle obtain the exact solution of the time-evolution of the coupling system. Compared to the treatment under rotating-wave approximation, we can present a more accurate description of the quantum behavior of the cantilever.

We propose a potential scheme to generate entangled photons by manipulating trapped ions embedded in two-mode microcavities, respectively, assisted by a magnetic field gradient. By means of the spin-spin coupling due to the magnetic field gradient and the Coulomb repulsion between the ions, we show how to efficiently generate entangled photons by detecting the internal states of the trapped ions. We emphasize that our scheme is advantageous to create complete sets of entangled multi-photon states. The requirement and the experimental feasibility of our proposal are discussed in detail.

By means of the Ising terms generated by Coulomb interaction between ions and the magnetic field gradient, we carry out teleportation with insurance with trapped ions. We show the feasibility and the favorable feature of our scheme by comparing with the recently achieved teleportation experiments with trapped ions.

The beam splitter and phase shifter, which are the key elements in the experiments of light interference, are realized in the motion of trapped ions. Some applications, such as the creation of quantum motional states and the realization of Mach-Zehnder interferometer, are illustrated. Several detection methods of motional states used in the interferometer are also discussed.

We propose a method to create two-mode squeezed states and their superposition in the center-of-mass mode and breathing mode of two-trapped ions. Each ion is illuminated simultaneously by two standing waves. One of the fields is tuned to excite resonantly and simultaneously both upper sidebands of the two normal modes, while the other field tuned to the corresponding lower sidebands.

We propose a scheme to perform basic gates of quantum computing and prepare entangled states in a system with cold trapped ions located in a single mode optical cavity. General quantum computing can be made with both motional state of the trapped ion and cavity state being qubits. We can also generate different kinds of entangled states in such a system without state reduction, and can transfer quantum states from the ion in one trap to the ion in another trap. Experimental requirement for achieving our scheme is discussed.

Quantum computing gates are proposed to apply on trapped ions in decoherence-free states. As phase changes due to time evolution of components with different eigenenergies of quantum superposition are completely frozen, quantum computing based on this model would be perfect. Possible application of our scheme in future ion-trap quantum computer is discussed.

The Raman interaction of a trapped ultracold ion with two travelling wave lasers is studied analytically with series solutions, in the absence of the rotating wave approximation (RWA) and the restriction of both the Lamb-Dicke limit and the weak excitation regime. The comparison is made between our solutions and those under the RWA to demonstrate the validity region of the RWA. As a practical example, the preparation of Schrödinger-cat states with our solutions is proposed beyond the weak excitation regime.

A k-quantum nonlinear Jaynes-Cummings model for two trapped ions interacting with laser beams resonant to k-th red side-band of center-of-mass mode, far from Lamb-Dicke regime, has been obtained. The exact analytic solution showed the existence of quantum collapses and revivals of the occupation of two atoms.

We showed that in Lamb-Dicke regime and under rotating wave approximation, the dynamical behavior of two trapped ions interacting with a laser beam resonant to the first red side-band of center-of-mass mode can be described by Jaynes-Cummings Model. An exact analytic solution for this kind of Jaynes-Cummings model is presented. The results showed that quantum collapses and revivals for the occupation of two atoms, and squeezing for vibratic motion of center-of-mass mode existed in both two different types of initial conditions. The maximum momentum squeezing for center-of-mass mode in these two types of conditions are found to be 42.4% and 43.8% respectively. The coherence, in the first type of initial conditions can keeps long times, and in the second type of initial conditions, a concrete form of coherent state is obtained, when the initial average number is very small.

Raman interaction of a trapped ultracold ion with two traveling wave lasers has been used extensively in the ion trap experiments. We solve this interaction in the absence of the rotating wave approximation by a continued fraction, without considering the restriction of the Lamb-Dicke limit and the weak excitation regime. Some interesting characteristics of the ion-trap system, particularly for the ion outside the weak excitation regime are found. Finally, a comparison of our results with the solution under the rotating wave approximation is made.

The superpositional wave function oscillations for finite-time implementation of quantum algorithms modifies the desired interference required for quantum computing. We propose a scheme with trapped ultracold ion-pairs being qubits to diminish the detrimental effect of the wave function oscillations, and apply the scheme to the two-qubit Grover's search. It can be also found that the qubits in our scheme are more robust against the decoherence caused by the environment, and the model is scalable.

We propose a scheme to generate a superposition with arbitrary coefficients on a line in phase space for the center-of-mass vibrational mode of N ions by means of isolating all other spectator vibrational modes from the center-of-mass mode. It can be viewed as the generation of previous methods for preparing motional states of one ion. For large number of ions, we need only one cyclic operatin to generate such a superposition of many coherent states.